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  • 1
    Online Resource
    Online Resource
    Cham : Springer International Publishing | Cham : Imprint: Springer
    Keywords: Physical geography. ; Water. ; Hydrology. ; Geochemistry. ; Environmental monitoring.
    Description / Table of Contents: Chapter 1 - Introduction -- 2. Mount Etna,- 3. Hydrogeological Basin of the Hyblean Mountains -- 4. Madonie hydrogeological basin -- 5. Nebrodi Mountains hydrogeological basin -- 6. Hydrogeological Basin of the Palermo Mountains -- 7. Peloritani Mountains Hydrogeological Basin -- 8. Piazza Armerina hydrogeological basin -- 9. Rocca Busambra hydrogeological basin -- 10. Sicani Mountains hydrogeological basin -- 11. Trabia and Termini-Imerese hydrogeological basin -- 12. Trapani Mountains hydrogeological basin.
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource(X, 234 p. 113 illus., 76 illus. in color.)
    Edition: 1st ed. 2024.
    ISBN: 9783031604737
    Language: English
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  • 2
    Publication Date: 2021-06-15
    Description: Sicily hosts many natural manifestations that include thermal waters, gas discharges and mud volcanoes. Due to the significant geodynamic and geological differences, the fluid discharges along a NE-WS–oriented transect that run from the Peloritani Mts. to the Sciacca Plain shows a large variability in water and gas chemical and isotopic compositions. The studied waters are characterized by Ca-HCO3, Ca(Mg)-SO4, Ca-Cl and Na-Cl compositions produced by distinct geochemical processes such as water-rock-gas interactions, mixing between deep and shallow aquifers and seawater and direct and reverse ion exchanges. The gas chemistry is dominated by CO2 to the east and CO2-N2 to the west of the study area, whereas the central part shows mud volcanoes discharging CH4-rich gases. Water isotopes suggest that the thermal waters are fed by a meteoric recharge, although isotopic exchange processes between thermal fluids and host rocks at temperature 〉150°C are recognized. Accordingly, liquid geothermometry suggests equilibrium temperatures up to 220°C. The carbon in CO2 and helium isotopes of the emissions from the westernmost sector of Sicily indicate that these two gases consists of up to 40 % of a mantle component, the latter decreasing to the east down to 10% where CO2 of thermometamorphic origin dominates. Accordingly, conceptual models of the fluid circulation for the western, central and eastern sectors are proposed. The regional geothermal reservoir, hosted in carbonates in the western sector and locally outcropping, is of low to medium temperature. Higher temperature conditions (up to 200-220°C) are suggested by geothermometry and probably related to deeper levels of the system. Sicily can be regarded as a potentially suitable area for future investigations to evaluate specific activities aimed at exploiting the geothermal resource.
    Description: Published
    Description: 102120
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Fluid geochemistry ; Stable isotopes ; Geothermal exploration ; Dissolved gases ; Tectonics ; 03. Hydrosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-06-30
    Description: This study presents the chemical and isotopic compositions of hydrothermal gases from fumaroles discharging around Copahue volcano (Argentina). Gas samples, including those from two fumaroles at the active summit crater, were collected during 13 surveys carried out by different research teams from 1976 to February 2016. The time-series of H2, CO and light hydrocarbons showed episodic increases related to the main events of the last eruptive cycle that started on 19 July 2012. Concentration peaks were likely caused by enhanced input of hot magmatic fluids affecting the hydrothermal reservoir. These data contrast with the temporal variations shown by Rc/Ra and δ13C-CO2 values in 2012–2014, which indicated an increasing input from a crustal fluid source. In 2015–2016, however, these isotopic parameters showed opposite trends; their composition became closer to that of the two summit fumaroles, which possibly corresponds to that of the deep magmatic-related end-member. The delayed and reduced compositional changes in the peripheral hydrothermal fluid discharge in response to the 2012–2016 eruptive events suggest that geochemical surveys of these emissions are unlikely to provide premonitory signals of volcanic unrest if the volcanic activity remains centered in the main crater. Instead, an instrument which is able to provide measurements of volcanic gases in the air (e.g.MultiGAS) may be used to detect changes at the summit crater. Otherwise, monitoring of seismic activity and ground deformation, as well as the periodic measurement of the chemistry of the water in the Rio Agrio, which is fed by thermal discharge from the summit crater, seem to represent the most reliable means of monitoring at Copahue. However, the relative compositional stability of the hydrothermal reservoir is a great advantage in terms of geothermal resource exploitation and could encourage new investments in the Copahue geothermal project which was abandoned in the 1990s.
    Description: Published
    Description: 69
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 6A. Geochimica per l'ambiente
    Description: 1TR. Studi per le Georisorse
    Description: JCR Journal
    Keywords: Geochemical monitoring ; Copahue volcano ; Fluid geochemistry ; Hydrothermal system ; Active volcano
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2020-11-11
    Description: We have mapped the diffuse CO2 efflux from the Specchio di Venere Lake area using the accumulation chamber method. We calculated a CO2 emission of 43± 5 t day−1 for the area studied, accounting for both diffuse degassing from soil and bubbling through the lake.We also present data on the water composition of Specchio di Venere Lake, the Polla 3 spring, and Liuzza well. On the basis of water chemistry, two physical-chemical processes, evaporation and mineral precipitation of carbonate species, are invoked to explain the CO2 degassing for the lake area.
    Description: Published
    Description: id 29
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2020-11-26
    Description: With this study a nine-year hiatus (May 2010-April 2019) in the quantification of the CO2 content of Lago Albano by our working group has been resolved through the acquisition and analysis from two new field campaigns. Based on a CO2 budget analysis the dynamics of CO2 degassing throughout the past thirty years (1989-2019) is detailed and quantified. The decreasing CO2 content (expressed as dissolved inorganic carbon, DIC) in the lake, since the co-seismic CO2 input during the 1989-1990 seismic swarm beneath Colli Albani volcano, was accelerated at lake bottom layers (-140 m to bottom, near -160 m) in the 4-5 years after the swarm, continued afterwards at lower depths (-125 to -95 m), and seems to have reached steady-state conditions during recent years. The peculiar lake basin morphology has control on the degassing dynamics. The low chemical gradients detected during the April 2019 survey have induced near-zero degassing conditions, and arguably stopped the gas-self lifting process: Lago Albano might not become CO2-free in the future. This finding has implications for gas hazard when the next seismic swarm will hit the area. The updated degassing model also takes into account the lake level drop, and hence the volume decrease of Lago Albano, caused by excessive well pumping for anthropic purposes. This volume decrease appears to have a destabilizing effect on the degassing dynamics, which renders Lago Albano’s gas release less predictable in the future. Enhanced gas surveys (high-frequency and fine-scale spatial measurements) are needed to shed light on how Lago Albano degasses in this quiescent stage during the Anthropocene. A submersible infra-red detector to directly measure in-lake dissolved CO2 concentrations, applied satisfactorily during this study, is an adapted instrument to do so.
    Description: In press
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: volcanic lake ; degassing dynamics ; dissolved CO2 ; lake stability ; limnology ; hazard assessment
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2021-03-01
    Description: Between 1994 and 1995, gas samples from fumaroles and thermal waters were collected on Ischia Island. The chemical composition of the shallow and deep natural hydrothermal fluids discharged is related to the main hydrological and lithological characteristics of the rock formations present in the reservoir. A biphase reservoir (liquid 1 gas) is identified, where the dominant liquid has a temperature of about 2808C. On the basis of d 13CTDC values it was possible to hypothesize a deep source characterised by carbon isotopic values varying from 0 to 23d‰. These values are noticeably more positive with respect to those attributed to magmatic CO2 d13CCO2 ranging from 25 to 28d ‰), thus suggesting a magmatic source modified by crustal contamination. This hypothesis is supported by the carbon isotopic composition of CO2 in sampled gases, which varied from 0 to 25d‰. The inferred isotopic value of carbon of magmatic CO2 would then be about 22d‰. The observed differences in C isotopic composition between fumarolic and magmatic gases would be caused by kinetic and/or equilibrium fractionation processes. These processes would cause a fractionation of d 13C of deep CO2 towards more negative values (down to 25‰). Actually, CO2 removal or addition processes caused by the interaction between deep gases and shallow hydrothermal waters are likely to be responsible for the different chemical and isotopic compositions of gaseous emissions. For these reasons, and on the basis of the homogeneity of geothermometric values, the existence of a single, large reservoir that feeds all of the fluids discharged at Ischia Island can be hypothesised. Based on acquired data, a new geochemical model of the geothermal system of Ischia Island is proposed.
    Description: Published
    Description: 151-178
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: gas thermometers; water geothermometer; dissolved gases; geothermal system; Ischia Island ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2021-05-12
    Description: L'Istituto Nazionale di Geofisica e Vulcanologia (INGV) è componente del Servizio Nazionale di Protezione Civile, ex articolo 6 della legge 24 febbraio 1992 n. 225 ed è Centro di Competenza per i fenomeni sismici, vulcanici e i maremoti per il Dipartimento della Protezione Civile Nazionale (DPC). L’Osservatorio Vesuviano, Sezione di Napoli dell’INGV, ha nei suoi compiti il monitoraggio e la sorveglianza H24/7 delle aree vulcaniche attive campane (Vesuvio, Campi Flegrei e Ischia). Tali attività sono disciplinate dall’Accordo-Quadro (AQ) sottoscritto tra il DPC e l’INGV per il decennio 2012-2021 e sono dettagliate negli Allegati A e B del suddetto AQ. Il presente Rapporto sul Monitoraggio dei Vulcani Campani rappresenta l’attività svolta dall’Osservatorio Vesuviano e dalle altre Sezioni INGV impegnate nel monitoraggio dell’area vulcanica campana nel primo semestre 2019.
    Description: Istituto Nazionale di Geofisica e Vulcanologia
    Description: Unpublished
    Description: 4V. Processi pre-eruttivi
    Description: 6SR VULCANI – Servizi e ricerca per la società
    Description: 1IT. Reti di monitoraggio e sorveglianza
    Keywords: Campi Flegrei ; Vesuvio ; Ischia ; Volcano Monitoring ; 04.06. Seismology ; 04.03. Geodesy ; 04.08. Volcanology ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 8
    Publication Date: 2021-06-22
    Description: Geochemical behaviour of rare earth elements (REE), Zr, andHfwas investigated in CO2-richwaters circulating in Pantelleria Island also including ‘Specchio di Venere’ Lakewithin a calderic depression. A wide range of total dissolved REE concentrationswas found (2.77–12.07 nmol L−1),with the highest contents in the lake. Themain REE complexes in the CO2-rich waters are [REE(CO3)2]− and [REECO3]+, showing changeable proportions as a function of pH. The REE normalized to post-Archean Australian Shale (PAAS) showed similar features with heavy REE (HREE) enrichments in CO2-rich waters collected from springs and wells, whereas a different REE pattern was found in the ‘Specchio di Venere’ Lake water with middle REE (MREE) enrichments. The PAAS normalized concentration ratios (LREE/HREE)N and (MREE/HREE)N in waters are b1, except for the lake water in which (MREE/HREE)N N 1. Positive Eu anomalies were found in the investigated waters owing to water–rock interactions with less evolved host rocks. Ce anomalies as a function of Eh values were recognized, with the highest Ce anomaly occurring in the lake water with respect to the CO2-rich waters. The Y/Ho and Zr/Hf molar ratios are higher in the investigated waters (except for lake water) than that in the local rocks, with values ranging from 35.4 to 77.9 and from 76.3 to 299, respectively. The precipitation of authigenic phases was considered to be responsible for the increase in the Y/Ho and Zr/Hf ratios owing to enhanced Hf and Ho removal with respect to Zr and Y. The REE patterns in the lake water show a similar shape (MREE-enriched and a positive Ce anomaly) as those found in the settling dust and in the desert varnish coating of the rocks in arid environments,which mainly contain Fe- and Mn-oxyhydroxides and clay minerals. Similarly, Y/Ho and Zr/Hf ratios in the ‘Specchio di Venere’ Lake (35.4 and 76.3, respectively) show a desert varnish signature. These data, coupled with the presence of iron oxyhydroxides and phyllosilicates in the shallowest water layer of the ‘Specchio di Venere’ Lake, verify the aeolian input from the Sahara Desert
    Description: Published
    Description: 1-11
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Rare earth elements ; Zirconium ; Hafnium ; CO2-rich waters ; Lake ; Aeolian input ; 05.09
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2020-02-18
    Description: Total CO2 output from fumaroles, bubbling and water dissolved gases and soil gases was investigated at Pantelleria Island volcano, Italy. The preliminary results indicate an overall output of 0.39 Mt a−1 of CO2 from the island. The main contribution to the total output was from diffuse soil degassing (about 0.32 Mt a−1), followed by dissolved CO2 (0.034 Mt a−1), focussed soil degassing (0.028 Mt a−1) and bubbling CO2 (0.013 Mt a−1). The contribution of CO2 from fumarole gases was found to be negligible (1.4×10−6 Mt a−1). Carbon-13 values for CO2 coupled with those for associated He in gases from fumaroles and sites of focussed soil degassing clearly rule out any significant organic CO2 component and suggest a common mantle origin for these gas species. The inferred mantle source beneath Pantelleria would seem to have peculiar geochemical characteristics, quite distinct from those of mantle producing MORB but compatible with those of magmatic sources of central Mediterranean and central European volcanoes. These findings indicate that the Pantelleria volcanic complex is a site of active mantle degassing that is worthy of attention for future geochemical surveillance of the island.
    Description: Published
    Description: 883-894
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: 05.09
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2018-04-24
    Description: The aim of this study was to obtain information on the presence and levels of hazardous organic pollutants in groundwater located close to solid waste landfills. Eighty-two environmental contaminants, including 16 polycyclic aromatic hydrocarbons (PAHs), 20 volatile organic compounds (VOCs), 29 polychlorinated biphenyls (PCBs), 7 dioxins (polychlorinated dibenzo-p-dioxins, PCDDs) and 10 furans (polychlorinated dibenzofurans, PCDFs) were monitored in areas characterised by different geological environments surrounding three municipal solid waste landfills (Palermo, Siculiana and Ragusa) in Sicily (Italy) in three sampling campaigns. The total concentrations of the 16 PAHs were always below the legal threshold. Overall, the Fl/Fl + Py diagnostic ratio revealed that PAHs had a petrogenic origin. VOC levels, except for two notable exceptions near Palermo landfill, were always below the legal limit. As concerns PCB levels, several samples were found positive with levels exceeding the legal limits. It is worth noting that the % PCB distribution differs from that of commercial compositions. In parallel, some samples of groundwater containing PCDDs and PCDFs exceeding the legal threshold were also found. Among the 17 congeners monitored, the most abundant were the highest molecular weight ones.
    Description: Published
    Description: 16869 – 16882
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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