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  • 1
    In: Chemical geology, Amsterdam [u.a.] : Elsevier, 1966, 254(2008), 1/2, Seite 19-35, 0009-2541
    In: volume:254
    In: year:2008
    In: number:1/2
    In: pages:19-35
    Type of Medium: Online Resource
    Pages: graph. Darst
    ISSN: 0009-2541
    Language: English
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  • 2
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    PANGAEA
    In:  Supplement to: Boschi, Chiara; Dini, Andrea; Frueh-Green, Gretchen L; Kelley, Deborah S (2008): Isotopic and element exchange during serpentinization and metasomatism at the Atlantis Massif (MAR 30°N): Insights from B and Sr isotope data. Geochimica et Cosmochimica Acta, 72(7), 1801-1823, https://doi.org/10.1016/j.gca.2008.01.013
    Publication Date: 2023-05-12
    Description: The Lost City hydrothermal system at the southern Atlantis Massif (Mid-Atlantic Ridge, 30°N) provides a natural laboratory for studying serpentinization processes, the temporal evolution of ultramafic-hosted hydrothermal systems, and alteration conditions during formation and emplacement of an oceanic core complex. Here we present B, O, and Sr isotope data to investigate fluid/rock interaction and mass transfer during detachment faulting and exhumation of lithospheric sequences within the Atlantis Massif. Our data indicate that extensive serpentinization was a seawater-dominated process that occurred predominately at temperatures of 150-250 °C and at high integrated W/R ratios that led to a marked boron enrichment (34-91 ppm). Boron removal from seawater during serpentinization is positively correlated with changes in d11B (11-16 per mil) but shows no correlation with O-isotope composition. Modeling indicates that B concentrations and isotope values of the serpentinites are controlled by transient temperature-pH conditions. In contrast to prior studies, we conclude that low-temperature marine weathering processes are insignificant for boron geochemistry of the Atlantis Massif serpentinites. Talc- and amphibole-rich fault rocks formed within a zone of detachment faulting at temperatures of approximately 270-350 °C and at low W/R ratios. Talc formation in ultramafic domains in the massif was subsequent to an early stage of serpentinization and was controlled by the access of Si-rich fluids derived through seawater-gabbro interactions. Replacement of serpentine by talc resulted in boron loss and significant lowering of d11B values (9-10 per mil), which we model as the product of progressive extraction of boron. Our study provides new constraints on the boron geochemical cycle at oceanic spreading ridges and suggests that serpentinization associated with ultramafic-hosted hydrothermal systems may have important implications for the behavior of boron in subduction zone settings.
    Keywords: ALV-3639; ALV-3642; ALV-3645; ALV-3646; ALV-3647; ALV-3648; ALV-3649; ALV-3651; ALV-3652; ALV-3863; ALV-3865; ALV-3867; ALV-3872; ALV-3873; ALV-3876; ALV-3877; ALV-3880; ALV-3881; ALVIN; AT03-60; AT03-60_D3; AT03-60_D4; AT07-34; Atlantis (1997); Dredge; DRG; Marvel; North Atlantic; Submersible Alvin
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 3
    Publication Date: 2023-05-12
    Keywords: Depth, bathymetric; DEPTH, sediment/rock; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; LATITUDE; LONGITUDE; Neodymium; Ratio; Rock type; Sample code/label; Strontium; Strontium-87/Strontium-86 ratio; Strontium isotope exchange; ε-Neodymium
    Type: Dataset
    Format: text/tab-separated-values, 306 data points
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  • 4
    Publication Date: 2023-05-12
    Keywords: ALV-3639; ALV-3642; ALV-3645; ALV-3646; ALV-3647; ALV-3648; ALV-3651; ALV-3652; ALV-3873; ALV-3881; ALVIN; AT03-60; AT07-34; Atlantis (1997); Boron; Boron-11/Boron-10 ratio; Boron-11/Boron-10 ratio, standard deviation; Depth, bathymetric; DEPTH, sediment/rock; Event label; LATITUDE; LONGITUDE; Marvel; Multicollector mass spectrometry; North Atlantic; Positive-ion thermal-ionization mass spectrometry; Rock type; Sample code/label; Strontium-87/Strontium-86 ratio; Strontium-87/Strontium-86 ratio, error; Submersible Alvin; δ11B; δ11B, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 160 data points
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  • 5
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    PANGAEA
    In:  Supplement to: Delacour, Adelie; Frueh-Green, Gretchen L; Frank, Martin; Gutjahr, Marcus; Kelley, Deborah S (2008): Sr- and Nd-isotope geochemistry of the Atlantis Massif (30°N, MAR): Implications for fluid fluxes and lithospheric heterogeneity. Chemical Geology, 254(1-2), 19-35, https://doi.org/10.1016/j.chemgeo.2008.05.018
    Publication Date: 2023-06-27
    Description: The Atlantis Massif (Mid-Atlantic Ridge, 30°N) is an oceanic core complex marked by distinct variations in crustal architecture, deformation and metamorphism over distances of at least 5 km. We report Sr and Nd isotope data and Rare Earth Element (REE) concentrations of gabbroic and ultramafic rocks drilled at the central dome (IODP Hole 1309D) and recovered by submersible from the southern ridge of the massif that underlie the peridotite-hosted Lost City Hydrothermal Field. Systematic variations between the two areas document variations in seawater penetration and degree of fluid-rock interaction during uplift and emplacement of the massif and hydrothermal activity associated with the formation of Lost City. Homogeneous Sr and Nd isotope compositions of the gabbroic rocks from the two areas (87Sr/86Sr: 0.70261-0.70429 and epsilon-Nd: +9.1 to +12.1) indicate an origin from a depleted mantle. At the central dome, serpentinized peridotites are rare and show elevated seawater-like Sr isotope compositions related to serpentinization at shallow crustal levels, whereas unaltered mantle isotopic compositions preserved in the gabbroic rocks attest to limited seawater interaction at depth. This portion of the massif remained relatively unaffected by Lost City hydrothermal activity. In contrast, pervasive alteration and seawater-like Sr and Nd isotope compositions of serpentinites at the southern wall (87Sr/86Sr: 0.70885-0.70918; epsilon-Nd: -4.7 to +11.3) indicate very high fluid-rock ratios (~20 and up to 10**6) and enhanced fluid fluxes during hydrothermal circulation. Our studies show that Nd isotopes are most sensitive to high fluid fluxes and are thus an important geochemical tracer for quantification of water-rock ratios in hydrothermal systems. Our results suggest that high fluxes and long-lived serpentinization processes may be critical to the formation of Lost City-type systems and that normal faulting and mass wasting in the south facilitate seawater penetration necessary to sustain hydrothermal activity.
    Keywords: 304-U1309B; 304-U1309D; 305-U1309D; DRILL; Drilling/drill rig; Exp304; Exp305; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Joides Resolution; Oceanic Core Complex Formation, Atlantis Massive 1; Oceanic Core Complex Formation, Atlantis Massive 2
    Type: Dataset
    Format: application/zip, 5 datasets
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  • 6
    Publication Date: 2023-06-27
    Keywords: 304-U1309B; 304-U1309D; Alteration; Calculated; Carbon, inorganic, total; Carbon, organic, total; Carbon, total; Coulometric titration; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Event label; Exp304; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Isotope ratio mass spectrometry; Joides Resolution; Oceanic Core Complex Formation, Atlantis Massive 1; Rock type; Sample code/label; δ13C, organic carbon; δ13C, total inorganic carbon
    Type: Dataset
    Format: text/tab-separated-values, 126 data points
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  • 7
    Publication Date: 2023-06-27
    Keywords: 305-U1309D; Alteration; Calculated; Carbon, inorganic, total; Carbon, organic, total; Carbon, total; Coulometric titration; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Exp305; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Isotope ratio mass spectrometry; Joides Resolution; Oceanic Core Complex Formation, Atlantis Massive 2; Rock type; Sample code/label; δ13C, organic carbon; δ13C, total inorganic carbon
    Type: Dataset
    Format: text/tab-separated-values, 279 data points
    Location Call Number Limitation Availability
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  • 8
    Publication Date: 2023-06-27
    Keywords: 304-U1309B; 304-U1309D; 305-U1309D; Alteration; Calcium carbonate; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; Exp304; Exp305; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Joides Resolution; Neodymium; Neodymium-143/Neodymium-144 ratio; Neodymium-143/Neodymium-144 ratio, error; Oceanic Core Complex Formation, Atlantis Massive 1; Oceanic Core Complex Formation, Atlantis Massive 2; Piece; Rock type; Sample code/label; Strontium; Strontium-87/Strontium-86 ratio; Strontium-87/Strontium-86 ratio, error; ε-Neodymium; ε-Neodymium, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 244 data points
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  • 9
    Publication Date: 2023-06-27
    Keywords: 304-U1309B; 304-U1309D; 305-U1309D; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; Exp304; Exp305; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Joides Resolution; Neodymium; Oceanic Core Complex Formation, Atlantis Massive 1; Oceanic Core Complex Formation, Atlantis Massive 2; Ratio; Rock type; Sample code/label; Strontium; Strontium-87/Strontium-86 ratio; Strontium isotope exchange; ε-Neodymium
    Type: Dataset
    Format: text/tab-separated-values, 54 data points
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  • 10
    Publication Date: 2023-05-12
    Keywords: Calcium carbonate; Depth, bathymetric; DEPTH, sediment/rock; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; LATITUDE; LONGITUDE; Neodymium; Neodymium-143/Neodymium-144 ratio; Neodymium-143/Neodymium-144 ratio, error; Rock type; Sample code/label; Strontium; Strontium-87/Strontium-86 ratio; Strontium-87/Strontium-86 ratio, error; ε-Neodymium; ε-Neodymium, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 370 data points
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