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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 84 (1980), S. 2888-2890 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 86 (1982), S. 1895-1898 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 88 (1984), S. 3877-3880 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 464-469 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have measured the total light scattered from a mixture of deuterated isobutyric acid and heavy water (deuterium oxide, D2O ) near its upper critical solution point. The resulting turbidity was measured in a reduced temperature region 10−6〈t〈10−2, where t=(T−Tc)/Tc and Tc is the critical solution temperature, in a sample close to the critical composition. This completely deuterated mixture near its critical point exhibits similar properties to the undeuterated mixture and the turbidity can be explained using an Ising model. When the critical exponents ν and γ were fixed at the values predicted from renormalization-group theory, the amplitude ξ0 of the correlation length was determined to be 0.343±0.024 nm, while the amplitude of the turbidity τ0 was (3.51±0.03)×10−6 cm−1, which seem consistent with two-scale-factor universality predictions.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 9476-9479 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A hyperthermal beam of state-selected NO+ X Σ+(v=0–6) ions is scattered on a clean, well-characterized GaAs(110) surface. The threshold for the appearance of scattered O− ions occurs at a collision energy of 25 eV. Vibrational energy proves to be an order of magnitude more effective than translational energy in enhancing the yield in this channel.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 3196-3207 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A model is presented to describe the dynamical processes of trapping/desorption as well as direct and indirect inelastic scattering on single-crystal surfaces. Newton's equations of motion are integrated for a system consisting of a rigid rotor interacting with a slab of 19 surface atoms. The surface atom which is closest to the center of mass of the molecule is permitted to translate only along the surface normal. In turn, this mobile surface atom is harmonically coupled to a microcanonical heat bath consisting of three subsurface atoms. This method is much less computationally intensive than the typical generalized Langevin equation (GLE) approach. Direct comparison is made between the predictions of this model and experiment for the NO/Pt(111) system. In the case of trapping/desorption, the model accurately describes the observed dependence of rotational alignment on rotational quantum number. For the inelastic scattering regime, the model successfully reproduces the degree of rotational excitation and qualitatively accounts for the observed rotational alignment. In addition, the model predicts correlations between final state velocity and final state rotational angular momentum (both direction and magnitude), as well as the effect of molecular orientation and surface impact parameter on the overall trapping probability.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 3182-3195 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Rotationally resolved experiments on the NO/Pt(111) system explore the mechanisms of inelastic scattering and trapping/desorption. The rotational dynamics associated with these two regimes are markedly different. A neat supersonic NO beam is scattered at normal incidence from a Pt(111) crystal at 375–475 K. The non-Boltzmann rotational population distribution of the scattered species exhibits considerable rotational excitation beyond the energy available from the incident beam. Thus, a surface vibration to rotational energy transfer mechanism must be operative. The accompanying rotational alignment data reveal that highly excited rotational states exhibit predominantly "cartwheel'' motion. In contrast, rotationally excited molecules that desorb from a 553 K Pt(111) surface show a preference for "helicopter'' motion. The opposite preferences for rotational alignment in the two dynamical regimes provide insight into the anisotropy of molecule–surface interactions.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 560-563 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: An empirical observation is made of an apparent universal shift in the consolute point (Xc=critical composition, Tc=critical temperature) of binary fluid mixtures when the system identity is perturbed. The shift in a "pure'' system's critical point (Xco, Tco) when perturbed becomes (Xc,Tc) which seems to obey (Tc−Tco)/Tco= (Xc−Xco)/Xco. This relation has been observed to hold in a wide range of systems including closed-loop coexistence curves (guaiacol–glycerol–water, or tertiary butyl alcohol in secondary butyl alcohol and water), deuterated systems (methanol–cyclohexane, or isobutyric acid–water), impurities added to methanol–cyclohexane, the molecular weight dependence in polystyrene–methylcyclohexane, and the pressure dependence of methanol–cyclohexane.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 63 (1992), S. 1969-1972 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The design and performance of a novel ion detector is described. The detector produces a two-dimensional image which displays the time-of-flight distribution of a pulsed packet of ions. Pulse sequencing within the detector allows for simultaneous mass and velocity resolution of the detected ions. The image capturing hardware combines long-term signal integration with single-ion detection in order to provide a wide dynamic range in ion sensitivity.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 28 (1989), S. 1650-1655 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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