Note: Front Cover -- Guide to Trivial Names, Trade Names and Synonyms for Substances Used in Analytical Nomenclature -- CHAPTER 1. ANALYTICAL CHEMISTRY DIVISION COMMISSION ON ANALYTICAL NOMENCLATURE -- INTRODUCTION.

Note: Front Cover -- The Gaseous State -- Copyright Page -- Table of Contents -- PREFACE -- GENERAL PHYSICAL CONSTANTS AND CONVERSION FACTORS -- INTRODUCTION -- CHAPTER 1. THE PERFECT GAS EQUATION -- DERIVATION OF THE EQUATION -- DALTON'S LAW OF PARTIAL PRESSURES -- THE ROOT-MEAN-SQUARE (R.M.S.) SPEED -- PROBLEMS -- CHAPTER 2. GAS IMPERFECTION -- THE TWO-PHASE REGION -- THE JOULE-THOMSON EFFECT -- DIETERICTS EQUATION -- THE VIRIAL EQUATION -- THE THEOREM OF CORRESPONDING STATES -- PROBLEMS -- CHAPTER 3. DISTRIBUTION OF VELOCITIES -- DIRECT TEST OF MAXWELL'S DISTRIBUTION LAW -- EQUIPARTITION OF ENERGY -- PROBLEMS -- CHAPTER 4. COLLISIONS -- COLLISIONS WITH THE WALL -- EFFUSION AND KNUDSEN'S METHOD -- THERMAL TRANSPIRATION -- THE DISTRIBUTION OF SPEEDS AMONG MOLECULES COLLIDING WITH THE WALL -- COLLISIONS BETWEEN MOLECULES -- MAXWELL'S MEAN FREE PATH -- DISTRIBUTION OF RELATIVE KINETIC ENERGY IN COLLISIONS -- PROBLEMS -- CHAPTER 5. VISCOSITY -- CORRECTION FOR THE PERSISTENCE OF VELOCITIES -- THE MEASUREMENT OF VISCOSITY -- PROBLEMS -- CHAPTER 6. THERMAL CONDUCTIVITY -- THE MEASUREMENT OF THERMAL CONDUCTIVITY -- PROBLEMS -- CHAPTER 7. DIFFUSION -- SELF-DIFFUSION -- MUTUAL DIFFUSION -- THE MEASUREMENT OF SELF-DIFFUSION COEFFICIENTS -- THE MEASUREMENT OF MUTUAL DIFFUSION COEFFICIENTS -- PROBLEMS -- CHAPTER 8. THERMAL DIFFUSION -- EXPERIMENTAL TECHNIQUES -- THE CLUSIUS AND DICKEL COLUMN -- PROBLEMS -- CHAPTER 9. BROWNIAN MOVEMENT AND THE DETERMINATION OF AVOGADRO'S NUMBER -- PERRIN'S BROWNIAN STUDIES -- FLETCHER AND MILLIKAN'S OIL-DROP METHOD -- METHODS BASED ON RADIOACTIVITY -- THE CRYSTALLOGRAPHIC METHOD -- MODERN METHODS -- PROBLEMS -- CHAPTER 10. ENERGY TRANSFER -- RELAXATION TIME AND THE PROBABILITY OF DEACTIVATION -- ROTATIONAL-TRANSLATIONAL RELAXATION -- PROBLEMS -- APPENDIX 1: SOME DEFINITE INTEGRALS -- APPENDIX 2: AVERAGING. , APPENDIX 3: VAN DER WAALS' b -- APPENDIX 4: THE METHOD OF UNDETERMINED MULTIPLIERS -- REFERENCES -- ANSWERS -- NAME INDEX -- SUBJECT INDEX.

Note: Front Cover -- Reaction Kinetics: Homogeneous Gas Reactions -- Copyright Page -- Table of Contents -- PREFACE -- A NOTE TO THE STUDENT -- CHAPTER 1. BASIC KINETIC LAWS -- RATE OF REACTION -- ANALYSIS OF KINETIC RESULTS -- METHOD OF INTEGRATION -- DIFFERENTIAL METHOD -- COMPARISON OF METHODS -- REACTIONS HAVING NO SIMPLE ORDER -- OPPOSING REACTIONS -- CONSECUTIVE REACTIONS -- REACTIONS IN FLOW SYSTEMS -- THE MEASUREMENT OF REACTION RATES -- PROBLEMS -- CHAPTER 2. MOLECULAR KINETICS -- THE ARRHENIUS LAW -- POTENTIAL-ENERGY SURFACES -- THE KINETIC THEORY OF COLLISIONS -- STATISTICAL MECHANICS OF CHEMICAL EQUILIBRIUM -- THE THEORY OF ABSOLUTE REACTION RATES -- THE THERMODYNAMICAL FORMULATION OF REACTION RATES -- KINETIC ISOTOPE EFFECTS -- PROBLEMS -- CHAPTER 3. ELEMENTARY GAS REACTIONS -- BIMOLECULAR REACTIONS -- TERMOLECULAR REACTIONS -- UNIMOLECULAR REACTIONS -- RECOMBINATION AND DISPROPORTIONATION -- GAS-PHASE REACTIONS INVOLVING IONS -- PROBLEMS -- CHAPTER 4. COMPLEX GAS REACTIONS -- DETECTION AND ESTIMATION OF ATOMS AND RADICALS IN REACTION SYSTEMS -- THE STEADY-STATE TREATMENT -- SOME INORGANIC REACTIONS -- ORGANIC DECOMPOSITIONS -- GAS PHASE AUTOXIDATIONS -- POLYMERIZATION REACTIONS -- PROBLEMS -- APPENDIX 1: CORRELATION, AND THE METHOD OF LEAST SQUARES -- THE METHOD OF LEAST SQUARES -- APPENDIX 2: NUMERICAL VALUES -- BIBLIOGRAPHY -- NAME INDEX -- SUBJECT INDEX.

Note: Front Cover -- Compendium of Analytical Nomenclature: Definitive Rules 1977 -- Copyright Page -- Table of Contents -- Chapter 0. PREAMBLE -- 0.1 Sources of the material incorporated in the compendium -- 0.2 General principles of nomenclature standardization -- 0.3 Physical quantities : ways of naming physical quantities -- 0.4 Scope and treatment of the present compendium -- Chapter 1. RECOMMENDATIONS FOR THE PRESENTATION OF THE RESULTS OF CHEMICAL ANALYSIS -- 1.1 Introduction -- 1.2 General terms -- 1.3 Reliability of results -- 1.4 Expression of results -- 1.5 Symbols -- 1.6 Methods of computation -- 1.7 Appendix -- Chapter 2. RECOMMENDATIONS FOR TERMINOLOGY TO BE USED WITH PRECISION BALANCES -- 2.1 Introduction -- 2.2 Terminology -- 2.3 Glossary of terms -- Chapter 3. RECOMMENDED NOMENCLATURE FOR SCALES OF WORKING IN ANALYSIS -- 3.1 Introduction -- 3.2 Sample weight classification (s) -- 3.3 Constituent content classification (c) -- Chapter 4. RECOMMENDATIONS ON NOMENCLATURE FOR CONTAMINATION PHENOMENA IN PRECIPITATION FROM AQUEOUS SOLUTION -- 4.1 Introduction -- 4.2 Definitions -- Chapter 5. RECOMMENDED NOMENCLATURE FOR AUTOMATIC ANALYSIS -- 5.1 Introduction -- 5.2 Recommended terminology -- Chapter 6. RECOMMENDATIONS FOR NOMENCLATURE OF THERMAL ANALYSIS -- 6.1 General recommendations -- 6.2 Terminology -- 6.3 Definitions and conventions -- Chapter 7. RECOMMENDATIONS FOR NOMENCLATURE OF MASS SPECTROMETRY -- Chapter 8. RECOMMENDED NOMENCLATURE FOR TITRIMETRIC ANALYSIS -- Chapter 9. REPORT ON THE STANDARDIZATION OF pH AND RELATED TECHNOLOGY -- 9.1 Introduction -- 9.2 Symbols -- 9.3 Operational definition of pH -- 9.4 Standards for measurement of pH -- 9.5 Ionic activity coefficients -- 9.6 pH of standard solutions -- 9.7 Approximate interpretation of pH -- 9.8 The abbreviation pαH. , Chapter 10. PRACTICAL MEASUREMENT OF pH IN AMPHIPROTIC AND MIXED SOLVENTS -- 10.1 Introduction -- 10.2 The operational pH scale -- 10.3 Interpretation of the measured pH -- 10.4 Extension to other,solvents -- 10.5 Selection of a pH unit for amphiprotic solvents -- 10.6 Operational pH scale for amphiprotic solvents -- 10.7 Reference solutions for values of pH amphiprotic solvents -- 10.8 Accuracy of practical scales -- Chapter 11. RECOMMENDED SYMBOLS FOR SOLUTION EQUILIBRIA -- 11.1 Introduction -- 11.2 General rules -- 11.3 Complex formation equilibria -- 11.4 Solubility equilibria -- 11.5 Liquid-liquid distribution equilibria -- Chapter 12. RECOMMENDED NOMENCLATURE FOR LIQUID-LIQUID DISTRIBUTION -- Chapter 13. RECOMMENDATIONS ON NOMENCLATURE AND PRESENTATION OF DATA IN GAS CHROMATOGRAPHY -- 13.1 Introduction -- 13.2 Name of technique -- 13.3 Apparatus -- 13.4 Reagents -- 13.5 Chromatographie records -- 13.6 Retention parameters -- 13.7 Recommendations: retention data -- 13.8 Apparatus performance -- 13.9 Discussion -- 13.10 Table of terms -- Chapter 14. RECOMMENDATIONS ON NOMENCLATURE FOR CHROMATOGRAPHY -- 14.1 Chromatography -- 14.2 Principal methods -- 14.3 Classification according to phases used -- 14.4 Classification according to mechanisms -- 14.5 Classification according to techniques used -- 14.6 Terms for special techniques -- 14.7 Terms relating to the method in general -- 14.8 Terms relating to the separation process and the apparatus -- 14.9 Terms relating to quantitative evaluation and the theory of chromatography -- 14.10 Appendix and list of symbols -- Chapter 15. RECOMMENDATIONS ON ION EXCHANGE NOMENCLATURE -- 15.1 Introduction -- 15.2 Definitions -- Chapter 16. NOMENCLATURE, SYMBOLS, UNITS AND THEIR USAGE IN SPECTROCHEMICAL ANALYSIS-I. GENERAL ATOMIC EMISSION SPECTROSCOPY -- 16.1 Foreword -- 16.2 General recommendations and practices. , 16.3 Terms and symbols for physical quantities in general use -- 16.4 Terms, symbols, and units related to radiant energy -- 16.5 Terms and symbols for the description of spectrographic instruments -- 16.6 Terms and symbols related to the analytical procedures -- 16.7 Terms and symbols related to fundamental processes occurring in light (excitation) sources -- 16.8 Photographic intensity measurements (photographic photometry) -- Appendix: Application of the concept of optical conductance -- Chapter 17. NOMENCLATURE, SYMBOLS, UNITS AND THEIR USAGE IN SPECTROCHEMICAL ANALYSIS - II. DATA INTERPRETATION -- 17.1 Introduction -- 17.2 General concepts -- 17.3 Analytical functions and curves -- 17.4 Terms relating to small concentrations -- 17.5 Glossary of terms and symbols used -- Chapter 18. NOMENCLATURE, SYMBOLS, UNITS AND THEIR USAGE IN SPECTROCHEMICAL ANALYSIS - III . ANALYTICAL FLAME SPECTROSCOPY AND ASSOCIATED NON-FLAME PROCEDURES -- 18.1 Introduction -- 18.2 Terms and symbols for general quantities and constants -- 18.3 Terms, symbols, and units for the description of the analytical apparatus -- 18.4 Terms and symbols relating to the analytical procedure and the performance of an analysis -- 18.5 Terms, symbols, and units relating to radiant energy, and its interaction with matter -- 18.6 Terms, symbols, and units relating to the gaseous state of matter -- 18.7 Index of terms† -- Chapter 19. CLASSIFICATION AND NOMENCLATURE OF ELECTROANALYTICAL TECHNIQUES -- 19.1 Introduction -- 19.2 Techniques in which neither the electrical double layer nor any electrode reaction need be considered -- 19.3 Techniques that involve double-layer phenomena but in which any electrode reactions need not be considered -- 19.4 Techniques involving electrode reactions and employing constant excitation signals. , 19.5 Techniques involving electrode reactions and variable excitation signals of large amplitude -- 19.6 Techniques involving electrode reactions and variable excitation signals of small amplitude -- 19.7 Index to Tables 19.2 - 19.6 -- Chapter 20. RECOMMENDATIONS FOR SIGN CONVENTIONS AND PLOTTING OF ELECTROCHEMICAL DATA -- Chapter 21. RECOMMENDATIONS FOR NOMENCLATURE OF ION-SELECTIVE ELECTRODES -- 21.1 General recommendations -- 21.2 Classification of ion -selective electrodes -- 21.3 Constants and symbols -- APPENDIX: RECOMMENDATIONS ON THE USAGE OF THE TERMS 'EQUIVALENT' AND 'NORMAL' -- INDEX.

Note: Front Cover -- An Approach to Chemical Analysis: Its Development and Practice -- Copyright Page -- Table of Contents -- AUTHOR'S PREFACE -- PART I -- CHAPTER1. THE EARLY HISTORY OF CHEMICAL ANALYSIS -- REFERENCES -- CHAPTER 2. CLASSICAL" ANALYSIS AND THE IMPACT OF PHYSICAL CHEMISTRY -- THE ROLE OF PHYSICAL CHEMISTRY-FROM 1870 ONWARDS -- PHYSICAL CHEMISTRY AND COMPLEX IONS -- PHYSICAL CHEMISTRY AND THE PHENOMENA OF PRECIPITATION -- REFERENCES -- CHAPTER 3. THE FIRST ORGANIC REAGENTS -- α-NITROSO-β-NAPHTHOL -- DIMETHYLGLYOXIME -- CUPFERRON -- REFERENCES -- CHAPTER 4. ORGANIC ANALYSIS -- GENERAL ORGANIC ANALYSIS -- ORGANIC ANALYSIS IN IMPORTANT INDUSTRIES -- REFERENCES -- CHAPTER 5. LARGE-SCALE INDUSTRY AND VOLUMETRIC ANALYSIS -- THE GROWTH OF VOLUMETRIC ANALYSIS -- REFERENCES -- CHAPTER 6. THE MODERN APPROACH TO CHEMICAL ANALYSIS -- LATER DEVELOPMENTS IN INORGANIC CHEMICAL ANALYSIS -- SPECTROPHOTOMETRY OF DITHIZONE SOLUTIONS -- pH VALUE AND THE APPARENT CO-EFFICIENT OF EXTRACTION -- EXAMPLES OF THE USE OF DITHIZONE -- OTHER NEW REAGENTS -- REFERENCES -- CHAPTER 7. ORGANIC MICRO-ANALYSIS -- QUANTITATIVE MICRO-ANALYSIS -- DETERMINATION OF OXYGEN -- FURTHER ADVANCES IN MICRO-ANALYSIS -- REFERENCES -- CHAPTER 8. USE OF NON-AQUEOUS SOLVENTS IN ANALYSIS -- 1. AS TITRATION MEDIUM -- 2. USE OF NON-AQUEOUS SOLVENTS FOR THE EXTRACTION OF METALS -- REFERENCES -- CHAPTER 9. POLAROGRAPHY -- THE BASE SOLUTION -- THE NATURE OF THE ANODE -- USES OF POLAROGRAPHY -- RECENT DEVELOPMENTS OF POLAROGRAPHY -- THE CATHODE RAY POLAROGRAPH -- REFERENCES -- CHAPTER 10. OTHER ELECTROCHEMICAL METHODS -- ELECTRODEPOSITION -- COULOMETRY -- POTENTIOMETRY -- AMPEROMETRIC TITRATION -- THE POLARIZATION END-POINT -- THE " DEAD STOP END-POINT -- CONDUCTIMETRIC TITRATION AND HIGH FREQUENCY TITRATION -- HIGH FREQUENCY TITRATION -- REFERENCES -- PART II: INTRODUCTION. , CHAPTER 11. FRACTIONAL DISTILLATION -- THE CONCEPT OF THE " THEORETICAL PLATE " AND ITS PRACTICAL REALIZATION -- REFERENCES -- CHAPTER 12. CHROMATOGRAPHY -- LIQUID-SOLID CHROMATOGRAPHY -- PARTITION LIQUID-LIQUID CHROMATOGRAPHY -- GAS CHROMATOGRAPHY -- REFERENCES -- CHAPTER 13. ABSORPTIOMETRY AND "COLORIMETRIC ANALYSIS -- INTRODUCTION -- VALIDITY OF LAMBERT-BEER LAWS -- ACCURACY OF ABSORPTIOMETRY -- INSTRUMENTATION -- ULTRA-VIOLET ANALYSIS -- USES OF ULTRA-VIOLET SPECTROPHOTOMETRY -- NON-DISPERSIVE INFRA-RED GAS ANALYSIS -- FLUORIMETRIC ANALYSIS -- REFERENCES -- CHAPTER 14. EMISSION SPECTROSCOPY -- APPARATUS FOR SPECTROGRAPHY -- PREPARATION AND ANALYSIS OF SAMPLES -- METAL ANALYSIS -- INTERPRETATION OF THE SPECTRA OBTAINED -- FLAME PHOTOMETRY -- REFERENCES -- CHAPTER 15. ATOMIC ABSORPTION SPECTROPHOTOMETRY -- REFERENCES -- CHAPTER 16. APPLICATIONS OF X-RAYS TO CHEMICAL ANALYSIS -- 1. X-RAY ANALYSIS BY ABSORPTION -- 2. X-RAY ANALYSIS BY CRYSTAL DIFFRACTION -- 3. X-RAY FLUORESCENCE ANALYSIS -- REFERENCES -- CHAPTER 17. APPLICATIONS OF RADIOACTIVITY TO CHEMICAL ANALYSIS -- THE NATURE OF RADIOACTIVITY -- METHODS OF MEASURING RADIOACTIVITY -- INSTRUMENTS USED -- THE METHODS OF RADIOACTIVE ANALYSIS -- PRINCIPLES OF NEUTRON ACTIVATION ANALYSIS -- THE COURSE OF THE ANALYSIS -- SUGGESTIONS FOR READING -- REFERENCES -- CHAPTER 18. MASS SPECTROMETRY -- THE MASS SPECTROMETER -- OPERATION -- REFERENCES -- CHAPTER 19. CHEMICAL ANALYSIS -- ART, CRAFT, OR SCIENCE? -- INDEX.

Note: Front Cover -- Some Electricaland Optical Aspects of Molecular Behaviour -- Copyright Page -- Table of Contents -- Some Numerical Constants -- Preface -- CHAPTER 1. An Introduction -- CHAPTER 2. The Refractive Index and theElectric Permittivity -- Polarization and Polarizability -- The Mossotti-Clausius Equation -- The Molar Polarization -- The Molar Refraction -- Polar Compounds -- The Measurement of the Permittivity, έ -- The Debye Equation -- Approximate Dipole Moments Evaluated from Solution Data -- Other Methods of Dipole Moment Determination -- CHAPTER 3. Molecular Dipole Moments -- Ionic Character of Diatomic Molecules -- Other Ionic Molecules -- Vector Character of Dipole Moments -- Group Moments and Molecular Structure -- Intramolecular Rotation -- CHAPTER 4. The Limitations and Extensions of the Simple (Debye) Treatment of the Molar Polarization -- The Dipole Concentration -- The Onsager Equation -- Water and Hydrogen-bonded Liquids -- CHAPTER 5. Dielectric Dispersion and Molecular Behaviour -- Phase Angle and Dielectric Loss -- The Pellat-Debye Equations -- Experimental Study of Dielectric Absorption -- Water -- Polar Solutes in Non-polar Solvents -- Organic Solids -- Ionic and Polar Solids -- CHAPTER 6. Aspects of Molecular Polarizability -- Light Scattering -- Light Scattering and the Molecular Weight of Solutes -- Measurement of Light Scattering by Solutions -- Dissymmetric Light Scattering and Molecular Shape -- Depolarization of Scattered Light -- Anisotropy of the Polarizability -- The Kerr Effect -- The Data and Interpretation of Molecular Anisotropy -- Polarizability and Optical Activity -- The Helical Model -- The Raman Effect -- Summary -- CHAPTER 7Electric Forces Between Molecules -- Ion-Ion -- Ion-Dipole -- Two Rigid Dipoles -- Induced Dipole -- Ion-Induced Dipole -- Dipole-Induced Dipole -- Dispersion (or London) Energy. , Quadrupole Moments -- Repulsion Energy -- Intermolecular Interaction Energies -- Ionic Interaction Energies -- Numerical Answers to Examples -- Index.

Note: Front Cover -- Non-Aqueous Solvents in Inorganic Chemistry -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER I. THE NATURE AND SCOPE OF INORGANIC NON-AQUEOUS SOLVENTS -- CHAPTER II. LIQUID AMMONIA -- Solubilities in Liquid Ammonia -- Ammonolysis -- Metals in Liquid Ammonia -- Further Reading -- CHAPTER III. REACTIONS IN LIQUID AMMONIA -- 1. Reactions of Metal-Ammonia Solutions -- 2. Oxidation Reactions -- 3. Metathetic Reactions -- 4. Titrations in Liquid Ammonia -- 5. Anhydrous Amines as Solvents -- 6. Titrations in Anhydrous Basic Solvents -- Further Reading -- CHAPTER IV. PROTONIC SOLVENTS -- Levelling Action -- Sulphuric Acid -- Hydrogen Fluoride -- Acetic Acid -- Further Reading -- CHAPTER V. NON-PROTONIC SOLVENTS -- Bromine Trifluoride -- Sulphur Dioxide -- Dinitrogen Tetroxide -- Phosphorus Oxychloride -- Noble Gas Compounds as Ionizing Solvents -- Further Reading -- CHAPTER VI. HIGH TEMPERATURE SOLVENTS -- Experimental Methods -- The Structure of Fused Salts and Oxides -- Solutions of Elements in Fused Salts -- Reactions in Fused Salts -- Further Reading -- INDEX.

Note: Front Cover -- Reaction Kinetics: Reactions in Solution -- Copyright Page -- Table of Contents -- Preface -- A Note to the Student -- CHAPTER 1. Reactions in Solution: General Principles -- REACTIONS BETWEEN IONS -- REACTIONS INVOLVING DIPOLES -- INFLUENCE OF PRESSURE ON RATES IN SOLUTION (3) -- SUBSTITUENT EFFECTS -- HOMOGENEOUS CATALYSIS IN SOLUTION -- PROBLEMS -- CHAPTER 2. Some Reaction Mechanisms in Solution -- PROTON-TRANSFER REACTIONS -- ELECTRON-TRANSFER REACTI0NS(1) -- ORGANIC SUBSTITUTION REACTIONS(1) -- HYDROLYSIS OF ESTERS -- HALOGENATION OF ACETONE -- THE ALDOL CONDENSATION -- AROMATIC SUBSTITUTION -- IONIC POLYMERIZATION(1) -- PROBLEM -- Appendix I Numerical Values -- Bibliography -- Name Index -- Subject Index.