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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 1910-1912 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Two different reaction mechanisms for Ti50C50 and Ti33B67 have been observed respectively during milling in a planetary ball mill. It is shown that a gradual reaction occurred during milling Ti50C50, while a self-sustained reaction was obtained during milling Ti33B67 under the same milling condition. Compared with the results of milling Ti50C50 in a spex mill, the difference in mechanism is suggested to be caused by the effect of plastic deformation on the changes of fine grains and internal strain during milling, and the different formation heat of TiC and TiB2, which is the driving force for the reactions. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 65 (1994), S. 2666-2668 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Titanium carbide (TiC) has been synthesized by mechanically alloying the elemental powder mixture of titanium and graphite at composition of Ti1−xCx (x=0.35, 0.43, 0.50). Under the employed milling condition, the formation of TiC has been found to undergo an abrupt, exothermic reaction. The final product is TiC for x=0.43 and 0.50, and TiC+Ti (small amount) for x=0.35. It is suggested that this reaction appears to be a self-sustained high-temperature synthesis process. The initial milling stage seems to be an incubation duration for the reaction, and the mechanical impacts to be the ignition of the following abrupt reaction. It is believed that this type of reaction is an important mechanism for mechanical alloying of the highly exothermic alloy systems. © 1994 American Institute of Physics.
    Type of Medium: Electronic Resource
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