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  • 1
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: High temperature chemistry. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (249 pages)
    Edition: 1st ed.
    ISBN: 9781483286730
    DDC: 541.3687
    Language: English
    Note: Front Cover -- High Temperature Phase Equilibria and Phase Diagrams -- Copyright Page -- Table of Contents -- Preface -- CHAPTER 1. Introduction -- CHAPTER 2. The phase rule, phase equilibria and phase diagrams -- 2.1 The Phase Rule -- 2.2 Phase Equilibria and Phase Diagrams -- 2.3 One-component Systems -- 2.4 Two-component Systems Consisting of Condensed Phases -- 2.5 Three-component and Multicomponent Systems Consisting of Condensed Phases Only -- 2.6 Gas Phase Systems -- CHAPTER 3. Experimental techniques -- 3.1 Preparation of Starting Materials -- 3.2 Temperature Measurement and Temperature Calibration -- CHAPTER 4. Mathematical analysis and applications of phase diagrams -- 4.1 Classification and Compilation of High Temperature Phase Diagrams -- 4.2 Co-ordination transformation for compositional points -- 4.3 Phase Boundaries and their Analytical Expression -- 4.4 Representation of Phase diagram by Projection and Section Figures -- 4.5 Applications of Phase Diagrams -- CHAPTER 5. The calculation of phase diagrams -- 5.1 The Development of Phase Diagram Calculation and Calculation Strategy -- 5.2 Data Collection -- 5.3 Mathematical Treatment of Thermodynamic Functions -- 5.4 Calculation of Phase Diagrams -- CHAPTER 6. Phase transition -- 6.1 Polymorphic Transition -- 6.2 Phase Transition in Solid Solutions -- CHAPTER 7. Meta-equilibria and meta-equilibria phase diagrams -- 7.1 Metastable State and Meta-equilibrium Phase Diagrams -- 7.2 Free Energy Relationships in the Metastable Systems -- 7.3 Solid-Liquid Meta-equilibria -- 7.4 Solid-Solid Meta-equilibria -- 7.5 Metastable Liquid Immiscibility -- 7.6 Solid-Gas Meta-equilibria -- 7.7 Meta-equilibria Phase Diagrams and their Calculations -- Index.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dy-α-sialon and β-Si3N4 materials containing Dy-oxynitride glass were hot pressed at 1800°C for 1 h. The luminescence spectra of Dy3+ in these samples were compared when excited at 350 nm. The results showed that two strong emission bands in the region 470–500 nm and 570-600 nm, associated with the 4F9/2→6H15/2 and 4F9/2→6H13/2 transitions of Dy3+ ions, were observed in Dy-α-sialon. However, no emission peak was detected from the β-Si3N4 sample, despite it containing the same amount of Dy3+ cations. This proved that only the Dy3+ cations in the α-sialon structure, not those in the oxynitride glass, produce the luminescence spectrum.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Using monolithic alumina ceramics as the reference, the thermal shock behavior of the hot-pressed alumina matrix ceramics with 3 mol% neodymium titanate was investigated. The thermal shock resistance of the materials was evaluated by water quenching and a subsequent three-point bending test to determine the flexural strength degradation. The hot-pressed composite exhibited a temperature differential of the thermal shock resistance 120°C higher than the monolith, mainly because of significantly improved fracture toughness.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effects of sintering cycles and doping elements on the microstructures of Ln-α-sialon were studied. The results showed that microstructures with an elongated α-sialon morphology could be obtained through high-temperature post-heat treatment (1800–1900°C) or by prolonging soaking times during sintering. Different rare-earth elements had a profound effect on the microstructure of the resulting α-sialon. The Ln-α-sialon doped with low-Z-value elements could easily develop elongated grains with higher aspect ratio.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thick translucent and luminescent Gd–α-sialon ceramic disks (0.7–1.06 mm in thickness) were prepared by hot pressing. The effect of carbon atmosphere on their optical properties during sintering was explored by change packing methods. The results show that the sample with a lower carbon contamination has a higher translucence in the visible band and IR band (450–3500 nm), increasing transmission around 10% even if it is thicker. When excited at 350 nm, Gd–α-sialon with the lower carbon contamination can produce a visible light at 450–500 nm bands, but the luminescence is very weak in the sample containing more carbon contamination. These indicate that carbon contamination causes a severe degradation of the optical properties of α-sialon ceramics, and reduction of carbon contamination of α-sialon ceramics is very important for the optical property improvement.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Two calcium-doped α-SiAlON compositions (Ca0.6Si10.2Al1.8−O0.6N15.4 and Ca1.8Si6.6Al5.4O1.8N14.2) were prepared by hot pressing at 1600° and 1500°C, respectively, for complete phase transformation from α-Si3N4 to α-SiAlON. Both samples were subsequently fired at different temperatures for different periods of time to study the grain growth of α-SiAlON. Elongated α-SiAlON grains were developed in both samples at high temperatures. The kinetics of grain growth was investigated based on the variations in length and width of the α-SiAlON grains under different sintering conditions. Different growth rates were found between the length and width directions of the α-SiAlON crystals, resulting in anisotropic grain growth in the microstructural development.
    Type of Medium: Electronic Resource
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