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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Geostandards and geoanalytical research 29 (2005), S. 0 
    ISSN: 1751-908X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: There is a growing need for new zircon reference materials for in situ Hf-isotope analysis by laser ablation-multicollector inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS). In this contribution we document the results of a preliminary investigation of seven natural zircons, conducted in order to test their suitability in this regard. Solution MC-ICP-MS data on separated Lu and Hf fractions provided reference compositional data while the results of ca. 750 in situ LA-MC-ICP-MS analyses allowed assessment of potential micrometre-scale heterogeneity. On the basis of these analyses and additional relevant considerations such as availability, size and (Lu)Yb/Hf ratio, we suggest that, of the currently available zircons, Temora-2 and Mud Tank are most likely to provide robust reference materials for Hf isotope determinations both at the present time and into the future. The former has the advantage of also being well-characterised for U-Th-Pb systematics and suitable for in situ age determination, while the latter is the most readily available and is of very large grain size. Additional materials such as BR266, and 91500, although limited in supply, show more consistent Lu/Hf ratios and are thus of use in monitoring elemental fractionation during ICP-MS analysis.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Geostandards and geoanalytical research 29 (2005), S. 0 
    ISSN: 1751-908X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The articles that comprise this critical review serve to draw attention to research papers published in specific fields of interest during 2003, provide critical comment on the relevance and importance of individual publications in these fields, and offer an overview of the comparative importance of advances in particular areas. In this way, these articles aim to assist experts in the field by keeping them informed of relevant recent publications, as well as providing an important resource for students or early career researchers who are embarking on studies in an area new to them. This year, five papers provide summaries of developments in bulk sample determinations employing (1) ICP-AES and ICP-MS (trace elements), (2) XRF and atomic absorption spectrometry and INAA, (3) isotope ratio measurements (TIMS, MC-ICP-MS, ICP-MS, ToF), as well as in situ measurements conducted using (4) secondary ion mass spectrometry and (5) laser ablation ICP-MS (trace element and isotope ratio determinations).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Geostandards and geoanalytical research 29 (2005), S. 0 
    ISSN: 1751-908X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: This annual review documents developments and applications in the field of isotope ratio determination, as reflected in the literature for the Earth and environmental sciences for the year 2003. Particular emphasis is placed upon the relationship between the two dominant analytical techniques-thermal ionisation mass spectrometry (TIMS) and multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS)-and the rapidly changing nature of their roles in isotope analysis. Additionally, the review covers developments in single-collector ICP-MS and TOF technologies, new sample preparation procedures and the characterisation of isotopic reference materials, together with fundamental investigations of mass spectrometer performance.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 362 (1993), S. 809-813 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The oxygen isotope compositions of fresh volcanic glasses from submarine volcanoes of 'enriched mantle' (EM-1 and EM-11) type appear to require the presence of subducted crustal components in the source of these lavas. These data confirm earlier inferences from trace elements and radiogenic ...
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 111 (1992), S. 458-467 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Sr-, Nd-isotopic and trace element data are reported for a suite of Marquesan volcanic rocks. These data complement earlier work on the island of Ua Pou and reveal that the marked shifts in source composition between shield-building and post-shield eruptives noted there are common to most islands in the archipelago. In addition, there appears to be a relationship between the magnitude of these shifts and the repose period between shield-building and post-shield activity such that, the longer the period of volcanic inactivity, the larger the isotopic and trace element differences between the two phases of volcanism. This, coupled with the compositional uniformity of the shield-building phase, and its close geochemical similarity to depleted mantle reservoirs, implies a strong lithosperic control on magmatic evolution: models invoking entrainment of asthenospheric material during plume ascent are not readily compatible with the observed time-compositional paths. Comparisons with other oceanic islands reveal two ‘end member’ styles of temporal evolution, herein termed ‘Marquesan’ and ‘Hawaiian’, and attributed to the interaction between the oceanic lithosphere and respectively weak and strong plumes, terms used to denote penetrative capacity and not necessarily size or buoyancy flux. Many other plumes may display characteristics intermediate between these extremes. The state of stress and temperature within the oceanic lithosphere in the region of an ascending diapir is also likely to exert a strong control on the geochemical evolution of OIB suites.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 140 (2000), S. 263-282 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The major and trace element and Pb–Sr–Nd isotopic compositions of Quaternary mafic lavas from the northern Ryukyu arc provide insights into the nature of the mantle wedge and its tectonic evolution. Beneath the volcanic front in the northern part of the arc, the subducted slab of the Philippine Sea Plate bends sharply and steepens at a depth of ∼80 km. Lavas from the volcanic front have high abundances of large ion lithophile elements and light rare earth elements relative to the high field strength elements, consistent with the result of fluid enrichment processes related to dehydration of the subducting slab. New Pb isotopic data identify two distinct asthenospheric domains in the mantle wedge beneath the south Kyushu and northern Ryukyu arc, which, in a parallel with data from the Lau Basin, appear to reflect mantle with affinities to Indian and Pacific-type mid-ocean ridge basalt (MORB). Indian Ocean MORB-type mantle, contaminated with subducted Ryukyu sediments can account for the variation of lavas erupted on south Kyushu, and probably in the middle Okinawa Trough. In contrast, magmas of the northern Ryukyu volcanic front appear to be derived from sources of Pacific MORB-type mantle contaminated with a sedimentary component. Along-arc variation in the northern Ryukyus reflects increasing involvement of a sedimentary component to the south. Compositions of alkalic basalts from the south Kyushu back-arc resemble intraplate-type basalts erupted in NW Kyushu since ∼12 Ma. We propose that the bending of the subducted slab was either caused by or resulted in lateral migration of asthenospheric mantle, yielding Indian Ocean-type characteristics from a mantle upwelling zone beneath NW Kyushu and the East China Sea. This model also accounts for (1) extensional counter-clockwise crustal rotation (∼4–2 Ma), (2) voluminous andesite volcanism (∼2 Ma), and (3) the recent distinctive felsic magmatism in the south Kyushu region.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 113 (1993), S. 479-491 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract New Pb-, Sr-, and Nd-isotopic data have been obtained for the rocks of volcanoes overlying a wide range of depths (100–580 km) to the Wadati-Benioff Zone (WBZ) in the New Britain island arc, Papua New Guinea. Well-defined trends consistent with two-component mixing are observed in combined Pb-isotope/trace-element plots. One of the components is believed to represent a slab contribution whose isotopic signature, unlike those noted for several other arcs, appears to be dominated by subducted, altered, oceanic crust rather than by sediment. This conclusion is consistent with the results of a recent Be−B study of New Britain rocks. The influence of the slab component is considered to decrease as depth to the WBZ increases. Higher abundances of high-field-strength elements correlate with increasing depths to the WBZ, and may be indicative of smaller degrees of partial melting of the mantle wedge as WBZ depths increase. Abundances of other incompatible elements appear to reflect a complex interplay between the slab-derived flux and melting process.
    Type of Medium: Electronic Resource
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  • 8
    Publication Date: 2017-07-21
    Description: This paper contains the results of an extensive isotopic study of United States Geological Survey GSD-1G and MPI-DING reference glasses. Thirteen different laboratories were involved using high-precision bulk (TIMS, MC-ICP-MS) and microanalytical (LA-MC-ICP-MS, LA-ICP-MS) techniques. Detailed studies were performed to demonstrate the large-scale and small-scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD-1G and the MPI-DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.
    Type: Article , PeerReviewed
    Format: text
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  • 9
    Publication Date: 2022-01-31
    Description: Highlights • The youngest known (2 Ma) volcanically-active subduction system. • Exceptionally diverse range of magma compositions coeval and spatially juxtaposed. • Mixing of an upwelling asthenospheric mantle melt and a slab melt. • Modern example of an immature subduction system building its proto forearc. • Modern analog of the environment where SSZ ophiolites lithosphere forms. Abstract The development of ideas leading to a greater understanding of subduction initiation is limited by the scarcity of present-day examples. Furthermore, the few examples identified so far unfortunately provide few insights into the nature of magmatism at the inception of subduction. Here we report new observations from the Matthew and Hunter (M&H) subduction zone, a very young subduction zone located in the South-West Pacific. Tectonics of the area show it is younger than 2 Ma, making the M&H the youngest known volcanically-active subduction system and hence providing unique insights into the earliest stages of subduction initiation. Volcanism in this area comprises an exceptionally diverse range of contemporaneously erupting magma compositions which are spatially juxtaposed. Pb isotopic compositions and abundance of LILE and REE strongly suggest melting of upwelling asthenospheric mantle (Indian MORB) and subducted oceanic crust (Pacific MORB of the South Fiji Basin) and the mixing of these two components. Volcanism occurs much closer to the trench compared to volcanism in more mature subduction zones. We demonstrate that the M&H subduction zone is a modern example of an immature subduction system at the stage of pre-arc, near-trench magmatism. It is not yet building an arc but what we propose to call a Subduction Initiation Terrane (SITER). Today, the proto-forearc of the M&H subduction zone is a collage of these SITERs, coeval back-arc domains and remnants of pre-existing terranes including old Vitiaz Arc crust. The M&H area represents a modern analog of a Supra Subduction Zone setting where potentially a majority of ophiolites have formed their crustal and lithospheric components. Present-day magmatism in the M&H area therefore provides clues to understanding unforeseen distribution of contrasted magmatic rock types in fossil forearcs, whether they are at the front of mature subduction zones or in ophiolites.
    Type: Article , PeerReviewed
    Format: text
    Format: text
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  • 10
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    PANGAEA
    In:  Supplement to: Beier, Christoph; Bach, Wolfgang; Turner, Stephnie; Niedermeier, D; Woodhead, Jon D; Erzinger, Jörg; Krumm, Stefan H (2015): Origin of silicic magmas at spreading centres - an example from the South East Rift, Manus Basin. Journal of Petrology, 56(2), 255-272, https://doi.org/10.1093/petrology/egu077
    Publication Date: 2023-05-12
    Description: There has been much recent interest in the origin of silicic magmas at spreading centres away from any possible influence of continental crust. Here we present major and trace element data for 29 glasses (and 55 whole-rocks) sampled from a 40 km segment of the South East Rift in the Manus Basin that span the full compositional continuum from basalt to rhyolite (50-75 wt % SiO2). The glass data are accompanied by Sr-Nd-Pb, O and U-Th-Ra isotope data for selected samples. These overlap the ranges for published data from this part of the Manus Basin. Limited increases in Cl/K ratios with increasing SiO2, La-SiO2 and Yb-SiO2 relationships, and the oxygen isotope data rule out models in which the more silicic lavas result from partial melting of altered oceanic crust or altered oceanic gabbros. Rather, the data form a coherent array that is suggestive of closed-system fractional crystallization and this is well simulated by MELTS models run at 0.2 GPa and QFM (quartz-fayalite-magnetite buffer) with 1 wt % H2O, using a parental magma chosen from the basaltic glasses. Although some assimilation of altered oceanic crust or gabbro cannot be completely ruled out, there is no evidence that this plays an important role in the origin of the silicic lavas. The U-series disequilibria are dominated by 238U and 226Ra excesses that limit the timescale of differentiation to less than a few millennia. Overall, the data point to rapid evolution in relatively small magma lenses located near the base of thick oceanic crust; we speculate that this was coupled with relatively low rates of basaltic recharge. A similar model may be applicable to the generation of silicic magmas elsewhere in the ocean basins.
    Type: Dataset
    Format: application/zip, 3 datasets
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