Note: Organophosphorus Chemistry -- Contents -- CHAPTER 1 Phosphines and Phosphonium Salts -- 1 Phosphines -- 1.1 Preparation -- 1.1.1 From Halogenophosphines and Organometallic Reagents -- 1.1.2 From Metallated Phosphines -- 1.1.3 By Addition of P-H to Unsaturated Compounds -- 1.1.4 By Reduction -- 1.1.5 Miscellaneous Methods -- 1.2 Reactions -- 1.2.1 Nucleophilic Attack at Carbon -- 1.2.2 Nucleophilic Attack at Halogen -- 1.2.3 Nucleophilic Attack at Other Atoms -- 1.2.4 Miscellaneous Reactions -- 2 Halogenophosphines -- 2.1 Preparations -- 2.2 Reactions -- 3 Phosphonium Salts -- 3.1 Preparation -- 3.2 Reactions -- 4 pπ-Bonded Phosphorus Compounds -- 5 Phosphirenes, Phospholes, and Phosphorins -- References -- CHAPTER 2 Pentaco-ordinated and Hexaco-ordinated Compounds -- 1 Introduction -- 2 Structure, Bonding, and Ligand Reorganisation -- 3 Acyclic Phosphoranes -- 4 Ring Containing Phosphoranes -- 4.1 Monocyclic Phosphoranes -- 4.2 Bicyclic and Tetracyclic Phosphoranes -- References -- CHAPTER 3 Phosphine Oxide and Related Compounds -- 1 Introduction -- 2 Preparation of Acyclic Phosphine Oxides -- 3 Preparation of Cyclic Phosphine Oxides -- 4 Structure and Physical Aspects -- 5 Reactions at Phosphorus -- 6 Reactions at the Side-chain -- 7 Phosphine Oxide Complexes -- References -- CHAPTER 4 Tervalent Phosphorus Acids -- 1 Introduction -- 2 Nucleophilic Reactions -- 2.1 Attack on Saturated Carbon -- 2.2 Attack on Unsaturated Carbon -- 2.3 Attack on Nitrogen, Chalcogen, or Halogen -- 3 Electrophilic Reactions -- 3.1 Preparation -- 3.2 Mechanistic Studies -- 3.3 Use for Nucleotide, Sugar Phosphate, or Phosphoprotein Synthesis -- 3.4 Miscellaneous -- 4 Reactions involving Two-co-ordinating Phosphorus -- References -- CHAPTER 5 Quinquevalent Phosphorus Acids -- 1 Phosphoric Acids and their Derivatives -- 1.1 Synthesis -- 1.2 Reactions. , 1.3 Synthetic Uses of Phosphoric Acid Derivatives -- 2 Phosphonic and Phosphinic Acids and their Derivatives -- 2.1 Synthesis -- 2.2 Reactions -- 2.3 Synthetic Uses -- References -- CHAPTER 6 Nucleotides and Nucleic Acids -- 1 Introduction -- 2 Mononucleotides -- 2.1 Chemical Synthesis -- 2.2 Cyclic Nucleotides -- 3 Nucleoside Polyphosphates -- 4 Oligo- and Poly-nucleotides -- 4.1 Chemical Synthesis -- 4.2 Enzymatic Synthesis -- 5 Other Studies -- 5.1 Affinity Separation -- 5.2 Affinity Labelling -- 5.3 Sequencing and Cleavage Studies -- 5.4 Post-Synthetic Modification -- 5.5 Metal Complexes -- 6 Analytical Techniques and Physical Methods -- References -- CHAPTER 7 Ylides and Related Compounds -- 1 Introduction -- 2 Methylenephosphoranes -- 2.1 Preparation and Structure -- 2.2 Reactions -- 2.2.1 Aldehydes -- 2.2.2 Ketones -- 2.2.3 Ylides Co-ordinated to Metals -- 2.2.4 Miscellaneous Reactions -- 3 Reactions of Phosphonate Anions -- 4 Selected Applications in Synthesis -- 4.1 Alkaloids -- 4.2 Carotenoids and Related Compounds -- 4.3 Leukotrienes and Related Compounds -- 4.4 Macrolides and Related Compounds -- 4.5 Pheromones -- 4.6 Prostaglandins -- 4.7 Miscellaneous Reactions -- References -- CHAPTER 8 Phosphazenes -- 1 Introduction -- 2 Acyclic Phosphazenes -- 3 Cyclophosphazenes -- 4 Cyclophospha(thia)zenes -- 5 Miscellaneous Phosphazene Containing Ring Systems -- 6 Poly( phosphazenes ) -- 7 Molecular Structure of Phosphazenes -- References -- AUTHOR INDEX.

Note: Organophosphorus Chemistry -- Contents -- CHAPTER 1 Phosphines and Phosphonium Salts -- 1 Phosphines -- 1.1 Preparation -- 1.1.1 From Halogenophosphines and Organometallic Reagents -- 1.1.2 From Metallated Phosphines -- 1.1.3 By Addition of P - H to Unsaturated Compounds -- 1.1.4 By Reduction -- 1.1.5 Miscellaneous Methods -- 1.2 Reactions -- 1.2.1 Nucleophilic Attack at Carbon -- 1.2.2 Nucleophilic Attack at Halogen -- 1.2.3 Nucleophilic Attack at Other Atoms -- 1.2.4 Miscellaneous Reactions -- 2 Halogenophosphines -- 2.1 Preparation -- 2.2 Reactions -- 3 Phosphonium Salts -- 3.1 Preparation -- 3.2 Reactions -- 4 pπ-Bonded Phosphorus Compounds -- 5 Phosphirenes, Phospholes, and Phosphorins -- References -- CHAPTER 2 Pentaco-ordinated and Hexaco-ordinated Compounds -- 1 Introduction -- 2 Structure, Bonding and Ligand Reorganization -- 3 Acyclic Phosphoranes -- 4 Ring Containing Phosphoranes -- 4.1 Monocyclic -- 4.2 Bicyclic and Tricyclic -- 5 Hexaco-ordinated Phosphorus Compounds -- References -- CHAPTER 3 Phosphine Oxides and Related Compounds -- 1 Introduction -- 2 Preparation of Acyclic Phospine Oxides -- 3 Preparation of Cyclic Phospine Oxides -- 4 Structure and Physical Aspects -- 5 Reactions at Phosphorus -- 6 Reactions at the Side-chain -- 7 Phosphine Oxide Complexes and Extractants -- References -- CHAPTER 4 Tervalent Phosphorus Acids -- 1 Introduction -- 2 Nucleophilic Reactions -- 2.1 Attack on Saturated Carbon -- 2.2 Attack on Unsaturated Carbon -- 2.3 Attack on Nitrogen, Chalcogen, or Halogen -- 3 Electrophilic Reactions -- 3.1 Preparation -- 3.2 Mechanistic Studies -- 3.3 Use for Nucleotide Synthesis -- 3.4 Miscellaneous -- 4 Reactions involving Two-co-ordinate Phosphorus -- 5 Miscellaneous Reactions -- References -- CHAPTER 5 Quinquevalent Phosphorus Acids -- 1 Phosphoric Acids and their Derivative s -- 1.1 Synthesis. , 1.2 Reactions and Properties -- 2 Phosphonic and Phosphinic Acids and their Derivatives -- 2.1 Synthesis -- 2.2 Reactions and Properties -- References -- CHAPTER 6 Nucleotides and Nucleic Acids -- 1Introduction -- 2 Mononucleotides -- 2.1 Chemical Synthesis -- 2.2 Cyclic Nucleotides -- 3 Nucleoside Polyophosphates -- 4 Oligo- and Poly- nucleotides -- 4.1 Chemical Synthesis -- 4.2 Enzymatic Synthesis -- 5 Other Studies -- 5.1 Affinity Separation -- 5.2 Affinity Labelling -- 5.3 Post-synthetic Modification -- 5.4 Sequencing and Cleavage Studies -- 5.5 Metal Complexes -- 6 Analytical Techniques and Physical Methods -- References -- CHAPTER 7 Ylides and Related Compounds -- 1 Introduction -- 2 Methylenephosphoranes -- 2.1 Preparation and Structure -- 2.2 Reactions -- 2.2.1 Aldehydes -- 2.2.2 Ketones -- 2.2.3 Miscellaneous Reactions -- 3 Reactions of Phosphonate Anions -- 4 Selected Applications in Synthesis -- 4.1 Carotenoids, Retinoids and Related Compounds -- 4.2 β-Lactams -- 4.3 Leukotrienes and Related Compounds -- 4.4 Macrolides and Related Compounds -- 4.5 Pheromones -- 4.6 Miscellaneous Reactions -- References -- CHAPTER 8 Phosphazenes -- 1 Introduction -- 2 Acyclic Phosphazenes -- 3 Cyclophosphazenes -- 4 Cyclophospha(thia)zenes -- 5 Miscellaneous Phosphazene-containing Ring Systems -- 6 Poly(phosphazenes) -- 7 Molecular Structures of Phosphazenes -- References -- CHAPTER 9 Physical Methods -- 1 Theoretical Studies -- 2 Nuclear Magnetic Resonance Spectroscopy -- 2.1 Biological and Analytical Applications -- 2.2.1 Phosphorus-31 -- δp of n1 and n2 compounds -- δp of n3 compounds -- δp of n4 compounds -- δp of n5 and n6 compounds -- 2.2.2 Carbon-13 -- 2.3 Shift Reagents and Liquid Crystals -- 2.4 Valence Isomerism, Restricted Rotation and Permutational Isomerism -- 2.5 Spin-Spin Couplings -- 2.5.1 J(PP) -- 2.5.2 J(PO) and J(PN) -- 2.5.3 J(PC). , 2.5.4 J(PH) -- 2.6 Anisotropy, Magnetisation Transfer, Relaxation and CIDNP -- 2.7 Nuclear Quadrupole Resonance -- 3 Electron Spin Resonance -- 4 Vibrational Spectroscopy -- 4.1 Assignments -- 4.2 Bonding -- 4.3 Stereochemistry -- 5 Electronic Spectroscopy -- 5.1 Absorption Spectroscopy -- 5.2 Fluorescence -- 5.3 Circular Dichroism -- 5.4 Photoelectron and X-ray Spectroscopy -- 6 Diffraction -- 6.1 X-ray Diffraction -- 6.1.1 n2 Compounds -- 6.1.2 n3 Compounds -- 6.1.3 n4 Compounds -- 6.1.4 n5 Compounds -- 6.2 Electron Diffraction -- 7 Dipole Moments, Kerr Effects, Polarography and Conductance -- 7.1 Dipole Moments and Kerr Effect -- 7.2 Polarography and Conductance -- 8 Mass Spectroscopy -- 9 Acidities, Basicities and Thermochemistry -- 10 Chromatography -- 10.1 Gas Liquid chromatography -- 10.2 Thin Layer Chromatography -- 10.3 Liquid Chromatography -- 11 Kinetics -- References -- AUTHOR INDEX.

Note: Organophosphorus Chemistry -- Contents -- Chapter 1 Phosphines and Phosphonium Salts -- 1 Phosphines -- 1.1 Preparation -- 1.1.1 From Halogenophosphines and Organometallic Reagents -- 1.1.2 From Metallated Phosphines -- 1.1.3 By Addition of P-H to Unsaturated Compounds -- 1.1.4 By Reduction -- 1.1.5 Miscellaneous Methods -- 1.2 Reactions -- 1.2.1 Nucleophilic Attack at Carbon -- 1.2.2 Nucleophilic Attack at Halogen -- 1.2.3 Nucleophilic Attack at Other Atoms -- 1.2.4 Miscellaneous Reactions -- 2 Halogenophosphines -- 2.1 Preparation -- 2.2 Reactions -- 3 Phosphonium Salts -- 3.1 Preparation -- 3.2 Reactions -- 4 pΠ-Bonded Phosphorus Compounds -- 5 Phospholes and Phosphorins -- References -- Chapter 2 Quinquecovalent Phosphorus Compounds -- 1 Introduction -- 2 Structure, Bonding, and Ligand Reorganization -- 3 Phosphoranes Containing a P-H Bond -- 4 Acyclic Phosphoranes -- 5 Ring-containing Phosphoranes -- 5.1 Monocyclic Phosphoranes -- 5.2 Bicyclic and Tricyclic Phosphoranes -- 6 Hexaco-ordinate Phosphorus Compounds -- References -- Chapter 3 Phosphine Oxides and Related Compounds -- 1 Introduction -- 2 Preparation of Acyclic Phosphine Oxides -- 3 Preparation of Cyclic Phosphine Oxides -- 4 Structure and Physical Aspects -- 5 Reactions at Phosphorus -- 6 Reactions at the Side-chain -- 7 Phosphine Oxide Complexes and Extractants -- References -- Chapter 4 Tervalent Phosphorus Acids -- 1 Introduction -- 2 Nucleophilic Reactions -- 2 . 1 Attack on Saturated Carbon -- 2 . 2 Attack on Unsaturated Carbon -- 2 . 3 Attack on Nitrogen, Chalcogen, or Halogen -- 3 Electrophilic Reactions -- 3.1 Preparation -- 3.2 Mechanistic Studies -- 3.3 Use for Nucleotide Synthesis -- 3.4 Miscellaneous -- 4 Reactions involving Two-co-ordinate Phosphorus -- 5 Miscellaneous Reactions -- References -- Chapter 5 Quinquevalent Phosphorus Acids -- 1 Introduction. , 2 Phosphoric Acids and their Derivatives -- 2.1 Synthesis -- 2.2 Reactions and Properties -- 3 Phosphonic and Phosphinic Acids and their Derivatives -- 3 . 1 Synthesis -- 3 . 2 Reactions -- 4 Miscellaneous Syntheses and Reactions -- References -- Chapter 6 Phosphates and Phosphonates of Biochemical -- 1 Introduction -- 2 Coenzymes and Cofactors -- 3 Sugar Phosphates -- 4 Phospholipids -- 5 Phosphonates -- 6 Enzyme Mechanisms and Phosphoproteins -- 7 Other Compounds of Biochemical Interest -- References -- Chapter 7 Nucleotides and Nucleic Acids -- 1 Introduction -- 2 Mononucleotides -- 2.1 Chemical Synthesis -- 2.2 Cyclic Nucleotides -- 3 Nucleoside Polyphosphates -- 4 Oligo- and Poly-nucleotides -- 4.1 Chemical Synthesis -- 4.2 Enzymatic Synthesis -- 5 Other Studies -- 5.1 Affinity Separation -- 5.2 Affinity Labelling -- 5.3 Post-synthetic Modification -- 5.4 Sequencing and Cleavage Studies -- 5.5 Metal Complexes -- 6 Analytical Techniques and Physical Methods -- References -- Chapter 8 Ylides and Related Compounds -- 1 Introduction -- 2 Methylenephosphoranes -- 2.1 Preparation and Structure -- 2.2 Reactions -- 2. 2.1 Reactions with Aldehydes -- 2.2.2 Reactions with Ketones -- 2.2.3 Miscellaneous Reactions -- 3 Reactions of Phosphonate Anions -- 4 Selected Applications in Synthesis -- 4.1 Carotenoids and Retinoids -- 4.2 β-Lactams -- 4.3 Leukotrienes and Related Compounds -- 4.4 Macrolides -- 4.5 Pheromones -- 4.6 Miscellaneous Applications -- References -- Chapter 9 Phosphazenes -- 1 Introduction -- 2 Acyclic Phosphazenes -- 3 Cyclophosphazenes -- 4 Cyclophospha(thia)zenes -- 5 Miscellaneous Phosphazene-containing Ring Systems -- 6 Polyphosphazenes -- 7 Molecular Structures of Phosphazenes -- References -- Chapter 10 Physical Methods -- 1 Nuclear Magnetic Resonance Spectroscopy -- 1.1 Biological Applications and Instrumental Techniques. , 1.2 Chemical Shifts and Shielding Effects -- 1.2.1 Phosphorus-31 -- δp of n2 compounds -- δp of n3 compounds -- δp of n4 compounds -- δP of n5 compounds -- δp of n6 compounds -- 1.2.2 Hydrogen-1 and -2 -- 1.3 Studies of Shift Reagents, Medium Effects, Liquid Crystals, and Solids -- 1.4 Inversion, Restricted Rotation, and Permutational Isomerism -- 1.5 Spin-Spin Couplings -- 1.5.1 J(PM) and J ( P P ) -- 1.5.2 J(PF) and J(PN) -- 1.5.3 J(PC) -- 1.5.4 J(PH) and J(P0CH) -- 1.6 Relaxation and N.Q.R. -- 2 Electron Spin Resonance -- 3 Vibrational Spectroscopy -- 3.1 Assignments -- 3.2 Bonding -- 3.3 Stereochemistry -- 4 Rotational Spectroscopy -- 5 Electronic Spectroscopy -- 5.1 Absorption Spectroscopy -- 5.2 Fluorescence -- 5.3 Optical Rotation -- 5.4 Photoelectron and X-Ray Spectroscopy -- 5.4.1 Photoelectron Spectroscopy -- 5.4.2 ESCA -- 6 Diffraction -- 6.1 X-R.ay Diffraction -- 6.1.1 n2 Compounds -- 6.1.2 n3 Compounds -- 6.1.3 n4 Compounds -- 6.1.4 n5 and n6 Compounds -- 6.2 Electron Diffraction -- 7 Dipole Moments, Kerr Effects, Polarography, and Conductance -- 7.1 Dipole Moment and Kerr Effect -- 7.2 Polarography and Conductance -- 8 Mass Spectrometry -- 9 Acidities, Basicities, and Thermochemistry -- 10 Chromatography -- 10.1 Gas-Liquid Chromatography -- 10.2 Thin-layer Chromatography -- 10.3 Liquid Chromatography -- 10.4 Gel Chromatography -- 10.5 Osmotic Properties, Solubilities, and Vapour Pressures -- References -- Author Index.

Note: Organophosphorus Chemistry -- Contents -- Chapter 1 Phosphines and Phosphonium Salts -- 1 Phosphines -- 1.1 Preparation -- 1.2 Reactions of Phosphines -- 2 Phosphine Oxides and Related Chalcogenides -- 2.1 Preparation -- 2.2 Reactions -- 2.3 Structural and Physical Aspects -- 2.4 Phosphine Chalcogenides as Ligands -- 3 Phosphonium Salts -- 3.1 Preparation -- 3.2 Reactions -- 4 pπ-Bonded Phosphorus Compounds -- 5 Phosphirenes, Phospholes and Phosphinines -- References -- Chapter 2 Pentacoordinated and Hexacoordinated Compounds -- Summary -- 1 Introduction -- 2 Monocyclic Phosphoranes -- 3 Bicyclic, Tricyclic and Tetracyclic Phosphoranes -- References -- Chapter 3 Tervalent Phosphorus Acid Derivatives -- 1 Introduction -- 2 Halogenophosphines -- 3 Tervalent Phosphorus Esters -- 3.1 Phosphinites -- 3.2 Phosphonites -- 3.3 Phosphites -- 4 Tervalent Phosphorus Amides -- 4.1 Aminophosphines -- 4.2 Phosphoramidites and Related Compounds -- References -- Chapter 4 Quinquevalent Phosphorus Acids -- 1 Introduction -- 2 Phosphoric Acids and Their Derivatives -- 2.1 Synthesis of Phosphoric Acids and Their Derivatives -- 2.2 Reactions of Phosphoric Acids and Their Derivatives -- 2.3 Selected Biological Aspects -- 3 Phosphonic and Phosphinic Acids -- 3.1 Synthesis of Phosphonic and Phosphinic Acids and Their Derivatives -- 3.2 Reactions of Phosphonic and Phosphinic Acids and Their Derivatives -- 3.3 Selected Biological Aspects -- 4 Structure -- References -- Chapter 5 Nucleic Acids and Nucleotides -- Mononucleotides -- 1 Introduction -- 2 Mononucleotides -- 2.1 Nucleoside Acyclic Phosphates -- 2.2 Nucleoside Cyclic Phosphates -- 2.3 Nucleoside Pyrophosphates -- 3 Nucleoside Polyphosphates -- 3.1 Nucleoside Pyrophosphates -- 3.2 Nucleoside Polyphosphates -- References -- Chapter 6 Nucleotides and Nucleic Acids -- Oligo- and Polynucleotides -- 1 Introduction. , 1.1 Oligonucleotide Synthesis -- 1.2 RNA Synthesis -- 1.3 The Synthesis of Modified Oligodeoxyribonucleotides and Modified Oligoribonucleotides -- 2 Aptamers -- 3 Oligonucleotide Conjugates -- 4 Nucleic Acid Structures -- References -- Chapter 7 Ylides and Related Species -- 1 Introduction -- 2 Phosphonium Ylides -- 2.1 Mechanistic and Theoretical Studies of Phosphonium Ylides and the Wittig Reaction -- 2.2 Synthesis and Characterisation of Phosphonium Ylides -- 2.3 Reactions of Phosphonium Ylides -- 2.4 Synthesis and Reactions of Aza-Wittig Reagents -- 2.5 Ylides Coordinated to Metals -- 3 Wittig-Horner Reactions of Metallated Phosphine Oxide Anions -- 4 Horner-Wadsworth-Emmons Reaction of Phosphonate Anions -- References -- Chapter 8 Phosphazenes -- 1 Introduction -- 2 Linear Phosphazenes -- 3 Cyclophosphazenes -- 4 Polyphosphazenes -- 5 Crystal Structures of Phosphazenes and Related Compounds -- References.

Note: OG9780851869803-FX001 -- OG9780851869803-FP001 -- OG9780851869803-FP005 -- OG9780851869803-FP007 -- OG9780851869803-FP013 -- OG9780851869803-00001 -- OG9780851869803-00033 -- OG9780851869803-00051 -- OG9780851869803-00069 -- OG9780851869803-00083 -- OG9780851869803-00104 -- OG9780851869803-00136 -- OG9780851869803-00150 -- OG9780851869803-00192 -- OG9780851869803-00219 -- OG9780851869803-00247 -- OG9780851869803-00273.