ISSN:
1572-8943
Keywords:
amides
;
carboxylic acid anhydrides
;
group-additivity correlation
;
imides
;
N-oxo-amides
;
standard enthalpy of formation
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract This work has been undertaken for the evaluation and revision of group additivity values necessary for predicting gaseous standard enthalpies of formation of nitrogen and oxygen containing compounds by means of Benson's group additivity methodology. The current database of experimental data for enthalpies of formation, enthalpies of vaporization and enthalpies of sublimation was used to derive the values of the strain-free increments for imines, amides, oxo-amides, and carboxylic acids anhydrides. The group-additivity parameters and strain corrections useful in the application of the Benson correlation are presented in tabular form, together with a description of their evaluation and comments on their reliability.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010193526125
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