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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 66 (1995), S. 3275-3277 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Synthesis of ultrafine titania particles is investigated in a diffusion flame aerosol reactor in the presence of a gaseous electric discharge (corona) created by two needle electrodes. The corona wind flattens the flame and reduces the particle residence time at high temperatures, resulting in smaller primary particle sizes and lower level of crystallinity. Increasing the applied potential from 5 to 8 kV reduces the particle size from 50 to 25 nm and the rutile content from 20 to 8 wt %. Coronas provide a clean and simple technique that facilitates gas phase synthesis of nanosized materials with controlled size and crystallinity. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1183-1192 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The competition between hydrolysis and oxidation of TiCl4 during vapor-phase synthesis of titania powders was experimentally investigated. The effects of reactor temperature, reactant mixing and H2O/TiCl4 ratio were studied in a hot wall aerosol flow reactor. The presence of water vapor resulted in rounded particles instead of the faceted ones observed in the absence of water; this effect was most pronounced at lower reactor temperatures. Mixing the water and TiCl4 vapor streams at low temperature resulted in anatase titania. Larger aggregates with smaller primary particles were observed for powders synthesized in the presence of water vapor. The mixing temperature of the water and TiCl4 vapors, as well as the H2O/TiCl4 ratios, did not affect the aggregate size or specific surface area. Analysis of micrographs of titania aggregates made in the presence of water revealed that the fractal dimension increased with process temperature.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 11 (1994), S. 359-366 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A log-normal model, based on the extended SIMPLER-algorithm utilizing the Modal Aerosol Dynamics Modelling Technique, and a sectional model are compared for Brownian coagulation in the transition regime. The models are in good agreement with respect to the calculated particle size distribution moments. Applying the log-normal model a simple coagulation model consisting of a closed set of five equations is developed that does not require the solution of ordinary diferential equations.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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