ISSN:
1573-9171
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Conclusions 1. The reaction of cyclohexene, formaldehyde, and hydrochloric acid at a temperature of 20-30°C leads to the formation of di(trans-2-chlorocyclohexylmethyl)formal. 2. 3-Hydroxymethylcyclohexene, formed during the dehydrochlorination of di(trans-2-chlorocyclohexylmethyl)formal by the action of alcoholic alkali, followed by methanolysis of dehydrochlorination of trans-1-hydroxymethyl-2-chlorocyclohexane by the action of potassium acetate, is converted into 3-chloro(bromo)methylcyclohexene via a tosylate, by the action of calcium chloride (sodium bromide) in glycerin.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00957243
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