ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. In the Na2S2O8-CuCl2 system, secondary aliphatic amines (RCH2CH2)2NH are transformed into 2-chloro- and 2,2-dichloroalkanals, alkanoic acids and their alkylamides; their most probable precursors are RCH2CH=NCH2CH2R azomethines, formed as a result of oxidative deprotonation. 2. In the Na2S2O8-NaCN-NaOH system, oxidation of dialkylamines by a mechanism of oxidative substitution with the formation of the products of N-cyanidation: cyanamides and ureas, and the products of N-hydroxylation, dialkylhydroxylamines, predominate.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00948513
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