ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The sodium-ammonia reduction of racemic norcamphor, exo-3-methylnorcamphor and 3,3-dimethyl-norcamphor (camphenilone) leads to substantial yields (60-90%) of the corresponding 2,2′-bisnorbornyl-2,2′-diols as diastereomeric mixtures. A combination of their 1H, 13C and infrared spectra together with the results of periodic acid and lead tetraacetate oxidations permits stereochemical assignments for these six pinacols.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270091208
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