Keywords:
Catalysis.
;
Electronic books.
Description / Table of Contents:
Newly added to Springer's Topics in Organometallic Chemistry series, this book provides the scientific community with specialized insights into a emerging realm of interdisciplinary research now influencing fields as diverse as medicine and materials science.
Type of Medium:
Online Resource
Pages:
1 online resource (376 pages)
Edition:
1st ed.
ISBN:
9783642337352
Series Statement:
Topics in Organometallic Chemistry Series ; v.43
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=3070879
DDC:
547.0504595
Language:
English
Note:
Intro -- Hydrofunctionalization -- Topics in Organometallic ChemistryAlso Available Electronically -- Aims and Scope -- Preface -- References -- Contents -- Alkyne and Alkene Insertion into Metal-Heteroatom and Metal-Hydrogen Bonds: The Key Stages of Hydrofunctionalization Process -- 1 Introduction -- 2 Insertion of CC and CC Bonds in the Metal Complexes -- 2.1 Reactions of CC and CC Bonds in the Coordination Sphere of the Metal Complex -- 2.2 Preliminary Activation of the Multiple Bonds upon Coordination to the Metal -- 2.3 The Role of Orientation of Heteroatom Group -- 2.4 Structural Reorganization of the Initial Complex -- 2.5 Selectivity of the Insertion Reaction, Steric and Electronic Effects -- 3 Conclusions -- References -- The Mechanism for Transition-Metal-Catalyzed Hydrochalcogenation of Unsaturated Organic Molecules -- 1 Introduction -- 1.1 Type I Mechanism -- 1.2 Type II Mechanism -- 1.3 Transition Metal Catalysts as Lewis Acids -- 1.4 Mechanism Through Vinylidene Intermediates -- 2 Type I Mechanism -- 2.1 Group X Metal-Catalyzed Hydrothiolation and Hydroselenation -- 2.1.1 Pd(OAc)2-Catalyzed Hydrothiolation and Hydroselenation -- 2.1.2 PdCl2L2-Catalyzed Hydrothiolation and Hydroselenation -- 2.1.3 Ni(II)-Catalyzed Hydrothiolation and Hydroselenation -- 2.2 Groups III and IV Metal-Catalyzed Hydrothiolation and Hydroalkoxylation -- 2.2.1 Organoactinide- and Organolanthanide-Catalyzed Hydrothiolation -- 2.2.2 Organozirconium(IV)-Catalyzed Hydrothiolation -- 2.2.3 Organolanthanide-Catalyzed Intramolecular Hydroalkoxylation -- 3 Type II Mechanism -- 3.1 Pd(0) and Pt(0)-Catalyzed Hydroselenation of Alkynes -- 3.2 Stoichiometric Reaction of Hydrido-Chalcogenolato Pt(II) Complexes with Alkynes -- 3.3 Hybrid Type of Type I and Type II Mechanisms: Rh(I) and Ir(I) Complex-Catalyzed Hydrothiolation -- 3.3.1 RhCl(PPh3)3-Catalyzed Hydrothiolation.
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3.3.2 Cationic Rh(I) and Ir(I) Complex-Catalyzed Hydrothiolation -- 4 Conclusion -- References -- Early Transition Metal (Group 3-5, Lanthanides and Actinides) and Main Group Metal (Group 1, 2, and 13) Catalyzed Hydroamination -- 1 Introduction: General Features -- 2 Mechanisms -- 2.1 Insertion Mechanism -- 2.2 Imido Mechanism -- 3 Intramolecular Hydroamination -- 3.1 Hydroamination/Cyclization of Aminoalkenes -- 3.1.1 Lanthanides and Actinides -- 3.1.2 Main Group Metal Catalysts -- 3.1.3 Group 4 Metal Catalysts -- 3.2 Hydroamination of Aminoalkynes -- 3.2.1 Rare Earth Metal Catalysts -- 3.2.2 Other Metals -- 3.3 Hydroamination of Conjugated Aminodienes -- 3.4 Hydroamination of Aminoallenes -- 3.4.1 Rare Earth Metals -- 3.4.2 Group 4 Metals -- 4 Hydroamination/Bicyclization -- 5 Intermolecular Hydroamination -- 5.1 Hydroamination of Unactivated Alkenes -- 5.2 Hydroamination of Conjugated Dienes -- 5.3 Hydroamination of Allenes and Methylenecyclopropanes -- 5.4 Hydroamination of Alkynes -- 6 Asymmetric Hydroamination -- 6.1 Intramolecular Hydroamination of Alkenes -- 6.1.1 Chiral Rare Earth Metal Catalysts -- 6.1.2 Chiral Alkali Metal Catalysts -- 6.1.3 Chiral Alkaline Earth Metal Catalysts -- 6.1.4 Chiral Group 4 Metal Catalysts -- 6.1.5 Chiral Group 5 Metal Catalysts -- 6.2 Intramolecular Hydroamination of Dienes -- 6.3 Intramolecular Hydroamination of Allenes -- 6.4 Intermolecular Asymmetric Hydroamination -- References -- Late Transition Metal-Catalyzed Hydroamination -- 1 Introduction -- 2 Thermodynamics in Direct and in Late Transition Metal-Catalyzed Addition -- 2.1 Direct Addition -- 2.2 Late Transition Metal-Catalyzed Addition -- 3 The Reaction Patterns and Mechanistic Details -- 3.1 C-C Multiple Bond Activation Pathway -- 3.1.1 Outer-Sphere Pathway -- 3.1.2 Nucleophilic Addition on Coordinated Alkenes or Alkynes.
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3.1.3 Nucleophilic Addition to Other pi-Coordination Systems -- Intermediacy of eta3-Allyl System -- Intermediacy of eta6-Arene System -- 3.2 Amine Activation Pathway -- 3.2.1 Inner-Sphere Pathway -- 3.2.2 Aminometallation Initiated by Oxidative Addition of Amines -- 3.2.3 Aminometallation Initiated by Coordination of Amines -- 4 Scope of Late Transition Metal-Catalyzed Hydroamination -- 4.1 The Reaction Pathway Depending on Catalyst Species -- 4.2 Intramolecular Hydroamination of Alkynes -- 4.3 Intramolecular Hydroamination of Allenes and Conjugated Dienes -- 4.4 Intramolecular Hydroamination of Alkenes -- 4.5 Intermolecular Hydroamination -- 5 Conclusion -- References -- Chiral Metal Complex-Promoted Asymmetric Hydrophosphinations -- 1 Introduction -- 2 Asymmetric Hydrophosphination of 1-Alken-1-ylphosphines -- 3 Asymmetric Hydrophosphination of Functionalized Phosphines -- 4 Asymmetric Hydrophosphination of Pyridylphosphines: Access to Chiral P-N Ligands -- 5 Asymmetric Hydrophosphination Involving Other Substrate Systems and Development of a Catalytic Protocol -- References -- Recent Progress in Transition Metal-Catalyzed Addition Reactions of H-P(O) Compounds with Unsaturated Carbon Linkages -- 1 Introduction -- 2 Addition Reactions of H-Phosphonates and Related Reagents with Alkynes -- 3 Addition Reactions of H-Phosphinates and Related H-P(O) Compounds with Alkynes -- 4 Addition Reactions of sec-Phosphine Oxides with Alkynes -- 5 Addition Reactions of H-P(O) Compounds with Alkenes, Dienes, and Isocyanides -- 6 Conclusion and Future Prospects -- References -- Group 8 Metals-Catalyzed O-H Bond Addition to Unsaturated Molecules -- 1 Introduction -- 2 Addition to Olefins -- 2.1 Addition of Alcohols -- 2.2 Addition of Carboxylic Acids -- 3 Addition of O-Nucleophiles to Alkynes -- 3.1 Addition of Carbamates -- 3.2 Addition of Carboxylic Acids.
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3.2.1 Markovnikov Addition -- 3.2.2 Anti-Markovnikov Addition -- 3.3 Addition of Alcohols -- 3.3.1 Addition of Allylic Alcohols -- 3.3.2 Intramolecular Addition of Hydroxy Group to Triple Bond -- 3.4 Addition of Water -- 4 Conclusion -- References -- Groups 9 and 10 Metals-Catalyzed O-H Bond Addition to Unsaturated Molecules -- 1 Introduction -- 2 Cobalt -- 2.1 Hydration -- 2.1.1 Alkenes -- 2.1.2 Nitriles -- 3 Rhodium -- 3.1 Hydration -- 3.1.1 Alkynes -- 3.1.2 Nitriles -- 3.2 Hydroalkoxylation -- 3.2.1 Alkynes -- 3.2.2 Allenes -- 3.3 Hydroacyloxylation -- 3.3.1 Alkynes -- 4 Iridium -- 4.1 Hydration -- 4.1.1 Alkynes -- 4.1.2 Nitriles -- 4.2 Hydroalkoxylation -- 4.2.1 Alkynes -- 4.3 Hydroacyloxylation -- 4.3.1 Alkynes -- 4.3.2 Allenes -- 5 Nickel -- 6 Palladium -- 6.1 Hydration -- 6.1.1 Alkenes -- 6.1.2 Alkynes -- 6.1.3 Nitriles -- 6.2 Hydroalkoxylation -- 6.2.1 Alkenes -- 6.2.2 Alkynes -- 6.3 Hydroacyloxylation -- 6.3.1 Alkenes -- 6.3.2 Alkynes -- 7 Platinum -- 7.1 Hydration -- 7.1.1 Alkenes -- 7.1.2 Alkynes -- 7.1.3 Nitriles -- 7.2 Hydroalkoxylation -- 7.2.1 Alkenes -- 7.2.2 Alkynes -- 7.2.3 Allenes -- References -- Gold-Catalyzed O-H Bond Addition to Unsaturated Organic Molecules -- 1 Introduction -- 2 Gold-Catalyzed Hydrofunctionalization of pi-Bonds -- 2.1 Hydration and Hydroalkoxylation of Alkynes -- 2.2 Hydroalkoxylation of Alkenes -- 2.3 Hydration and Hydroalkoxylation of Allenes -- 3 Addition of Nucleophiles to 1,n-Enynes -- 3.1 Hydroxycyclization and Alkoxycyclization of 1,5-Enynes -- 3.2 Hydroxycyclization and Alkoxycyclization of 1,6-Enynes -- 3.3 Hydroxycyclization and Alkoxycyclization of 1,7-Enynes -- References -- Transition-Metal-Catalyzed S-H and Se-H Bonds Addition to Unsaturated Molecules -- 1 Introduction -- 2 Transition-Metal-Catalyzed Hydrothiolation with Thiols -- 2.1 Hydrothiolation of Alkynes -- 2.1.1 Markovnikov Addition.
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Palladium Catalysts -- Nickel Catalysts -- Rhodium Catalysts -- Early Transition Metal Catalysts -- 2.1.2 Markovnikov Addition and Double-Bond-Isomerization -- 2.1.3 Anti-Markovnikov Addition -- 2.1.4 Double Hydrothiolation -- 2.2 Hydrothiolation of Allenes -- 3 Transition-Metal-Catalyzed Hydroselenation with Selenols -- 4 Applications to the Synthesis of Functionalized Sulfur Compounds -- 5 Conclusions -- References -- Index.
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