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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 25 (1992), S. 4382-4391 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 3419-3429 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In situ interfacial impedance measurements are used to study the effects of moisture at 80 °C on the interface between oxidized silicon and a diglycidyl ether of bisphenol A epoxy cured with diethylene triamine. Bulk impedance measurements follow Randles behavior; conduction in the bulk epoxy is ionic, and is diffusion controlled at low frequencies. An additional conduction process between interfacial electrodes is observed even though a water layer does not condense in the interface. Through comparative use of linear network models, it is found that the "interfacial'' conduction path represents distributed bulk conduction in the epoxy with displacement current leakage into the conductive silicon substrate through an interfacial capacitance. Both electrochemical and bulk coating properties jump at humidities near 70%, indicating greatly increased ionic mobility, coating permittivity, and interfacial capacitances. The permittivity and ionic mobility behavior suggest the formation of large water-swollen demains or highly elongated water clusters near the property jump threshold. Because humidity effects are resolved into bulk and interfacial components, interfacial impedance measurements appear to have great utility for the in situ study of transport and electrochemical properties of interfaces and coatings during environmental exposure.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1781-1788 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Electrolyzing sparingly soluble gases as they are absorbed from bubbles can be significantly facilitated by addition of a soluble redox couple which serves to increase both mass and charge transfer rates. A diffusion layer model is used to calculate reaction-catalyzed mass transfer rates in regions of boundary layer penetration by reactive bubbles for the case of (m, n)-order irreversible homogeneous reaction. The dissolved redox catalyst is continuously regenerated at the solid electrode surface. Approximate solutions, which relate surface flux to concentration driving force, are in excellent agreement with the numerical solutions under conditions of fast homogeneous reaction and concentrated catalyst (modified Damköhler number and dimensionless catalyst concentration greater than 3). Diffusion layer thickness is calculated from the mass transfer coefficient kp in penetrated regions. A model based on spherical penetrating bubbles is used to determine kp and specific surface area ap of penetrated regions from kpap values that have been measured in gas-liquid flow through a packed bed. The mass transfer behavior provides useful insight into why the penetration process is so effective in increasing overall reaction rates.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1504-1510 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The measurement of gas-liquid interfacial areas and mass transfer coefficients in concurrent upward bubbly flow (uG from 0.02 to 0.16 m/s, uL from 0.0051 to 0.056 m/s) over a packed bed consisting of 1.2 mm glassy carbon particles is described. Specific surface areas were measured by chemical absorption of O2 into Na2SO3 solutions; volumetric mass transfer coefficients were measured by physical desorption of O2 into N2 bubbles. Surface areas were obtained in the range of 4 × 103 to 2 × 105 m-1, much higher than have been previously reported. High areas are related to the use of electrolytes and small packing particles. Bubble size was found to depend primarily on liquid velocity. Volumetric mass transfer coefficients kLaG are also high (0.1 〈 kLaG 〈 2.3 s-1), primarily as a result of high gas-liquid interfacial areas. Mass transfer coefficients kL are small, however. For the smaller bubble dispersions, mass transport is controlled by diffusion rather than by convection.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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