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  • 1
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (335 pages)
    Edition: 1st ed.
    ISBN: 9780080565163
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Front Cover -- Advances in Catalysis, Volume XII -- Copyright Page -- Contents -- List of Contributors -- Preface -- Chapter 1. The Wave Mechanics of the Surface Bond in Chemisorption -- I. Introduction -- II. A Solid with a Free Surface -- III. The Molecular Orbital Theory of the Surface Bond -- IV. Types of Surface Bonds -- V. Chemisorption on Semiconductors -- VI. Conclusion -- References -- Chapter 2. Magnetic Resonance Techniques in Catalytic Research -- I. Introduction -- II. Nuclear Magnetic Resonance -- III. Electron Paramagnetic Resonance -- IV. Conclusion -- References -- Chapter 3. Base-Catalyzed Reactions of Hydrocarbons -- I. Introduction -- II. Isomerization -- III. Side-Chain Alkylation of Arylalkanes -- IV. Nuclear Alkylation of Aromatics -- V. Alkylation of Alkylpyridines -- VI. Reactions of Olefins -- VII. Conclusion -- References -- Chapter 4. The Use of X-Ray K-Absorption Edges in the Study of Catalytically Active Solids -- I. Introduction -- II. Origin of Fine Structure -- III. Experimental -- IV. Spectra of Known Compounds -- V. Spectra of Catalysts -- VI. Summary -- References -- Chapter 5. The Electron Theory of Catalysis on Semiconductors -- I. Introduction -- II. Types of Chemisorption Bonds -- III. Radical and Valence-Saturated Forms of Chemisorption -- IV. Electron Transitions in Chemisorption -- V. Catalytic Activity of a Semiconductor -- VI. Interaction of the Surface with the Bulk of the Semiconductor -- VII. Promoters and Poisons in Catalysis -- VIII. Factors Affecting the Adsorptivity and Catalytic Activity of a Semiconductor -- IX. Chemisorption and Catalysis on a Real Surface -- X. Conclusions -- References -- Chapter 6. Molecular Specificity in Physical Adsorption -- I. Introduction -- II. The Perturbation of Solids by Adsorbed Molecules -- III. Perturbation of Adsorbed Gases. , IV. Over-all Changes at the Solid-Gas Interface -- V. Conclusion -- References -- Auther Index -- Subject Index.
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  • 2
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Chemistry, Physical and theoretical. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (395 pages)
    Edition: 1st ed.
    ISBN: 9780080565156
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Cover -- Copyright -- Contributors to Volume XI -- Preface -- Contents -- Chapter 1. The Kinetics of the Stereospeciflc Polymerization of α-Oleflns -- I. Introduction to Anionic Coordinated Polymerization of α-Olefins -- II. Over-All Kinetics of Polymerization Process -- III. Chain Transfer, Termination Processes, and Molecular Weight of the Polymers -- IV. Steric Composition of Polymers -- V. Determination of the Number of Active Centers -- VI. Mean Lifetime of the Growing Polymeric Chains -- VII. Conclusions -- References -- Chapter 2. Surface Potentials and Adsorption Process on Metals -- I. Introduction -- II. The Surface Properties of Metals -- III. The Modification of Surface Properties by Adsorbates . . -- IV. The Preparation of Clean Metal Surfaces -- V. The Measurement of Work-Function Changes -- VI. Adsorption and Work-Function Studies -- VII. Surface-Potential Data -- VIII. Electron Transfer and Bond Formation -- IX. The Kinetics of Desorption and Surface Migration -- X. Surface Reaction Mechanisms -- XI. Heats of Adsorption -- XII. Conclusions -- References -- Chapter 3. Gas Reactions of Carbon -- I. Introduction -- II. Thermodynamics of Gas-Carbon Reactions -- III. Review of General Mechanisms for the Gas-Carbon Reactions -- IV. Review of Kinetics for the Gas-Carbon Reactions -- V. Role of Mass Transport in Gas-Carbon Reactions -- VI. Use of Density and Area Profiles on Reacted Carbon Rods for Better Understanding of Gas-Carbon Reactions -- VII. Some Factors, Other than Mass Transport, Which Affect the Rate of Gas- Carbon Reactions -- Appendix -- References -- Chapter 4. The Catalytic Exchange of Hydrocarbons with Deuterium -- I. Introduction -- II. General Aspects of Exchange Reactions -- III. The Exchange of Molecules Possessing a High Degree of Symmetry -- IV. The Exchange of Molecules Possessing 8 Low Degree of Symmetry. , V. Some Results with Unsaturated Molecules -- VI. Concluding Remarks -- References -- Chapter 5. lmmersional Heats and the Nature of Solid Surfaces -- I. Introduction -- II. Experimintal -- III. Wetting and Adsorption Thermodynamics -- IV. Wetting by Water -- V. Wetting by Organic Liquids -- VI. Average Polarity of Solids -- VII. Site Energy Distribution -- VIII. Solution Adsorption -- References -- Chapter 6. The Catalytic Activation of Hydrogen in Homogeneous, Heterogeneous, and Biological Systems -- I. Introduction -- II. Homogeneous Systems -- III. Heterogeneous Systems -- IV. Biological Systems -- V. Concluding Remarks -- References -- Author Index -- Subject Index.
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  • 3
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Chemistry, Physical and theoretical. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (473 pages)
    Edition: 1st ed.
    ISBN: 9780080565170
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Front Cover -- Advances in Catalysis: and Related Subjects -- Copyright Page -- Contents -- Contributors -- Preface -- Professor W. E. Garner -- Chapter 1. Chemisorption and Catalysis on Metallic Oxides -- I. Introduction -- II. The Adsorption and Oxidation of Carbon Monoxide -- III. The Uptake of Oxygen by Metals and Metallic Oxides -- IV. The Emergence and Significance of the Electronic Factor -- V. Adsorption and Catalysis on Doped Oxides -- VI. Photoadsorption and Photocatalysis -- VII. Conclusion -- References -- Chapter 2. Radiation Catalysis -- I. Introduction -- II. Experimental Studies of Some Irradiated Heterogeneous Systems -- III. General Degradation Scheme of Radiation Energy in Solids -- IV. Radiation Catalysis -- V. Some Comments About the Experimental Results -- VI. General Conclusion -- Appendix -- References -- Chapter 3. Polyfunctional Heterogeneous Catalysis -- I. Introduction -- II. Principles of Polystep Catalysis -- III. The Technique of Physically Mixed Catalyst Components -- IV. Some Major Polystep Reactions of Hydrocarbons -- V. The Petroleum Naphtha "Reforming" Reaction -- VI. Other Polystep Reactions -- VII. Conclusions -- References -- Chapter 4. A New Electron Diffraction Technique, Potentially Applicable to Research in Catalysis -- I. Experimental Apparatus -- II. Oxygen on Nickel -- References -- Chapter 5. The Structure and Analysis of Complex Reaction Systems -- I. Introduction -- II. Reversible Monomolecular Systems -- III. The Determination of the Values of the Rate Constants for Typical Reversible Monomolecular Systems Using the Characteristic Directions -- IV. Irreversible Monomolecular Systems -- V. Miscellaneous Topics Concerning Monomolecular Systems -- VI. Pseudo-Mass-Action Systems in Heterogeneous Catalysis -- VII. Qualitative Features of General Complex Reaction Systems. , VIII. General Discussion and Literature Survey -- Appendices -- I. The Orthogonal Characteristic System -- II. Explicit Solution for the General Three Component System -- III. A Convenient Method for Computing the Characteristic Vectors and Roots of the Rate Constant Matrix K -- IV. Canonical Forms -- V. List of Symbols -- References -- Chapter 6. Catalytic Effects in Isocyanate Reactions -- I. Introduction -- II. Polymerization of Isocyanates -- III. Reactions of Isocyanates with Compounds Containing Active Hydrogen -- IV. Applications -- References -- Author Index -- Subject Index.
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  • 4
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Chemisorption. ; Paramagnetism. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (185 pages)
    Edition: 1st ed.
    ISBN: 9780323160568
    Language: English
    Note: Front Cover -- Chemisorption and Magnetization -- Copyright Page -- Table of Contents -- Preface -- Chapter I. Introduction -- 1. Solid-Vapor Interfaces -- 2. Chemisorption -- 3. Definitions in Magnetism -- 4. Paramagnetism -- 5. Ferromagnetism -- 6. Antiferromagnetism and Ferrimagnetism -- References -- Chapter II. Superparamagnetism -- 1. Very Small Particles -- 2. Anisotropy and Relaxation -- 3. Experimental Evidence for Superparamagnetism -- 4. Particle Size and Saturation Moment -- 5. Particle Size and Internal Field -- References -- Chapter III. Magnetization Measurements at High M/M0 -- 1. The Experimental Problem -- 2. The Weiss Extraction Method -- 3. Correction for Demagnetizing Field -- 4. Correction for the Magnetic Image Effect -- 5. Calibration -- 6. The Faraday Method -- 7. General Procedure -- References -- Chapter IV. Magnetic Particle Size Determination -- 1. Granulometry -- 2. The Langevin Low-Field (LLF) and High-Field (LHF) Methods -- 3. The Néel Remanence (NR) Method -- 4. Comparisons of Methods -- References -- Chapter V. Magnetic Saturation Results for H2/Ni, H2/Ni-Cu, H2/Co, and H2/Fe -- 1. The Fractional Change of M 0 -- 2. Hydrogen on Nickel -- 3. Hydrogen on Nickel-Copper Alloy -- 4. Hydrogen on Cobalt -- 5. Hydrogen on Iron -- References -- Chapter VI. Magnetization Measurements at Low M/M0 -- 1. The Permeameter -- 2. General Considerations -- 3. Theory of Low M/M0 Measurements -- References -- Chapter VII. Low-Field Results for H2/Ni, H2/Co, and H2/Fe -- 1. Magnetization-Volume Isotherms for H2/Ni -- 2. Temperature of Adsorption and Temperature of Measurement -- 3. Elevated Pressure and Preadsorbed Molecules -- 4. The "Slow" Sorption of H 2 on Ni -- 5. The Systems H 2/Co and H2/Fe -- 6. Thermal Transients -- 7. Evaluation of the Low M/M0 Method -- References -- Chapter VIII. Hydrogen Bonding on Ni, Ni-Cu, Co, and Fe. , 1. Conclusions from Magnetic Data -- 2. Related Experimental Data -- 3. Theoretical Studies -- 4. Summary of Conclusions -- References -- Chapter IX. Determination of Bond Number, O 2 , CO, CO2 , H2S, (CH3)2S, and N2 -- 1. Bond Number -- 2. Oxygen -- 3. Carbon Monoxide -- 4. Carbon Dioxide -- 5. Hydrogen Sulfide and Dimethyl Sulfide -- 6. Nitrogen -- References -- Chapter X. Ethane, Ethylene, and Acetylene -- 1. Ethane -- 2. The Chemisorption of Ethylene -- 3. Remarks on the Hydrogénation of Ethylene -- 4. Acetylene -- References -- Chapter XI. Benzene and Related Compounds -- 1. Cyclohexane -- 2. Cyclohexene -- 3. The Chemisorption of Benzene -- 4. The Interaction of Benzene and Hydrogen -- References -- Chapter XII. Other Systems -- 1. Palladium and Platinum -- 2. Oxides -- 3. Raney Nickel -- 4. Reflections -- References -- Appendix -- Symbols Used More Than Once -- Definitions and Units in Magnetism -- Author Index -- Subject Index.
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 60 (1956), S. 452-457 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 66 (1962), S. 450-453 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 61 (1957), S. 1564-1567 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 64 (1960), S. 1114-1120 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 76 (1954), S. 2281-2282 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 76 (1954), S. 2641-2644 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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