Keywords:
Nuclear magnetic resonance.
;
Electronic books.
Description / Table of Contents:
For those wanting to become rapidly acquainted with specific areas of NMR, this title provides unrivalled scope of coverage.
Type of Medium:
Online Resource
Pages:
1 online resource (588 pages)
Edition:
1st ed.
ISBN:
9781847553881
Series Statement:
Issn Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1185839
DDC:
543.0877
Language:
English
Note:
Nuclear Magnetic Resonance -- Contents -- Chapter 1 NMR Books and Reviews -- 1 Books -- 2 Regular Reviews Series -- 3 Edited Books and Symposia -- 4 Reviews in Periodicals -- 5 Reviews and Books in Foreign Languages -- Chapter 2 Theoretical and Physical Aspects of Nuclear Shielding -- 1 Theoretical Aspects of Nuclear Shielding -- 1.1 General Theory -- 1.2 Ab initio Calculations -- 2 Physical Aspects of Nuclear Shielding -- 2.1 Anisotropy of the Shielding Tensor -- 2.2 Shielding Surfaces and Rovibrational Averaging -- 2.3 Isotope Shifts -- 2.4 Intermolecular Effects on Nuclear Shielding -- 2.5 Absolute Shielding Scales -- 3 References -- Chapter 3 Applications of Nuclear Shielding -- 1 Introduction -- 2 Shielding of Particular Nuclear Species -- 2.1 Group l (1H, 2H, 6,7Li, 23Na, 39K, 87Rb, 133Cs) -- 2.1.1 Hydrogen (1H) (I = 1/2) -- 2.1.2 Deuterium (2H) (I = 1) -- 2.1.3 Lithium (6,7Li) (I = 1,2/3) -- 2.1.4 Sodium (23Na) (I = 3/2) -- 2.1.5 Potassium (39K) ( = 3/2) -- 2.1.6 Rubidium (87Rb) (I = 3/2) -- 2.1.7 Caesium (133Cs) (I = 7/2) -- 2.2 Group 2 (9Be, 25Mg, 43Ca, 137Ba) -- 2.2.1 Beryllium (9Be) (I =-3/2) -- 2.2.2 Magnesium (25Mg) (I = -5/2) -- 2.2.3 Calcium (43Ca) (I = 7/2) -- 2.2.4 Barium (137Ba) (I = 3/2) -- 2.3 Group 3 (45Sc, 89Y, 139La, 171Yb) -- 2.3.1 Scandium (45Sc) (I = 7/2) -- 2.3.2 Yttrium (89Y) (I =-1/2) -- 2.3.3 Lanthanum (139La) (I = 7/2) -- 2.3.4 Ytterbium (171Yb) (I = 1/2) -- 2.4 Group 4 (47,49Ti) -- 2.4.1 Titanium (47,49Ti) (I = - 5/2, -7/2) -- 2.5 Group 5 (51V and 93Nb) -- 2.5.1 Vanadium (51V) (I = 7/2) -- 2.5.2 Niobium (93Nb) (I = 9/2) -- 2.6 Group 6 (53Cr, 95Mo, 183W) -- 2.6.1 Chromium (53Cr) (I = - 3/2) -- 2.6.2 Molybdenum (95Mo) (I = 5/2) -- 2.6.3 Tungsten (183W) (I = 1/2) -- 2.7 Group 7 (55Mn, 99Tc, 185,187Re) -- 2.7.1 Manganese (55Mn) (I = 5/2) -- 2.7.2 Technetium (99Tc) (I = 9/2) -- 2.7.3 Rhenium (185,187Re) (I = 5/2).
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2.8 Group 8 (57Fe, 99Ru) -- 2.8.1 Iron(57Fe)(I = 1/2) -- 2.8.2 Ruthenium (99Ru) (I = 3/2) -- 2.9 Group 9 (59Co, 103Rh) -- 2.9.1 Cobalt (59Co) (I = 7/2) -- 2.9.2 Rhodium (103Rh) (I = 1/2) -- 2.10 Group 10 (195Pt) -- 2.10.1 Platinum (195Pt) (I = 1/2) -- 2.11 Group 11 (63Cu, 107,109Ag) -- 2.11.1 Copper (63Cu) (I = 3/2) -- 2.11.2 Silver (107,109Ag) (I = 1/2, 1/2) -- 2.12 Group 12 (67Zn, 111,113Cd, 199Hg) -- 2.12.1 Zinc(67Zn)(I = 5/2) -- 2.12.2 Cadmium (111,113Cd) (I = 1/2, 1/2) -- 2.12.3 Mercury (199Hg) (I = 1/2) -- 2.13 Group 13 (11B, 27Al, 71Ga, 203,205Tl) -- 2.13.1 Boron (11B) (I = 3/2) -- 2.13.2 Aluminium (27Al) (I = 5/2) -- 2.13.3 Gallium (71Ga) (I = 3/2) -- 2.13.4 Thallium (203,205Tl) (I = 1/2, 1/2) -- 2.14 Group 14 (13C, 29Si, 73Ge, 117,119Sn, 207Pb) -- 2.14.1 Carbon (13C) (I = 1/2) -- 2.14.2 Silicon (29Si) (I = 1/2) -- 2.14.3 Germanium (73Ge) (I = 9/2) -- 2.14.4 Tin (117,119Sn) (I = 1/2, 1/2) -- 2.14.5 Lead (207Pb) (I = 1/2) -- 2.15 Group15 (14,15N,31P) -- 2.15.1 Nitrogen (14,15N) (I = 1, 1/2) -- 2.15.2 Phosphorus (31P) (I = 1/2) -- 2.16 Group 16 (17O,33S, 77Se, 125Te) -- 2.16.1 Oxygen (17O) (I = 5/2) -- 2.16.2 Sulfur (33S) (I = 3/2) -- 2.16.3 Selenium (77Se) (I= 1/2) -- 2.16.4 Tellurium (125Te) (I = 1/2) -- 2.17 Group 17 (19F, 35,37Cl) -- 2.17.1 Fluorine (19F) (I = 1/2) -- 2.17.2 Chlorine (35,37Cl) (I= 3/2, 3/2) -- 2.18 Group 18 (3He, 129Xe) -- 2.18.1 Helium (3He) (I = 1/2) -- 2.18.2 Xenon (129Xe) (I =1/2) -- 3 References -- Chapter 4Theoretical Aspects of Spin-Spin Couplings -- 1 Introduction -- 2 Relativistic Calculation of Spin-Spin Couplings -- 3 Ab Initio Calculation of Spin-Spin Couplings -- 3.1 The Effect of Lone Pairs and Electronegativity -- 3.2 Nuclear Motion Corrections -- 3.3 Triple Excitation Effects -- 3.4 Ab Initio Calculations of [1.1.1]Propellane and Bicyclo[1.1.1]pentane -- 3.5 Ab Initio Calculations of Karplus Relations.
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4 Density Functional Theory -- 4.1 Self-interaction Correction -- 4.2 Natural J Coupling Analysis -- 4.3 Conformational and Configurational Aspects -- 4.4 3J(C,H) Couplings in 1-X-Bicyclo[1.1.1]pentanes -- 4.5 Intermolecular Nuclear Spin-Spin Coupling in van der Waals Dimers -- 5 Spin-Spin Couplings Across Hydrogen Bonds -- 5.1 Introduction -- 5.2 19F-1H Coupling Constants -- 5.3 Structural Dependencies of Interresidue Scalar Coupling 3hJ(N, C) -- 5.4 3hJ(31P, 15N) and 2hJ(31P, 1H) Coupling Constants Across Hydrogen Bonds -- 5.5 2hJ(15N, 15N) and lhJ(15N, 1H) Coupling Constants Across Hydrogen Bonds -- 6 Through-space Couplings -- 7 References -- Chapter 5 Applications of Spin-Spin Couplings -- 1 Introduction -- 2 New Methods -- 3 One-bond Couplings to Hydrogen -- 4 One-bond Couplings not Involving Hydrogen -- 5 Two-bond Couplings to Hydrogen -- 6 Two-bond Couplings not Involving Hydrogen -- 7 Three-bond Hydrogen-Hydrogen Couplings -- 8 Three-bond Couplings to Hydrogen -- 9 Three-bond Couplings not Involving Hydrogen -- 10 Couplings over More than Three Bonds and Through Space -- 11 Couplings Through Hydrogen Bonds -- 12 Residual Dipolar Couplings -- 13 References -- Chapter 6 Nuclear Spin Relaxation in Liquids and Gases -- 1 Introduction -- 2 General, Physical and Experimental Aspects of Nuclear Spin Relaxation -- 2.1 General Aspects -- 2.2 Experimental Aspects -- 2.3 Relaxation in Coupled Spin Systems -- 2.4 Dipolar Couplings and Distance Information -- 2.5 Exchange Spectroscopy -- 2.6 Radiation Damping -- 2.7 Quadrupolar Interactions -- 2.8 Intermolecular Dipolar Interaction in Diamagnetic and Paramagnetic Solution -- 2.9 Slow Motions in Glasses -- 2.10 Models for Molecular Dynamics -- 3 Selected Applications of Nuclear Spin Relaxation -- 3.1 Pure Liquids -- 3.2 Non-electrolyte Solutions -- 3.3 Electrolyte Solutions -- 3.4 Molten Salts.
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4 Nuclear Spin Relaxation in Gases -- 5 Self-diffusion in Liquids -- 5.1 Experimental and Theoretical Aspects -- 5.2 Selected Examples -- 6 References -- Chapter 7 Solid-state NMR Spectroscopy -- 1 Introduction -- 2 Reviews and Introductory Articles -- 3 Theory and Numerical Calculations -- 4 Experiment -- 4.1 New Technique Developments -- 4.1.1 1H NMR -- 4.1.2 2D Correlation Spectroscopy -- 4.1.3 2D MQ MAS -- 4.1.4 Other Experimental Aspects -- 4.2 Distance and Angle Measurements by REDOR and Other Solid-state NMR Techniques -- 4.3 NMR Parameters: Experimental and Theoretical Studies -- 4.4 Exotic and Troublesome Nuclei -- 5 Applications -- 5.1 Organic Solids -- 5.2 Organometallic and Coordination Compounds -- 5.3 Natural Products -- 5.4 Biochemical Applications -- 5.4.1 Amino Acids, Peptides and Proteins -- 5.4.2 Lipids and Membranes -- 5.5 Coals and Carbonaceous Materials -- 5.6 Soils and Related Materials -- 5.7 Polymers -- 5.8 Glasses and Amorphous Solids -- 5.9 Micro- and Mesoporous Solids -- 5.10 Surface Science and Catalysis -- 5.11 Inorganic and Other Related Solids -- 6 References -- Chapter 8 Multiple Pulse NMR -- 1 Introduction -- 2 Isotropic Mixing -- 3 NOE, Chemical Exchange, Relaxation and Diffusion -- 3.1 NOE and Chemical Exchange -- 3.2 Relaxation Rate Measurements -- 3.3 Cross-correlated Relaxation Experiments -- 3.4 Diffusion Experiments -- 4 Coupling Constants Measurements -- 4.1 Scalar Couplings -- 4.2 Couplings Across Hydrogen Bonds -- 4.3 Residual Dipolar Couplings -- 5 Inverse Proton Detected Correlation Spectroscopy -- 5.1 Isotope Filtered Experiments -- 5.2 Isotope Edited Experiments -- 5.3 TROSY -- 5.4 Heteronuclear Triple Resonance Experiments -- 6 References -- Chapter 9 NMR of Proteins and Nucleic Acids -- 1 Introduction -- 2 Application and Development of New Methodology -- 2.1 Automated Analysis.
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2.2 Dipolar Couplings -- 2.3 Transverse Relaxation Optimized Spectroscopy (TROSY) -- 3 Solution Structures -- 3.1 Free Proteins -- 3.2 Membrane Proteins -- 3.3 Protein-Small Molecule Complexes -- 3.4 Protein-Protein Complexes -- 3.5 Protein-Nucleic Acid Complexes -- 4 Protein Relaxation and Dynamics -- 5 Protein Folding -- 6 References -- Chapter 10 NMR of Carbohydrates, Lipids and Membranes -- 1 Introduction -- 1.1 Studies of Natural Membrane Assemblies -- 1.2 Hydrogen Bonding and Conformational Studies -- 1.3 Surfactants -- 2 In Vivo NMR Studies, LC-NMR and Metabolomics -- 2.1 Data Bases -- 2.2 NMR in Pharmaceutical Applications -- 2.3 Metabolomics -- 2.4 Proteomics of Enzymes Involved in Polysaccharide Metabolism/Catabolism and Toxicogenomic Approaches -- 3 Natural Products Analysis -- 3.1 Bacteria -- 3.1.1 Mammalian Pathogens -- 3.1.2 Other Bacteria -- 3.2 Mycobacteria -- 3.3 Fungus -- 3.4 Lichen -- 3.5 Algae -- 3.6 Sponges -- 3.7 Plants -- 3.7.1 Polysaccharides -- 3.7.2 Triterpenes -- 3.7.3 Flavanoid Glycosides -- 3.7.4 Lipids -- 3.8 Parasites -- 4 Carbohydrate Binding Proteins (Toxins, Adhesins and Lectins) and Antibody Binding Studies -- 5 Mammalian Glycoconjugates -- 5.1 Glycolipids -- 5.2 Glycoproteins -- 5.3 Proteoglycans -- 5.4 Other Conjugates -- 6 Conformational Studies in Protein Folding Disorders -- 7 References -- Chapter 11 Synthetic Macromolecules -- 1 Introduction -- 2 Primary Structure -- 3 Liquid Crystalline Polymers -- 4 Imaging -- 5 Characterization of the Synthetic Macromolecules -- 6 Dynamics of the Synthetic Macromolecules -- 7 Polymer Blend of the Synthetic Macromolecules -- 8 References -- Chapter 12 NMR in Living Systems -- 1 General Applications and New Methodology -- 1.1 Methodologies -- 1.2 Spectral Analysis -- 1.3 Intracellular Ions and pH -- 2 Cells -- 2.1 Microorganisms -- 2.2 Blood.
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2.3 Cultured Mammalian and Tumour Cells.
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