Note: Inorganic Syntheses -- Preface -- Dedication -- Notice to Contributors and Checkers -- Toxic Substances and Laboratory Hazards -- Contents -- Chapter One: Transition Metal Halide Compounds -- 1. Octahedral Hexatantalum Halide Clusters -- A. Tetradecachlorohexatantalum Octahydrate -- B. Tetradecabromohexatantalum Octahydrate -- C. Tetrakis(benzyltributylammonium) Octadecachlorohexatantalate -- 2. Octahedral Hexamolybdenum Halide Clusters -- A. Tetradecachlorohexamolybdate Hexahydrate (Chloromolybdic Acid) -- B. Hexamolybdenum Dodecachloride -- 3. Ether Complexes of Molybdenum(III) and Molybdenum(IV) Chlorides -- A. Tetrachlorobis(diethyl ether)molybdenum(IV) -- B. Trichlorotris(tetrahydrofuran)molybdenum(III) -- 4. Octahedral Hexatungsten Halide Clusters -- A. Bis(hydroxonium) Tetradecachlorohexatungstate Heptahydrate (Chlorotungstic Acid) -- B. Hexatungsten Dodecachloride -- 5. Trinuclear Tungsten Halide Clusters -- A. Tritungsten Decachloride -- B. Trisodium Tridecachlorotritungstate -- C. Tris(benzyltributylammonium) Tridecachlorotritungstate -- 6. Crystalline and Amorphous Forms of Tungsten Tetrachloride -- A. Crystalline Tungsten Tetrachloride by Solid-State Reduction -- B. Amorphous Tungsten Tetrachloride by Solution-Phase Reduction -- Chapter Two: Cyclopentadienyl Compounds -- 7. Sodium and Potassium Cyclopentadienide -- A. Sodium Cyclopentadienide -- B. Potassium Cyclopentadienide -- 8. (Pentafluorophenyl)cyclopentadiene and its Sodium Salt -- A. (Pentafluorophenyl)cyclopentadiene -- B. Sodium (Pentafluorophenyl)cyclopentadienide -- 9. Bis(η5-pentamethylcyclopentadienyl) Complexes of Scandium -- A. Bis(η5-pentamethylcyclopentadienyl)chloroscandium -- B. Bis(η5-pentamethylcyclopentadienyl)methylscandium -- C. Bis(η5-pentamethylcyclopentadienyl)phenylscandium -- D. Bis(η5-pentamethylcyclopentadienyl)(o-tolyl)scandium. , 10. Bis(η5-pentamethylcyclopentadienyl) Complexes of Titanium, Zirconium, and Hafnium -- A. Bis(η5-pentamethylcyclopentadienyl)dichlorotitanium(IV) -- B. Bis(η5-pentamethylcyclopentadienyl)dichlorozirconium(IV) -- C. Bis(η5-pentamethylcyclopentadienyl)dichlorohafnium(IV) -- 11. Bis(η5-pentamethylcyclopentadienyl) Complexes of Niobium and Tantalum -- A. Bis(η5-pentamethylcyclopentadienyl)dichlorotantalum(IV) -- B. Bis(η5-pentamethylcyclopentadienyl)dichloroniobium(IV) -- 12. Bis(η5-pentamethylcyclopentadienyl) Complexes of Molybdenum -- A. Bis(pentamethylcyclopentadienyl)dichloromolybdenum(IV) -- B. Bis(pentamethylcyclopentadienyl)dihydridomolybdenum(IV) -- 13. (η5-Cyclopentadienyl)tricarbonylmanganese(I) Complexes -- A. (η5-Cyclopentadienyl)tricarbonylmanganese(I) -- B. (η5-Pentamethylcyclopentadienyl)tricarbonylmanganese(I) -- 14. 1,1'-Diaminoferrocene -- A. 1,1'-Dilithioferrocene N,N,N',N'-Tetramethylethylenediamine -- B. 1,1'-Dibromoferrocene -- C. One-Pot Preparation of 1,1'-Dibromoferrocene from Ferrocene -- D. 1,1'-Diaminoferrocene -- E. 1,1'-Diaminoferrocenium Hexafluorophosphate -- F. 1,1'-Diaminoferrocenium Triflate -- 15. Mono(η5-pentamethylcyclopentadienyl) Complexes of Osmium -- A. Bromoosmic Acid -- B. Bis(η5-pentamethylcyclopentadienyl)tetrabromodiosmium(III) -- C. (η5-Pentamethylcyclopentadienyl)(1,5-cyclooctadiene)- bromoosmium(II) -- Chapter Three: Compounds with Metal-Metal Bonds -- 16. Tetra(acetato)dimolybdenum(II) -- 17. Supramolecular Arrays Based on Dimolybdenum Building Blocks -- A. Tetrakis(N,N'-di-p-anisylformamidinato)dimolybdenum(II) -- B. Tris(N,N'-di-p-anisylformamidinato)di(chloro)- dimolybdenum(II,III) -- C. cis-Bis(N,N'-di-p-anisylformamidinato)tetrakis(acetonitrile)- dimolybdenum(II) Bis(tetrafluoroborate) -- D. (μ2-Succinato)bis[tris(N,N"-di-p-anisylformamidinato)- dimolybdenum(II)]. , E. (μ2-η2,η2-Molybdato)bis[tris(N,N'-di-p-anisylformamidinato)- dimolybdenum(II)] -- F. (μ2-N,N'-Diphenylterephthaloyldiamidato)bis[tris(N,N'-di-panisylformamidinato) dimolybdenum(II)] -- G. Molecular Propeller: (μ3-Trimesate)tris[tris(N,N0-di-panisylformamidinato) dimolybdenum(II)] -- H. Molecular Loop: closo-Bis(μ2-malonato)bis[bis(N,N'-di-panisylformamidinato) dimolybdenum(II)] -- I. Molecular Triangle: closo-Tris(μ2-eq,eq-1,4-cyclohexanedicarboxylato) tris[bis(N,N'-di-p-anisylformamidinato)- dimolybdenum(II)] -- J. Molecular Square: closo-Tetrakis(μ2-oxalato)tetrakis[bis(N,N'- di-p-anisylformamidinato)dimolybdenum(II)] -- K. Molecular Cage: closo-Tetrakis(μ3-trimesate)hexakis[bis(N,N'- di-p-anisylformamidinato)dimolybdenum(II)] -- 18. Dimolybdenum and Ditungsten Hexa(alkoxides) -- A. Hexa(tert-butoxy)dimolybdenum(III) -- B. Hexakis(2-trifluoromethyl-2-propoxy)dimolybdenum(III) -- C. Sodium Heptachloropentakis(tetrahydrofuran)ditungstate(III) -- D. Hexa(tert-butoxy)ditungsten(III) -- E. Hexakis(2-trifluoromethyl-2-propoxy)ditungsten(III) -- 19. Linear Trichromium, Tricobalt, Trinickel, and Tricopper Complexes of 2,2'-Dipyridylamide -- A. Dichlorotetrakis(2,2'-dipyridylamido)trichromium(II) -- B. Dichlorotetrakis(2,2'-dipyridylamido)tricobalt(II) -- C. Dichlorotetrakis(2,2'-dipyridylamido)trinickel(II) -- D. Dichlorotetrakis(2,2'-dipyridylamido)tricopper(II) -- E. Bis(acetonitrile)tetrakis(2,2'-dipyridylamido)trichromium(II) Bis(hexafluorophosphate) -- F. Bis(acetonitrile)tetrakis(2,2'-dipyridylamido)tricobalt(II) Bis(hexafluorophosphate) -- G. Bis(acetonitrile)tetrakis(2,2'-dipyridylamido)trinickel(II) Bis(hexafluorophosphate) -- 20. Bis(tetrabutylammonium) Octachloroditechnetate(III) -- A. Tetrabutylammonium Pertechnetate(VII) -- B. Tetrabutylammonium Oxotetrachlorotechnetate(V) -- C. Bis(tetrabutylammonium) Octachloroditechnetate(III). , 21. Diruthenium Formamidinato Complexes -- A. Chlorotris(acetato)(N,N'-di-2,6-xylylformamidinato)- diruthenium(II,III) -- B. trans-Chlorobis(acetato)bis(N,N'-di-2,6-xylylformamidinato)- diruthenium(II,III) -- C. cis-Chlorobis(acetato)bis(N,N'-di-p-anisylformamidinato)- diruthenium(II,III) -- D. Chloro(acetato)tris(N,N'-di-p-anisylformamidinato)- diruthenium(II,III) -- E. Chlorotetrakis(N,N'-di-p-anisylformamidinato)- diruthenium(II,III) -- 22. Heptacarbonyl(disulfido)dimanganese(I). -- 23. Di(carbido)tetracosa(carbonyl)decaruthenate(2-) Salts -- A. Calcium Di(carbido)tetracosa(carbonyl)decaruthenate(2-) -- B. Bis[bis(triphenylphosphoranylidene)ammonium] Di(carbido)tetracosa(carbonyl)decaruthenate(2-) -- Chapter Four: General Transition Metal Compounds -- 24. Bis(1,2-bis(dimethylphosphano)ethane)tricarbonyltitanium(0) and Hexacarbonyltitanate(2-) -- A. Bis(1,2-bis(dimethylphosphano)ethane)- tricarbonyltitanium(0) -- B. Bis[18-crown-6)(acetonitrile)potassium] Hexacarbonyltitanate(2-) -- 25. Tungsten Benzylidyne Complexes -- A. Trichloro(1,2-dimethoxyethane)benzylidynetungsten(VI) -- B. Chloro Bis[1,2-bis(diphenylphosphino)ethane]- benzylidynetungsten(IV) -- 26. Tungsten Oxytetrachloride and (Acetonitrile)tetrachlorotungsten Imido Complexes -- A. Tungsten Oxytetrachloride -- B. (Acetonitrile)tetrachloro(phenylimido)tungsten(VI) -- C. (Acetonitrile)tetrachloro(2-propylimido)tungsten(VI) -- D. (Acetonitrile)tetrachloro(2-propenylimido)tungsten(VI) -- 27. Tungsten Oxytetrachloride and Several Tungstate Salts -- A. Tungsten Oxytetrachloride -- B. Bis(tetrabutylammonium) Hexapolytungstate -- C. Di(cetylpyridinium) Peroxoditungstate -- D. Bis(tetrabutylammonium) Phenylphosphonatodiperoxotungstate -- 28. Bromotricarbonyldi(pyridine)manganese(I) -- 29. Bis(tetraethylammonium) fac-Tribromotricarbonylrhenate(I) and -Technetate(I). , A. Bis(tetraethylammonium) fac-Tribromotricarbonylrhenate(I) -- B. Bis(tetraethylammonium) fac-Trichlorotricarbonyltechnetate( I) -- 30. Methyl(oxo)rhenium(V) Complexes with Chelating Ligands -- A. Methyl(oxo)(1,2-ethanedithiolato)rhenium(V) Dimer -- B. Methyl(oxo)bis(2-oxyquinoline)rhenium(V) -- C. Methyl(oxo)(2,2'-thiodiacetato)(triphenylphosphine)- rhenium(V) -- 31. Hexahydridoferrate(II) Salts -- A. Tetrakis[bromobis(tetrahydrofuran)magnesium] Hexahydridoferrate( II) -- B. Tetrakis[2-methyl-2-propoxomagnesium] Hexahydridoferrate(II) -- 32. Tris(allyl)iridium and -Rhodium -- A. Allyllithium -- B. mer-Trichlorotris(tetrahydrothiophene)iridium(III) -- C. mer-Trichlorotris(tetrahydrothiophene)rhodium(III) -- D. Tris(allyl)iridium(III) -- E. Tris(allyl)rhodium(III) -- 33. Trinuclear Palladium(II) Acetate -- Chapter Five: Main Group Compounds and Ligands -- 34. Monocarbaborane Anions with 10 or 12 Vertices -- A. Tetraethylammonium arachno-6-Carba-decaboranate(14) -- B. Tetraethylammonium closo-2-Carba-decaboranate(10) -- C. Tetraethylammonium closo-1-Carba-decaboranate(10) -- D. Tetraethylammonium closo-1-Carba-dodecaboranate(12) -- E. Tetraethylammonium nido-6-Phenyl-6-carbadecaboranate( 12) -- F. Tetraethylammonium closo-2-Phenyl-2-carbadecaboranate( 10) -- G. Tetraethylammonium closo-1-Phenyl-1-carbadecaboranate( 10) -- H. Tetraethylammonium closo-1-Phenyl-1-carbadodecaboranate( 12) -- 35. Tetrakis(5-tert-butyl-2-hydroxyphenyl)ethene -- A. 5,5'-Di-tert-butyl-2,2'-dimethoxybenzophenone -- B. Titanium Trichloride 1,2-Dimethoxyethane (1:1.5) -- C. Tetrakis(5-tert-butyl-2-methoxyphenyl)ethene -- D. Tetrakis(5-tert-butyl-2-hydroxyphenyl)ethene -- 36. Electrochemical Synthesis of Tetraethylammonium Tetrathiooxalate -- 37. Mid-Infrared Emitting Lead Selenide Nanocrystal Quantum Dots -- A. Lead Selenide NQDs Emitting at 2.5 μm (0.50 eV). , B. Lead Selenide NQDs Emitting at 2.8 μm (0.44 eV).