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  • 1
    Online Resource
    Online Resource
    Hauppauge :Nova Science Publishers, Incorporated,
    Keywords: Laser plasmas. ; Laser-induced breakdown spectroscopy. ; Spectrum analysis. ; High power lasers. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (95 pages)
    Edition: 1st ed.
    ISBN: 9781628087734
    DDC: 543/.5
    Language: English
    Note: Intro -- SPECTROSCOPIC ANALYSIS OF CHEMICAL SPECIES IN CARBON PLASMAS INDUCED BY HIGH-POWER IR CO2 LASER -- LIBRARY OF CONGRESS CATALOGING-IN-PUBLICATION DATA -- CONTENTS -- PREFACE -- Chapter 1 INTRODUCTION -- Chapter 2 FUNDAMENTALS OF LASER INDUCED BREAKDOWN SPECTROSCOPY (LIBS) -- 2.1. NATURE OF THE PLASMAS -- 2.2. LOCAL THERMODYNAMIC EQUILIBRIUM (LTE). MODEL FOR THE PLASMA -- 2.3. LIB PLASMA -- 2.3.1. Initiation Mechanism: Multiphoton Ionization (MPI) and Electron Impact Ionization (EII) -- 2.3.2. Electron Attachment, Recombination and Diffusion -- 2.4. ELEMENTS OF LIBS -- 2.4.1. Line Radiation -- 2.4.2. Continuum Radiation -- 2.4.3. Line Broadening -- Determination of Electron Number Density from Stark Broadening of Spectral Lines -- Natural Broadening -- Doppler Broadening -- Pressure Broadening -- 2.4.4. Determination of Excitation, Vibrational and Rotational Temperatures -- 2.4.5. Ionization Degree of the Plasmas: Saha Equation -- 2.5. EFFECTS OF PHYSICAL VARIABLES IN LIBS -- 2.5.1. Laser Parameters -- 2.5.2. Focal Properties -- 2.5.3. Laser Absorption in the Plasma -- Chapter 3 EXPERIMENTAL -- 3.1. PULSED TEA CO2 LASER -- 3.2. SPECTROGRAPHS AND DETECTORS -- 3.3. SCHEMATIC DIAGRAM FOR LIBS -- 3.4. TIMING CONSIDERATIONS -- Chapter 4 RESULTS AND DISCUSSION -- 4.1. IDENTIFICATION OF THE CHEMICAL SPECIES IN THE PULSE LASER ABLATION PLASMA PLUME -- 4.2. Plasma Excitation, Vibrational and Rotational Temperature Measurements -- 4.3. IONIZATION DEGREE OF THE PLASMA -- 4.4. ELECTRON NUMBER DENSITY -- 4.5. EFFECT OF LASER IRRADIANCE -- 4.6. EFFECT OF AMBIENT PRESSURE ON THE PLASMA -- 4.7. SPATIAL CHARACTERIZATION -- 4.8. TEMPORAL EVOLUTION OF THE PLASMA -- Chapter 5 CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES -- INDEX.
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  • 2
    Online Resource
    Online Resource
    Berlin, Heidelberg : Springer Berlin Heidelberg
    Keywords: Analytical biochemistry ; Chemistry, Physical organic ; Polymers ; Laser physics ; Nanotechnology ; Chemistry ; Aufsatzsammlung ; Supramolekül ; Fluoreszenz ; Makromolekül ; Fluoreszenz ; Nanostrukturiertes Material ; Fluoreszenz
    Type of Medium: Online Resource
    Pages: Online-Ressource (digital)
    ISBN: 9783540739289
    Series Statement: Springer Series on Fluorescence 4
    RVK:
    Language: English
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  • 3
    Publication Date: 2021-06-28
    Description: Biological data are presented on two specimens of Taningia danae , an adult female caught by a trawler in Galician waters (north-west Spain) and a juvenile caught in a deep-water research trawl in Scottish waters (UK). The species has not previously been recorded in either area, although its presence has been inferred from beaks found in sperm whale stomach contents.
    Type: Article , PeerReviewed
    Format: text
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  • 4
    Publication Date: 2024-06-12
    Description: This dataset provides the values of stable carbon and nitrogen stable isotopes in bulk muscle samples of 11 species of cetacea from the Macaronesian regions (Canary, Madeira, and Azores Islands) collected between 1996 and 2018. The values of nitrogen stable isotopes in amino acids of muscle samples of the common dolphin (Delphinus delphis) were also provided. The samples were collected from stranded animals by trained personnel. Cetacean samples were obtained from necropsies of stranded cetaceans following a standard protocol defined by the European Cetacean Society (after Kuiken and García Hartmann 1991). Additional data included body length, age (adult, juvenile) and sex for each animal, along with carbon, nitrogen, and lipid content of muscle samples. Isotope data for bulk samples included values for samples with and without lipids. Exact latitude and longitude coordinates for each sample are not available, geographical position of the center of a circle including each island is given instead. Samples were freeze dried or dried (60°C, 48h) before analysis. Stable isotopes in bulk muscle samples were analysed in an isotope-ratio mass spectrometer coupled to an elemental analyser. Aliquots of each sample were analysed whole or after lipid extraction with trichloromethane:methanol (Bligh and Dyer, 1959). Stable nitrogen isotopes in amino acids were analysed after hydrolisis and derivatization of samples in an isotope-ratio mass spectrometer coupled to a gas chromatograph. Details on the analytical procedures can be found in Bode et al. (2021).
    Keywords: Alanine; Alanine, δ15N; Area/locality; Aspartamine and Aspartic acid; Aspartamine and Aspartic acid, δ15N; Atlantic spotted dolphin; bottlenose dolphin; Bryde's whale; Calculated; Carbon, total; Carbon/Nitrogen ratio; Carbon isotopes; Cetacea_Faial; Cetacea_Fuerteventura; Cetacea_Gran_Canaria; Cetacea_La_Gomera; Cetacea_La_Graciosa; Cetacea_La_Palma; Cetacea_Lanzarote; Cetacea_Madeira; Cetacea_Pico; Cetacea_Porto_Santo; Cetacea_Sao_Miguel; Cetacea_Tenerife; Cetacea_Terceira; common dolphin; Cuvier's beaked whale; DATE/TIME; DEPTH, water; Elemental analyser - isotope ratio mass spectrometry; Event label; Faial, Azores Islands, Portugal; fin whale; Fuerteventura, Canary Islands, Spain; Gas chromatography - Isotope ratio mass spectrometer (GC-IRMS); Glutamine and Glutamic acid; Glutamine and Glutamic acid, δ15N; Glycine; Glycine, δ15N; Gran Canaria, Canary Islands, Spain; GRAV; Gravimetry; Isoleucine; Isoleucine, δ15N; La Gomera, Canary Islands, Spain; La Graciosa, Canary Islands, Spain; Lanzarote, Canary Islands, Spain; La Palma, Canary Islands, Spain; Latitude of event; Length, total; Leucine; Leucine, δ15N; Life stage; Lipids; Location; Longitude of event; Lysine; Lysine, δ15N; Madeira, Madeira Islands, Portugal; Methionine; Methionine, δ15N; Necropsy after Kuiken and García Hartmann (1991); Nitrogen, total; nitrogen isotopes; Phenylalanine; Phenylalanine, δ15N; Pico, Azores Islands, Portugal; Porto Santo, Madeira Islands, Portugal; Proline; Proline, δ15N; pygmy sperm whale; Risso's dolphin; Sample ID; Sao Miguel, Azores Islands, Portugal; Serine; Serine, δ15N; Sex; short-finned pilot whale; Species; Species code; sperm whale; Stable isotopes; striped dolphin; SUMMER; Sustainable Management of Mesopelagic Resources; Tape measure; Tenerife, Canary Islands, Spain; Terceira, Azores Islands, Portugal; Threonine; Threonine, δ15N; Uniform resource locator/link to reference; Valine; Valine, δ15N; Visual observation; Year of observation; δ13C; δ15N
    Type: Dataset
    Format: text/tab-separated-values, 2379 data points
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 76 (1972), S. 712-720 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of medicinal chemistry 20 (1977), S. 970-974 
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 53-59 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A model for radiative transport of electronic excitation energy in solution is presented and applied to the time-resolved and steady-state fluorescence of DPA (9, 10-diphenylanthracene) in benzene. The model predicts a nonexponential and wavelength-dependent decay at high concentrations, in agreement with experimental results. Recovered parameters, along with the time-resolved emission spectrum, are interpreted on the basis of a progression of the excitation with time farther into the cell, after the excitation pulse.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 8143-8149 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A model for reversible monomer–excimer kinetics that considers the time dependence of the excimer formation rate coefficient is proposed and tested for pyrene in cyclohexanol from 25 up to 85 °C. Simultaneous analysis of the monomer and excimer experimental decay curves allows the determination of all the relevant parameters for this reaction. The diffusion coefficient follows an Arrhenius plot with activation energy of 36±1 KJ mol−1, the encounter radius varies between 7.3 and 8.9 A(ring), and the intrinsic rate constant for excimer formation varies between 2.4×109 and 1.1×1010 M−1 s−1. The intrinsic reciprocal lifetime of the excimer follows an Arrhenius plot with activation energy of 12±1 KJ mol−1, and the rate constant for excimer dissociation, determined for high temperatures (T〉55 °C) when reversibility is important, has different values depending whether geminate pair effects are considered or not in the analysis. The binding energy of pyrene excimer obtained considering pair effects (ΔH=32±2 KJ mol−1) agrees with the published values for nonviscous solvents.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 1817-1824 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A model for reversible monomer–excimer kinetics is developed, taking into account that different distributions of monomers around the excited ones are created by light absorption and excimer dissociation. The excimer formation rate coefficient departs from the Collins–Kimball equation owing to reversibility, originating significant deviations to Birks' kinetics in the monomer and excimer decays. The contribution of the geminate pair created by excimer dissociation on the overall kinetics is significant for low monomer concentrations and high viscosities. Simultaneous analysis of the monomer and excimer decay curves according to the model developed should allow to extract all the relevant information concerning the excimer formation diffusion controlled process.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 8048-8055 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Fluorescence depolarization by energy transfer resulting from dipole–dipole interaction (Förster type) is studied in donor–acceptor pairs of like and unlike chromophores at a fixed distance and with random and uncorrelated static orientations. For unlike chromophores, the acceptor anisotropy decay is shown to display three different extreme types of behavior. When the intrinsic decay rate of the acceptor is much faster than both the transfer rate and the donor intrinsic decay rate, the acceptor anisotropy decays from a positive value, then rises and passes through a maximum, and finally tends to a negative limiting value, yielding a zero steady-state value. The existence of a maximum is shown to be due to the peculiar relation between the orientation factor and the average angle formed by the donor and acceptor transition moments. For pairs of like chromophores, the exact anisotropy is calculated and compared with that given by an approximate treatment. It is also shown that the anisotropy of the indirectly excited partner varies with time, tending to zero, in contradiction to previous work, where it is reported to be 4% of that of the directly excited chromophore.
    Type of Medium: Electronic Resource
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