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  • 1
    Publication Date: 2024-02-05
    Description: Intact polar lipids (IPLs) were extracted by a modified Bligh and Dyer extraction. The total lipid extract was seperated via column chromatography (activated Si-column). Displayed data shows the analyzed polar subfraction of the individual sediment intervals.
    Keywords: Ancient carbon; arctic fjord; Betaine lipids per unit sediment mass; Carbon cycle; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Diphosphatidylglycerol per unit sediment mass; GC; Gravity corer; HH14-897-GC-MF; Hornsund, Spitsbergen; Intact polar lipids; Lyso-Diphosphatidylglycerol per unit sediment mass; Phosphatidylcholine per unit sediment mass; Phosphatidyldimethylethanolamine per unit sediment mass; Phosphatidylethanolamine per unit sediment mass; Phosphatidylglycerol per unit sediment mass; Phosphatidylmethylethanolamine per unit sediment mass
    Type: Dataset
    Format: text/tab-separated-values, 58 data points
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2024-02-05
    Description: Intact polar lipids (IPLs) were extracted by a modified Bligh and Dyer extraction. The total lipid extract was seperated via column chromatography (activated Si-column). Displayed data shows the analyzed polar subfraction of the individual sediment intervals as wt. % of the polar fraction.
    Keywords: Ancient carbon; arctic fjord; Betaine lipids, percentage of polar fraction; Carbon cycle; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Diphosphatidylglycerol, percentage of polar fraction; GC; Gravity corer; HH14-897-GC-MF; Hornsund, Spitsbergen; Intact polar lipids; Lyso-Diphosphatidylglycerol, percentage of polar fraction; Phosphatidylcholine, percentage of polar fraction; Phosphatidyldimethylethanolamine, percentage of polar fraction; Phosphatidylethanolamine, percentage of polar fraction; Phosphatidylglycerol, percentage of polar fraction; Phosphatidylmethylethanolamine, percentage of polar fraction
    Type: Dataset
    Format: text/tab-separated-values, 58 data points
    Location Call Number Limitation Availability
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  • 3
    Publication Date: 2024-02-05
    Description: Intact polar lipids (IPLs) were extracted by a modified Bligh and Dyer extraction. The total lipid extract was seperated via column chromatography (activated Si-column). Displayed data shows the analyzed polar subfraction of the individual sediment intervals.
    Keywords: Ancient carbon; arctic fjord; Betaine lipids per unit sediment mass; Carbon cycle; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Diphosphatidylglycerol per unit sediment mass; GC; Gravity corer; HH14-897-GC-MF; Hornsund, Spitsbergen; Intact polar lipids; Lyso-Diphosphatidylglycerol per unit sediment mass; Phosphatidylcholine per unit sediment mass; Phosphatidyldimethylethanolamine per unit sediment mass; Phosphatidylethanolamine per unit sediment mass; Phosphatidylglycerol per unit sediment mass; Phosphatidylmethylethanolamine per unit sediment mass
    Type: Dataset
    Format: text/tab-separated-values, 46 data points
    Location Call Number Limitation Availability
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  • 4
    Publication Date: 2024-02-05
    Description: Intact polar lipids (IPLs) were extracted by a modified Bligh and Dyer extraction. The total lipid extract was seperated via column chromatography (activated Si-column). Displayed data shows the analyzed polar subfraction of the individual sediment intervals as wt. % of the polar fraction.
    Keywords: Ancient carbon; arctic fjord; Betaine lipids, percentage of polar fraction; Carbon cycle; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Diphosphatidylglycerol, percentage of polar fraction; GC; Gravity corer; HH14-897-GC-MF; Hornsund, Spitsbergen; Intact polar lipids; Lyso-Diphosphatidylglycerol, percentage of polar fraction; Phosphatidylcholine, percentage of polar fraction; Phosphatidyldimethylethanolamine, percentage of polar fraction; Phosphatidylethanolamine, percentage of polar fraction; Phosphatidylglycerol, percentage of polar fraction; Phosphatidylmethylethanolamine, percentage of polar fraction
    Type: Dataset
    Format: text/tab-separated-values, 40 data points
    Location Call Number Limitation Availability
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  • 5
    Publication Date: 2024-02-05
    Description: Surface DIC radiocarbon-values were estimated using Finite-volumE Sea ice-Ocean Model FESOM255 equipped with radiocarbon56 (neglecting marine biological processes).
    Keywords: Ancient carbon; arctic fjord; Carbon cycle; compound specific radiocarbon dating; DATE/TIME; Fraction modern carbon; Hornsund_fjord; Intact polar lipids; Modeled
    Type: Dataset
    Format: text/tab-separated-values, 171 data points
    Location Call Number Limitation Availability
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  • 6
    Publication Date: 2024-02-05
    Description: Fatty acid concentrations were extracted and purified with wet chemical methods (details in publication) and quantified by an internal standard (19-MA) using a GC-FID.
    Keywords: 12-methyltetradecanoic acid, standard deviation; 12-methyltetradecanoic acid per unit sediment mass; 14-methylpentadecanoic acid, standard deviation; 14-methylpentadecanoic acid per unit sediment mass; Ancient carbon; arctic fjord; Carbon cycle; compound specific radiocarbon dating; DEPTH, sediment/rock; Docosahexaenoic acid, standard deviation; Docosahexaenoic acid per unit sediment mass; Docosanoic acid, standard deviation; Docosanoic acid per unit sediment mass; Eicosapentaenoic acid, standard deviation; Eicosapentaenoic acid per unit sediment mass; Eicosatetraenoic acid, standard deviation; Eicosatetraenoic acid per unit sediment mass; Gas chromatography - Flame Ionization Detection (GC-FID); GC; Gravity corer; Heneicosanoic acid, standard deviation; Heneicosanoic acid per unit sediment mass; Heptadecanoic acid, standard deviation; Heptadecanoic acid per unit sediment mass; Hexacosanoic acid, standard deviation; Hexacosanoic acid per unit sediment mass; Hexadecanoic acid, standard deviation; Hexadecanoic acid per unit sediment mass; Hexadecenoic acid, standard deviation; Hexadecenoic acid per unit sediment mass; HH14-897-GC-MF; Hornsund, Spitsbergen; Icosanoic acid, standard deviation; Icosanoic acid per unit sediment mass; Intact polar lipids; Nonacosanoic acid, standard deviation; Nonacosanoic acid per unit sediment mass; Nonadecanoic acid, standard deviation; Nonadecanoic acid per unit sediment mass; Octacosanoic acid, standard deviation; Octacosanoic acid per unit sediment mass; Octadec-11-enoic acid, standard deviation; Octadec-11-enoic acid per unit sediment mass; Octadec-9-enoic acid, standard deviation; Octadec-9-enoic acid per unit sediment mass; Octadecadienoic acid, standard deviation; Octadecadienoic acid per unit sediment mass; Octadecanoic acid, standard deviation; Octadecanoic acid per unit sediment mass; Pentacosanoic acid, standard deviation; Pentacosanoic acid per unit sediment mass; Pentadecanoic acid, standard deviation; Pentadecanoic acid per unit sediment mass; Tetracosanoic acid, standard deviation; Tetracosanoic acid per unit sediment mass; Tetradecanoic acid, standard deviation; Tetradecanoic acid per unit sediment mass; Triacontanoic acid, standard deviation; Triacontanoic acid per unit sediment mass; Tricosanoic acid, standard deviation; Tricosanoic acid per unit sediment mass
    Type: Dataset
    Format: text/tab-separated-values, 896 data points
    Location Call Number Limitation Availability
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  • 7
    Publication Date: 2024-02-05
    Description: Intact polar lipids (IPLs) were extracted by a modified Bligh and Dyer extraction. The total lipid extract was seperated via column chromatography (activated Si-column). Displayed data shows the analyzed polar subfraction of the individual sediment intervals.
    Keywords: Ancient carbon; arctic fjord; Betaine lipids per unit sediment mass; Carbon cycle; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Diphosphatidylglycerol per unit sediment mass; GC; Gravity corer; HH14-897-GC-MF; Hornsund, Spitsbergen; Intact polar lipids; Lyso-Diphosphatidylglycerol per unit sediment mass; Phosphatidylcholine per unit sediment mass; Phosphatidyldimethylethanolamine per unit sediment mass; Phosphatidylethanolamine per unit sediment mass; Phosphatidylglycerol per unit sediment mass; Phosphatidylmethylethanolamine per unit sediment mass
    Type: Dataset
    Format: text/tab-separated-values, 40 data points
    Location Call Number Limitation Availability
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  • 8
    Publication Date: 2024-02-05
    Description: GDGT concentrations were extracted and purified with wet chemical methods (details in publication) and quantified by an internal standard (C46) using a GC-MS
    Keywords: Acyclic glycerol dibiphytanyl glycerol tetraether; Acyclic glycerol dibiphytanyl glycerol tetraether, standard deviation; Ancient carbon; arctic fjord; Branched glycerol dialkyl glycerol tetraether, Ia; Branched glycerol dialkyl glycerol tetraether, Ia, standard deviation; Branched glycerol dialkyl glycerol tetraether, Ib; Branched glycerol dialkyl glycerol tetraether, Ib, standard deviation; Branched glycerol dialkyl glycerol tetraether, Ic; Branched glycerol dialkyl glycerol tetraether, Ic, standard deviation; Branched glycerol dialkyl glycerol tetraether, IIa (5); Branched glycerol dialkyl glycerol tetraether, IIa (5), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIa (6); Branched glycerol dialkyl glycerol tetraether, IIa (6), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIb (5); Branched glycerol dialkyl glycerol tetraether, IIb (5), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIb (6); Branched glycerol dialkyl glycerol tetraether, IIb (6), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIc (5); Branched glycerol dialkyl glycerol tetraether, IIc (5), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIc (6); Branched glycerol dialkyl glycerol tetraether, IIc (6), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIIa (5); Branched glycerol dialkyl glycerol tetraether, IIIa (5), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIIa (6); Branched glycerol dialkyl glycerol tetraether, IIIa (6), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIIb (5); Branched glycerol dialkyl glycerol tetraether, IIIb (5), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIIb (6); Branched glycerol dialkyl glycerol tetraether, IIIb (6), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIIc (5); Branched glycerol dialkyl glycerol tetraether, IIIc (5), standard deviation; Branched glycerol dialkyl glycerol tetraether, IIIc (6); Branched glycerol dialkyl glycerol tetraether, IIIc (6), standard deviation; Carbon cycle; compound specific radiocarbon dating; Crenarchaeol; Crenarchaeol, standard deviation; Crenarchaeol isomer; Crenarchaeol isomer, standard deviation; DEPTH, sediment/rock; Dicyclic glycerol dibiphytanyl glycerol tetraether; Dicyclic glycerol dibiphytanyl glycerol tetraether, standard deviation; Gas chromatography - Mass spectrometry (GC-MS); GC; Gravity corer; HH14-897-GC-MF; Hornsund, Spitsbergen; Hydroxylated acyclic glycerol dialkyl glycerol tetraether; Hydroxylated acyclic glycerol dialkyl glycerol tetraether, standard deviation; Hydroxylated dicyclic glycerol dibiphytanyl glycerol tetraether; Hydroxylated dicyclic glycerol dibiphytanyl glycerol tetraether, standard deviation; Hydroxylated monocyclic glycerol dibiphytanyl glycerol tetraether; Hydroxylated monocyclic glycerol dibiphytanyl glycerol tetraether, standard deviation; Intact polar lipids; Monocyclic glycerol dibiphytanyl glycerol tetraether; Monocyclic glycerol dibiphytanyl glycerol tetraether, standard deviation; Tricyclic glycerol dibiphytanyl glycerol tetraether; Tricyclic glycerol dibiphytanyl glycerol tetraether, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 1056 data points
    Location Call Number Limitation Availability
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  • 9
    Publication Date: 2024-02-05
    Description: Intact polar lipids (IPLs) were extracted by a modified Bligh and Dyer extraction. The total lipid extract was seperated via column chromatography (activated Si-column). Displayed data shows the analyzed polar subfraction of the individual sediment intervals as wt. % of the polar fraction.
    Keywords: Ancient carbon; arctic fjord; Betaine lipids, percentage of polar fraction; Carbon cycle; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Diphosphatidylglycerol, percentage of polar fraction; GC; Gravity corer; HH14-897-GC-MF; Hornsund, Spitsbergen; Intact polar lipids; Lyso-Diphosphatidylglycerol, percentage of polar fraction; Phosphatidylcholine, percentage of polar fraction; Phosphatidyldimethylethanolamine, percentage of polar fraction; Phosphatidylethanolamine, percentage of polar fraction; Phosphatidylglycerol, percentage of polar fraction; Phosphatidylmethylethanolamine, percentage of polar fraction
    Type: Dataset
    Format: text/tab-separated-values, 46 data points
    Location Call Number Limitation Availability
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  • 10
    Publication Date: 2024-02-12
    Description: Between 2019 and 2022 three sediment cores HH14-897-MF-GC (2014), He519_2-3 (2018), and He560_26-2 (2020) were analyzed using biogeochemical markers to assess organic carbon dynamics and its bio-availability in the Hornsund Fjord (Svalbard) sediments. Depositional history was assessed by 210Pb+137Cs data (obtained by γ-spectrometer) building the basis for associated sedimentary age models (Bruel & Sabatier, 2020), with bulk total organic carbon concentrations (using an element analyzer) and dual C-isotopes of δ13C (obtained by isotope ration mass spectrometer) and F14C (by accelerator mass spectrometry) (Werner & Brand, 2001, Brodie et al. 2011 and Mollenhauer et al., 2021). Additionally, lipid biomarker were extracted, separated, and quantified with wet chemical perpetrations of n-alkanes (Wei, 2020) (quantified with gas chromatography – flame ionization detector), fatty acids (quantified with gas chromatography – flame ionization detector) (Wei, 2020), and GDGTs (Hopmans, 2016) (quantified with gas chromatography – mass spectrometry). Included are datasets of associated biomarker indices of Carbon Preference Index (CPI) (Bray & Evans, 1961), Branched and Isoprenoid Tetraether (BIT) Index (Hopmann et al., 2004), and Terrestrial Aquatic Ratio (TAR) of fatty acids (Meyers, 1997). Further microbial utilization and bio-availability of petrogenic- and marine organic carbon was assed using Intact Polar Lipid (IPL) based compound specific radiocarbon analysis (CSRA) in combination with a DI14C age model of the local surface waters. IPLs were extracted form sediments with a modified Bligh and Dyer (1959) and subsequently separated with wet-chemical seperations (Slater, 2006). CSRA (Mollenhauer et al., 2021) of IPLs was performed on purified single compound fatty acid (FA) methyl esters of the IPL precursor lipids (Wei et al., 2021). The bio-availability of petrogenic organic carbon was based on CSRA data of IPL-FAs using an isotope mass balance with two endmembers of fossil petrogenic and modern marine primary production (DI14C age model of the local surface waters) (Ruben et al., 2022). For the DI14C age model of the local surface waters simulations were run using the Finite-volumE Sea ice-Ocean Model FESOM2 (Danilov et al., 2017) equipped with radiocarbon (Lohmann et al., 2020). Data validity was assessed by relative concentrations of IPLs in the radiocarbon analyzed PL-fraction (Wörmer et al., 2013). Detailed dataset interpretation can be found in Ruben et al. (2023).
    Keywords: Ancient carbon; arctic fjord; Carbon cycle; compound specific radiocarbon dating; Intact polar lipids
    Type: Dataset
    Format: application/zip, 29 datasets
    Location Call Number Limitation Availability
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