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  • 1
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Fries1 observed that, in spite of extensive investigation of the anaerobic degradation of DDT, little has been firmly established except that TDE is a major degradation product. In the present study, the identification of p,p'-DDCN, as an important nitrogen-containing environmental breakdown ...
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 232 (1971), S. 327-330 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Our studies were designed to discover the fate of oleic acid in an aquatic sediment. The basis of our experiments was to add 9,10-3H, l-14C-oleic acid to the upper layers of the Recent sediments of the Severn Estuary and then to isolate the labelled products of short term diagenesis. The ratios of ...
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 319 (1984), S. 126-131 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Summary ‘Physico-chemical speciation’ is presented as a concept to describe the environmental chemistry of organic compounds in aquatic systems, using polycyclic aromatic hydrocarbons as an example. Survey data and experimental results are reported which demonstrate the presence of different physico-chemical species of PAH in the Tamar Estuary, UK. The degree, and hence chemistry of binding of PAH to particulates in the Tamar is shown to be incompatible with current sorption modelling techniques. This finding has extensive repercussions on prediction of the aquatic chemistry of PAH, including availibility of the compounds for fates such as photo-oxidation and biological uptake/ toxicity.
    Notes: Zusammenfassung Die „physikalisch-chemische Speziation“ wird dargestellt zur Beschreibung der Umweltchemie organischer Verbindungen in aquatischen Systemen. Dabei dienen die PAH als Beispiel. Es werden Meßergebnisse und experimentelle Befunde gegeben, die die Anwesenheit verschiedener physikalisch-chemischer Spezien von PAH in der Mündung des Tamar-Flusses (UK) demonstrieren. Es wird gezeigt, daß der Grad und damit der Chemismus der Teilchenbindung von PAH im Tamarfluß nicht den üblichen Sorptionsmodellen entspricht. Diese Feststellung hat beträchtliche Auswirkungen auf die Voraussehbarkeit des aquatischen Chemismus der PAH einschließlich der Verfügbarkeit dieser Verbindungen für Photooxidation und biologische Aufnahme (Toxizität).
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  • 4
    ISSN: 1573-5117
    Keywords: paleolimnology ; annual laminations ; magnetism ; sediment influx ; sediment chemistry ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The sediments of Loe Pool, a eutrophic coastal lake in south west England, consist largely of laminated clays and clay-gyttjas. Studies of the diatom microstratigraphy of frozen sediment cores from the Pool indicate that the laminations are annual, and that they contain pairs of light and dark bands formed by seasonal variations in the supply of sediment to the Pool from its catchment. Analysis of the magnetic properties of individual laminations demonstrates the presence of physical and mineralogical microstratigraphic variations, which may also be related to seasonality. A varve chronology, which is confirmed by 137Cs analysis and historical records, has been used to provide a timescale for the interpretation of data from other paleolimnological studies. A close agreement between variations in the abundance of sedimentary Sn, and the history of mining in the catchment, has been found. Similarly, analysis of total organic matter, total phosphorus, sedimentary chlorophyll a, sterols, diatoms and Cladocera in the uppermost sediments all indicate eutrophication of the Pool in the period AD 1940 to the present.
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