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  • 1
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    Unknown
    PANGAEA
    In:  Supplement to: Lehmann, Nadine; Granger, Julie; Kienast, Markus; Brown, Kevin S; Rafter, Patrick A; Martínez Méndez, Gema; Mohtadi, Mahyar (2018): Isotopic evidence for the evolution of subsurface nitrate in the Western Equatorial Pacific. Journal of Geophysical Research: Oceans, 123(3), 1684-1707, https://doi.org/10.1002/2017JC013527
    Publication Date: 2023-03-03
    Description: Subsurface waters from both hemispheres converge in the Western Equatorial Pacific (WEP), some of which form the Equatorial Undercurrent (EUC) that influences equatorial Pacific productivity across the basin. Measurements of nitrogen (N) and oxygen (O) isotope ratios in nitrate (d15N-NO3 and d18O-NO3), the isotope ratios of dissolved inorganic carbon (d13C-DIC), and complementary biogeochemical tracers reveal that northern and southern WEP waters have distinct biogeochemical histories. Organic matter remineralization plays an important role in setting the nutrient characteristics on both sides of the WEP. However, remineralization in the northern WEP contributes a larger concentration of the nutrients, consistent with the older "age" of northern thermocline- and intermediate-depth waters. Remineralization introduces a relatively low d15N-NO3 to northern waters, suggesting the production of sinking organic matter by N2 fixation at the surface - consistent with the notion that N2 fixation is quantitatively important in the North Pacific. In contrast, remineralization contributes elevated d15N-NO3 to the southern WEP thermocline, which we hypothesize to derive from the vertical flux of high-d15N material at the southern edge of the equatorial upwelling. This signal potentially masks any imprint of N2 fixation from South Pacific waters. The observations further suggest that the intrusion of high d15N-NO3 and d18O-NO3 waters from the eastern margins is more prominent in the northern than southern WEP. Together, these north-south differences enable the examination of the hemispheric inputs to the EUC, which appear to derive predominantly from southern hemisphere waters.
    Keywords: Center for Marine Environmental Sciences; CTD/Rosette; CTD-RO; Date/Time of event; Density, mass density; Density, sigma-theta (0); DEPTH, water; Difference; EISPAC/WESTWIND; Elevation of event; Event label; GeoB17401-1; GeoB17403-1; GeoB17404-1; GeoB17407-1; GeoB17412-1; GeoB17413-2; GeoB17417-1; GeoB17420-1; GeoB17424-1; GeoB17426-1; GeoB17428-2; GeoB17432-1; GeoB17433-1; GeoB17434-1; GeoB17436-2; Latitude of event; Longitude of event; MARUM; Nitrate; Oxygen; Oxygen saturation; Phosphate; Pressure, water; Salinity; Silicate; SO228; Sonne; Temperature, water; δ13C, dissolved inorganic carbon; δ13C, dissolved inorganic carbon, standard deviation; δ15N, nitrate; δ15N, nitrate, standard deviation; δ18O, nitrate; δ18O, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 88998 data points
    Location Call Number Limitation Availability
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  • 2
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    PANGAEA
    In:  Supplement to: Rafter, Patrick A; Herguera, Juan-Carlos; Southon, John R (2018): Extreme lowering of deglacial seawater radiocarbon recorded by both epifaunal and infaunal benthic foraminifera in a wood-dated sediment core. Climate of the Past, 14(12), 1977-1989, https://doi.org/10.5194/cp-14-1977-2018
    Publication Date: 2023-01-13
    Description: For over a decade, oceanographers have debated the interpretation and reliability of sediment microfossil records indicating extremely low seawater radiocarbon (14C) during the last deglaciation-observations that suggest a major disruption in marine carbon cycling coincident with rising atmospheric CO2 concentrations. Possible flaws in these records include poor age model controls, utilization of mixed, infaunal foraminifera species possibly influenced by changing porewater chemistry, and bioturbation. We have addressed these concerns using a glacial-interglacial record of epifaunal benthic foraminifera 14C on an ideal sedimentary age model (wood calibrated to atmosphere 14C). Our results affirm – with important caveats – the fidelity of these microfossil archives and confirm previous observations of highly depleted seawater 14C at intermediate depths in the deglacial northeast Pacific
    Type: Dataset
    Format: application/zip, 3 datasets
    Location Call Number Limitation Availability
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  • 3
    Publication Date: 2023-02-07
    Description: Planktic and benthic foraminifera 14C measurements, published in Rafter et al. (2019) in GRL. These are a companion dataset to the benthic foraminifera 14C measurements published by Rafter et al. (2018) in Climate of the Past.
    Keywords: 14C; Age, dated; Age, dated material; Age, dated standard deviation; AOM; Calendar age; Calendar age, standard error; Core; CORE; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Foraminifera; Globigerina bulloides; Gulf of California; Habitat; hydrothermal; Laboratory code/label; LPAZ-21P; Pacific; planktic; planktonic; radiocarbon; volcanism; Δ14C; Δ14C, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 759 data points
    Location Call Number Limitation Availability
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  • 4
    Publication Date: 2023-02-07
    Keywords: Age, 14C; Age, 14C calibrated, CALIB 7.1 (Stuiver et al. 2017); Age, dated; Age, dated material; Age, dated standard error; Analytical method; Calendar age; Calendar age, maximum/old; Calendar age, minimum/young; Comment; Core; CORE; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; ET97-7T; Gulf of California; Sample ID
    Type: Dataset
    Format: text/tab-separated-values, 310 data points
    Location Call Number Limitation Availability
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  • 5
    Publication Date: 2023-02-07
    Keywords: Age, 14C; Age, dated; Age, dated material; Age, dated standard error; Core; CORE; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Gulf of California; LPAZ-21PG; Sample ID
    Type: Dataset
    Format: text/tab-separated-values, 42 data points
    Location Call Number Limitation Availability
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  • 6
    Publication Date: 2023-02-08
    Keywords: Age, dated; Age, dated material; Age, dated standard error; Comment; Core; CORE; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Gulf of California; LPAZ-21P; Sample ID
    Type: Dataset
    Format: text/tab-separated-values, 923 data points
    Location Call Number Limitation Availability
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  • 7
    Publication Date: 2024-02-03
    Description: The database for nitrate concentrations and nitrate δ15N includes new data and most of the measurements that have been published to date. This database also includes most of the nitrate δ15N measurements in the database of Rafter et al. (2019; Biogeosciences 16, 2617-2633; https://doi.org/10.5194/bg-16-2617-2019). It consists of 944 stations with 15300 measurements of nitrate δ15N. All data are uploaded, except the GOSHIP P2 and P6 sections for which we report average profiles vs. depth. Full data sets for these sections will be included upon publication in a follow-up version.
    Keywords: Comment; Cruise/expedition; DEPTH, water; Identification; LATITUDE; LONGITUDE; nitrate; Nitrate; nitrogen isotopes; ocean; Reference/source; Time Stamp; Vessel; δ15N, nitrate
    Type: Dataset
    Format: text/tab-separated-values, 100052 data points
    Location Call Number Limitation Availability
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  • 8
    Publication Date: 2024-05-28
    Description: Using a new global compilation of deep-sea 14C/C, we estimated (in Rafter et al. 2022) the average D14C (units of per mil) and 14C ventilation age (units of years) over the last 25,000 years for the deep Pacific, Atlantic, and Southern Oceans. Particularly, we estimated these basin averages for mid-depth waters (between the 27.5 to 28.0 neutral density surfaces) and bottom waters (having a neutral density 〉28.0). These basin averages are calculated using LOESS smoothing, but see the original text for more details. Our reasons for uploading this new data are: (1) An earlier dataset here contained an error for the mid-depth Atlantic; (2) Earlier datasets did not include the trends as D14C values; and (3) Earlier datasets did not include the Raw data (the data before normalization). We have corrected this with the new submission. Please cite the Rafter et al. 2022 when using this dataset.
    Keywords: 0050PG; 0066PG; 145-883; 145-887; 146-893A; 167-1019A; 202-1240; 202-1242A; 341-U1419; 35MF20120125, OISO_21, INDIEN SUD 2; 47396B; 50-37KL; 64-480; 90b; AII125-8-55; AII125-8-56; Akademik M.A. Lavrentiev; ALV-3887-1549-004-007; ALV-3887-1549-004-009; ALV-3887-1549-004-012; ALV-3890-1407-003-001; ALV-3891-1459-003-002; ALV-3891-1758-006-003; AMOCINT, IMAGES XVII; ANT-XI/4; ANT-XXIII/9; ANT-XXVI/2; Argentine Basin; ARK-II/5; ARK-X/2; Azores; B34-91; BC; Bering Sea; Binary Object; BO04-PC11; Box corer; Brazil Basin; Burdwood_Bank; CALYPSO; CALYPSO2; Calypso Corer; Calypso Corer II; Calypso square corer; Calypso Square Core System; Canarias Sea; Cape_Horn; Caribbean Sea; CASQ; CASQS; CD159; CD159-10; CD159-15; CD159-17; CD38-17P; Celtic Sea; Cenderawasih Bay; Central Pacific; CH84-14; Charles Darwin; CHAT_10k; CHAT_16k; CHAT-3K; CHAT-5K; Chatham Rise; COMPCORE; Composite Core; Conrad Rise; Core; CORE; Core1471; Core2088; Core21210009; Core2307; Core2631; Core2657; Core2706; Core2774; Core47396; Core654; Core660; Core936; Corner Rise; Denmark Strait; Drake Passage; DRILL; Drilling/drill rig; Eastern Equatorial Pacific; Eastern slope of Kurile Basin; East Pacific; Emperor Seamounts; EN06601; EN066-39GGC; Endeavor; Equatorial East Pacific; ESTASE1; EW0408; EW0408-26JC; EW0408-85JC; EW0408-87JC; Exp341; F2-92-P3; F8-90-G21; File content; Galapagos; Galápagos Islands; GC; GC_POI; GeoB1503-1; GeoB2104-3; GeoB7149-2; GeoB7162-6; GeoB7163-7; GeoB7167-6; GGC; GGC5; gh02-1030; Giant box corer; Giant gravity corer; Giant piston corer; GIK17940-1; GIK23243-2 PS05/431; GKG; Glomar Challenger; GPC; Gravity corer; Gravity corer (Kiel type); Gravity corer (POI); GS07-150-17/1GC-A; GS07-150-20/2A; Gulf of Alaska; Gulf of California; H209; H213; HH12-946MC; HU72-021-7; HU89038-8PC; IMAGES III - IPHIS; IMAGES IV-IPHIS III; IMAGES V; IMAGES VIII - MONA; IMAGES VII - WEPAMA; IMAGES XII - MARCO POLO; IMAGES XV - Pachiderme; Indian Ocean; INOPEX; Interim_Seamount; Japan Trench; Jean Charcot; JM-FI-19PC; Joides Resolution; JPC; JPC30; JT96-09; JT96-09PC; Jumbo Piston Core; KAL; KALMAR II; Kasten corer; KL; KN_USA; KN11002; KN159-5; Knorr; KNR073-04-003; KNR110-50; KNR110-66; KNR110-82a; KNR110-82GGC; KNR140; KNR140-01JPC; KNR140-02JPC; KNR140-12JPC; KNR140-2-12JPC; KNR140-2-22JPC; KNR140-22JPC; KNR140-2-30GGC; KNR140-2-51GGC; KNR140-26GGC; KNR140-30GGC; KNR140-37JPC; KNR140-39GGC; KNR140-43GGC; KNR140-50GGC; KNR140-51GGC; KNR140-56GGC; KNR140-66GGC; KNR159-5; KNR159-5-36GGC; KNR159-5-78GGC; KNR176-17GC; KNR178; KNR178-2GGC; KNR178-32JPC; KNR195-5-CDH23; KNR195-5-CDH26; KNR195-5-CDH41; KNR195-5-GGC43; KNR197-10; KNR197-10CDH42; KNR197-10-CDH42; KNR197-10-CDH46; KNR197-10-GGC17; KNR197-10-GGC36; KNR197-10-GGC5; KNR198-CDH36; KNR198-GGC15; KNR31GPC5; KNR733P; KNR734P; KNR736P; KOL; KOMEX; KOMEX II; KR02-15-PC06; Kronotsky Peninsula; KT89-18-P4; Lakshadweep Sea; Laurentian fan; Leg145; Leg146; Leg167; Leg202; Leg64; Le Suroît; LPAZ21P; LV27/GREGORY; LV27-2-4; LV29-114-3; LV29-2; M16/2; M23/2; Marion Dufresne (1972); Marion Dufresne (1995); Maurice Ewing; Mazatlan; MCSEIS; MD012378; MD01-2378; MD012386; MD01-2386; MD012416; MD01-2416; MD012420; MD01-2420; MD022489; MD02-2489; MD022519; MD02-2519; MD03-2697; MD03-2707; MD052896; MD05-2896; MD052904; MD05-2904; MD07-3076; MD07-3076Q; MD07-3088; MD08-3169; MD08-3180; MD09-3256; MD09-3256Q; MD09-3257; MD106; MD111; MD114; MD122; MD12-3396Cq; MD126; MD13; MD134; MD147; MD159; MD168; MD173; MD189; MD77-176; MD972106; MD97-2106; MD972120; MD97-2120; MD972121; MD97-2121; MD972138; MD97-2138; MD982165; MD98-2165; MD982181; MD98-2181; MD99-2334; ME0005A; ME0005A-24JC; ME0005A-43JC; Melville; Meteor (1986); ML1208-01PC; MONITOR MONSUN; MR01-K03; MR06-04_PC04A; MUC; Multichannel seismics; MultiCorer; MV99-GC38; MV99-MC17/GC32/PC10; MV99-MC19/GC31/PC08; NEMO; Nesmeyanov25-1-GGC15; Nesmeyanov25-1-GGC18; Nesmeyanov25-1-GGC20; Nesmeyanov25-1-GGC27; New_England_Seamounts; North Atlantic; North Greenland Sea; North Pacific/Gulf of California/BASIN; North Pacific Ocean; Northwest Atlantic; Norwegian Sea; OCE326-GGC14; OCE326-GGC26; OCE326-GGC5; off Chile; off Nova Scotia; OSIRIS III; Pacific Ocean; PALEOCINAT; PC; Philippine Sea; PICABIA; Piston corer; Piston corer (BGR type); Piston corer (Kiel type); PLDS-007G; PLDS-1; Pleiades; Polarstern; PS05; PS1243-2; PS2606-6; PS2644-2; PS30; PS30/144; PS31; PS31/160; PS69; PS69/907-2; PS69/912-3; PS69/912-4; PS75/059-2; PS75/100-4; PS75/104-1; PS75 BIPOMAC; PUCK; RAPiD-10-1P; RAPiD-15-4P; RAPiD-17-5P; RBDASS05; RC24; RC24-8GC; RC27; RC27-14; RC27-23; Remote operated vehicle; RETRO-2; RNDB-GGC15; RNDB-GGC5; RNDB-PC11; RNDB-PC13; Robert Conrad; ROV; RR0503-36JPC; RR0503-41JPC; RR0503-64JPC; RR0503-79JPC; RR0503-831C; RR0503-83GC; S67-FFC15; S794; S931; Sakhalin shelf and slope; Sars_Seamount; Scotia Sea; Sea of Okhotsk; SEDCO; Sediment corer; Shackleton_Fracture_Zone; SHAK03-6K; SHAK05-3K; SHAK06-4K; SHAK06-5K; SHAK10-10K; SHAK14-4G; Shirshov Ridge; SK129-CR2; SL; Smithsonian_48735.1; SO156/2; SO156/3; SO161/3; SO161/3_22; SO178; SO178-13-6; SO201/2; SO201-2-101; SO201-2-12KL; SO201-2-77; SO201-2-85; SO202/1; SO202/1_18-6; SO213/2; SO213/2_76-2; SO213/2_79-2; SO213/2_82-1; SO213/2_84-1; SO95; Sonne; SOPATRA; South Atlantic; South Atlantic Ocean; South China Sea; Southern Alaska Margin: Tectonics, Climate and Sedimentation; South of Iceland; South Pacific Ocean; South Tasman Rise; Southwest Pacific Ocean; SPOC; Station 6, MD189-3396; SU90-08; Thomas G. Thompson (1964); Thomas Washington; Timor Sea; TNO57-21; TR163-22; TR163-23; TR163-31; TT154-10; TTN13-18; TTXXX; U938; V34; V34-98; V35; V35-5; V35-6; Vema; Vigo; VINO19-4-GGC17; VINO19-4-GGC37; VM21-29; VM21-30; VM23-81; VM28-122; VM28-238; VNTR01; VNTR01-10GC; W8709A; W8709A-13; Wecoma
    Type: Dataset
    Format: text/tab-separated-values, 14 data points
    Location Call Number Limitation Availability
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  • 9
    Publication Date: 2024-05-28
    Description: This dataset includes a global compilation of new and published 14C measurements of benthic foraminifera and deep-sea corals (from 0-to 49872 years BP). We synthesized this new dataset into basin-average 14C ventilation age values over the 25,000 years, along density surfaces associated with the upper and lower cells of global ocean overturning circulation (27.5 and 28 kg m^-3, respectively). The published datasets are from all ocean basins, even those not utilized in our synthesis. We also provide the basin-average estimates for the Atlantic, Southern, and Pacific Oceans as produced by the Rafter et al. 2022 study.
    Keywords: 0050PG; 0066PG; 145-883; 145-887; 146-893A; 167-1019A; 202-1240; 202-1242A; 341-U1419; 35MF20120125, OISO_21, INDIEN SUD 2; 47396B; 50-37KL; 64-480; 90b; AII125-8-55; AII125-8-56; Akademik M.A. Lavrentiev; ALV-3887-1549-004-007; ALV-3887-1549-004-009; ALV-3887-1549-004-012; ALV-3890-1407-003-001; ALV-3891-1459-003-002; ALV-3891-1758-006-003; AMOCINT, IMAGES XVII; ANT-XI/4; ANT-XXIII/9; ANT-XXVI/2; Argentine Basin; ARK-II/5; ARK-X/2; Azores; B34-91; BC; Bering Sea; Binary Object; BO04-PC11; Box corer; Brazil Basin; Burdwood_Bank; CALYPSO; CALYPSO2; Calypso Corer; Calypso Corer II; Calypso square corer; Calypso Square Core System; Canarias Sea; Cape_Horn; Caribbean Sea; CASQ; CASQS; CD159; CD159-10; CD159-15; CD159-17; CD38-17P; Celtic Sea; Cenderawasih Bay; Central Pacific; CH84-14; Charles Darwin; CHAT_10k; CHAT_16k; CHAT-3K; CHAT-5K; Chatham Rise; COMPCORE; Composite Core; Conrad Rise; Core; CORE; Core1471; Core2088; Core21210009; Core2307; Core2631; Core2657; Core2706; Core2774; Core47396; Core654; Core660; Core936; Corner Rise; Denmark Strait; Drake Passage; DRILL; Drilling/drill rig; Eastern Equatorial Pacific; Eastern slope of Kurile Basin; East Pacific; Emperor Seamounts; EN06601; EN066-39GGC; Endeavor; Equatorial East Pacific; ESTASE1; EW0408; EW0408-26JC; EW0408-85JC; EW0408-87JC; Exp341; F2-92-P3; F8-90-G21; File content; Galapagos; Galápagos Islands; GC; GC_POI; GeoB1503-1; GeoB2104-3; GeoB7149-2; GeoB7162-6; GeoB7163-7; GeoB7167-6; GGC; GGC5; gh02-1030; Giant box corer; Giant gravity corer; Giant piston corer; GIK17940-1; GIK23243-2 PS05/431; GKG; Glomar Challenger; GPC; Gravity corer; Gravity corer (Kiel type); Gravity corer (POI); GS07-150-17/1GC-A; GS07-150-20/2A; Gulf of Alaska; Gulf of California; H209; H213; HH12-946MC; HU72-021-7; HU89038-8PC; IMAGES III - IPHIS; IMAGES IV-IPHIS III; IMAGES V; IMAGES VIII - MONA; IMAGES VII - WEPAMA; IMAGES XII - MARCO POLO; IMAGES XV - Pachiderme; Indian Ocean; INOPEX; Interim_Seamount; Japan Trench; Jean Charcot; JM-FI-19PC; Joides Resolution; JPC; JPC30; JT96-09; JT96-09PC; Jumbo Piston Core; KAL; KALMAR II; Kasten corer; KL; KN_USA; KN11002; KN159-5; Knorr; KNR073-04-003; KNR110-50; KNR110-66; KNR110-82a; KNR110-82GGC; KNR140; KNR140-01JPC; KNR140-02JPC; KNR140-12JPC; KNR140-2-12JPC; KNR140-2-22JPC; KNR140-22JPC; KNR140-2-30GGC; KNR140-2-51GGC; KNR140-26GGC; KNR140-30GGC; KNR140-37JPC; KNR140-39GGC; KNR140-43GGC; KNR140-50GGC; KNR140-51GGC; KNR140-56GGC; KNR140-66GGC; KNR159-5; KNR159-5-36GGC; KNR159-5-78GGC; KNR176-17GC; KNR178; KNR178-2GGC; KNR178-32JPC; KNR195-5-CDH23; KNR195-5-CDH26; KNR195-5-CDH41; KNR195-5-GGC43; KNR197-10; KNR197-10CDH42; KNR197-10-CDH42; KNR197-10-CDH46; KNR197-10-GGC17; KNR197-10-GGC36; KNR197-10-GGC5; KNR198-CDH36; KNR198-GGC15; KNR31GPC5; KNR733P; KNR734P; KNR736P; KOL; KOMEX; KOMEX II; KR02-15-PC06; Kronotsky Peninsula; KT89-18-P4; Lakshadweep Sea; Laurentian fan; Leg145; Leg146; Leg167; Leg202; Leg64; Le Suroît; LPAZ21P; LV27/GREGORY; LV27-2-4; LV29-114-3; LV29-2; M16/2; M23/2; Marion Dufresne (1972); Marion Dufresne (1995); Maurice Ewing; Mazatlan; MCSEIS; MD012378; MD01-2378; MD012386; MD01-2386; MD012416; MD01-2416; MD012420; MD01-2420; MD022489; MD02-2489; MD022519; MD02-2519; MD03-2697; MD03-2707; MD052896; MD05-2896; MD052904; MD05-2904; MD07-3076; MD07-3076Q; MD07-3088; MD08-3169; MD08-3180; MD09-3256; MD09-3256Q; MD09-3257; MD106; MD111; MD114; MD122; MD12-3396Cq; MD126; MD13; MD134; MD147; MD159; MD168; MD173; MD189; MD77-176; MD972106; MD97-2106; MD972120; MD97-2120; MD972121; MD97-2121; MD972138; MD97-2138; MD982165; MD98-2165; MD982181; MD98-2181; MD99-2334; ME0005A; ME0005A-24JC; ME0005A-43JC; Melville; Meteor (1986); ML1208-01PC; MONITOR MONSUN; MR01-K03; MR06-04_PC04A; MUC; Multichannel seismics; MultiCorer; MV99-GC38; MV99-MC17/GC32/PC10; MV99-MC19/GC31/PC08; NEMO; Nesmeyanov25-1-GGC15; Nesmeyanov25-1-GGC18; Nesmeyanov25-1-GGC20; Nesmeyanov25-1-GGC27; New_England_Seamounts; North Atlantic; North Greenland Sea; North Pacific/Gulf of California/BASIN; North Pacific Ocean; Northwest Atlantic; Norwegian Sea; OCE326-GGC14; OCE326-GGC26; OCE326-GGC5; off Chile; off Nova Scotia; OSIRIS III; Pacific Ocean; PALEOCINAT; PC; Philippine Sea; PICABIA; Piston corer; Piston corer (BGR type); Piston corer (Kiel type); PLDS-007G; PLDS-1; Pleiades; Polarstern; PS05; PS1243-2; PS2606-6; PS2644-2; PS30; PS30/144; PS31; PS31/160; PS69; PS69/907-2; PS69/912-3; PS69/912-4; PS75/059-2; PS75/100-4; PS75/104-1; PS75 BIPOMAC; PUCK; RAPiD-10-1P; RAPiD-15-4P; RAPiD-17-5P; RBDASS05; RC24; RC24-8GC; RC27; RC27-14; RC27-23; Remote operated vehicle; RETRO-2; RNDB-GGC15; RNDB-GGC5; RNDB-PC11; RNDB-PC13; Robert Conrad; ROV; RR0503-36JPC; RR0503-41JPC; RR0503-64JPC; RR0503-79JPC; RR0503-831C; RR0503-83GC; S67-FFC15; S794; S931; Sakhalin shelf and slope; Sars_Seamount; Scotia Sea; Sea of Okhotsk; SEDCO; Sediment corer; Shackleton_Fracture_Zone; SHAK03-6K; SHAK05-3K; SHAK06-4K; SHAK06-5K; SHAK10-10K; SHAK14-4G; Shirshov Ridge; SK129-CR2; SL; Smithsonian_48735.1; SO156/2; SO156/3; SO161/3; SO161/3_22; SO178; SO178-13-6; SO201/2; SO201-2-101; SO201-2-12KL; SO201-2-77; SO201-2-85; SO202/1; SO202/1_18-6; SO213/2; SO213/2_76-2; SO213/2_79-2; SO213/2_82-1; SO213/2_84-1; SO95; Sonne; SOPATRA; South Atlantic; South Atlantic Ocean; South China Sea; Southern Alaska Margin: Tectonics, Climate and Sedimentation; South of Iceland; South Pacific Ocean; South Tasman Rise; Southwest Pacific Ocean; SPOC; Station 6, MD189-3396; SU90-08; Thomas G. Thompson (1964); Thomas Washington; Timor Sea; TNO57-21; TR163-22; TR163-23; TR163-31; TT154-10; TTN13-18; TTXXX; U938; V34; V34-98; V35; V35-5; V35-6; Vema; Vigo; VINO19-4-GGC17; VINO19-4-GGC37; VM21-29; VM21-30; VM23-81; VM28-122; VM28-238; VNTR01; VNTR01-10GC; W8709A; W8709A-13; Wecoma
    Type: Dataset
    Format: text/tab-separated-values, 8 data points
    Location Call Number Limitation Availability
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  • 10
    Publication Date: 2023-03-21
    Description: Gas exchange between the atmosphere and ocean interior profoundly impacts global climate and biogeochemistry. However, our understanding of the relevant physical processes remains limited by a scarcity of direct observations. Dissolved noble gases in the deep ocean are powerful tracers of physical air-sea interaction due to their chemical and biological inertness, yet their isotope ratios have remained underexplored. Here, we present high-precision noble gas isotope and elemental ratios from the deep North Atlantic (~32°N, 64°W) to evaluate gas exchange parameterizations using an ocean circulation model. The unprecedented precision of these data reveal deep-ocean undersaturation of heavy noble gases and isotopes resulting from cooling-driven air-to-sea gas transport associated with deep convection in the northern high lati-tudes. Our data also imply an underappreciated and large role for bubble-mediated gas exchange in the global air-sea transfer of sparingly soluble gases, including O2, N2, and SF6. Using noble gases to validate the physical representation of air-sea gas exchange in a model also provides a unique opportunity to distinguish physical from biogeochemical signals. As a case study, we compare dissolved N2/Ar measurements in the deep North Atlantic to physics-only model predictions, revealing excess N2 from benthic denitrification in older deep waters (below 2.9 km). These data indicate that the rate of fixed N removal in the deep Northeastern Atlantic is at least three times higher than the global deep-ocean mean, suggesting tight coupling with organic carbon export and raising potential future implications for the marine N cycle.
    Description: NSF, UK NERC, University of Oxford Advanced Research Computing facility
    Description: https://www.bco-dmo.org/project/887496
    Description: research
    Keywords: ddc:551 ; gas exchange ; nitrogen cycle ; overturning circulation ; air-sea interaction ; noble gases
    Language: English
    Type: doc-type:article , publishedVersion
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