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  • 1
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The Late Cretaceous (late Cenomanian-Campanian) Loma Chumico Formation consists of laminated to massive bedded siliceous shales, cherts, ash fall tuffs/volcanic glass beds and volcaniclastic sandstones. The Loma Chumico Formation is at least 630 m thick (core data) in the Tempisque Basin, and can be subdivided in the subsurface into organic-rich and organic-lean (total organic carbon 〈1%) facies. Rock-Eval total organic carbon (TOC) data show that TOC in the organic-rich facies averages 15·5%, with values as high as 33%. Inorganic geochemical, petrological and sedimentological analyses indicate that all the lithologies of the Loma Chumico Formation were deposited in middle shelf to outer slope environments adjacent to an active subaerial island arc.The organic geochemistry and palaeontology of the Loma Chumico Formation help constrain the factors that controlled biological productivity in the region during the Late Cretaceous. Biomarkers, identified in organic-rich facies by gas chromatography/mass spectrometry (GC/MS), show a high abundance of total steranes relative to hopanes in the Morote-1 core, indicating algal-dominated organic input. The hopane-to-sterane ratio of the extract from the Manzanillo-1 core indicates a relatively high bacterial component to the organic matter.Upwelling and extrusive volcanism were the most important factors that controlled nutrient supply (including silica flux) and biological productivity within the Loma Chumico Formation depositional system. Episodic radiolarian, dinoflagellate or diatom ‘blooms’, instigated by rapid infusions of volcanogenic silica, may have resulted in expansion of the oxygen minimum zone (OMZ), enhancing the preservation of organic matter. Productivity appears to have been uniform, even during deposition of the organic-lean facies.The findings of this study suggest that ocean-wide anoxia in the eastern Pacific was unlikely during the Late Cretaceous. High TOC contents of organic-rich radiolarites from central Caribbean Deep Sea Drilling Project (DSDP) sites may be related to upwelling produced in the eastern Pacific by convergence of the easterly Trade Winds (Eastern Pacific Equatorial Upwelling Zone), or may be part of a more complex Pacific-Atlantic Ocean interaction.The end of deposition of organic-rich rocks began near the end of the latest Santonian-earliest Campanian in the central Caribbean and Costa Rica.Palaeoceanographic models suggest that improved circulation and ventilation of bottom waters due to early opening of the North Atlantic-South Atlantic seaway may explain this observation. This may represent the influx of a previously unrecognized source of colder, oxygenated intermediate/bottom water (proto-Antarctic Intermediate Water) into the Late Cretaceous central Atlantic and eastern Pacific oceans.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 444 (2006), S. 744-747 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Oxygenation of the Earth’s surface is increasingly thought to have occurred in two steps. The first step, which occurred ∼2,300 million years (Myr) ago, involved a significant increase in atmospheric oxygen concentrations and oxygenation of the surface ocean. A further increase in ...
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2016-10-24
    Description: Perhaps the most significant event in the Cretaceous record of the carbon isotope composition of carbonate1,2, other than the 1–2.5 ‰ negative shift in the carbon isotope composition of calcareous plankton at the Cretaceous/Tertiary boundary3, is the rapid global positive excursion of ~2 ‰ (13C enrichment) which took place between ~91.5 Myr and 90.3 Myr (late Cenomanian to earliest Turonian (C/T boundary event))1,4,5. This excursion has been attributed to a change in the isotope composition of the marine total dissolved carbon (TDC) reservoir resulting from an increase in rate of burial of 13C-depleted organic carbon, which coincided with a major global rise in sea level5 during the so-called C/T oceanic anoxic event (OAE)6. Here we present new data, from nine localities, which demonstrate that a positive excursion in the carbon isotope composition of organic carbon at or near the C/T boundary7,8 is nearly synchronous with that for carbonate and is widespread throughout the Tethys and Atlantic basins (Fig. 1), as well as in more high-latitude epicontinental seas. The postulated increase in the rate of burial of organic carbon may have had a significant effect on CO2 and O2 concentrations in the oceans and atmosphere, and consequent effects on global climate and sedimentary facies.
    Type: Article , PeerReviewed
    Format: text
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  • 4
    Publication Date: 2016-10-24
    Description: Rhythmic bedding is a prominent feature of North American and European Upper Cretaceous pelagic carbonate sequences deposited in epicontinental and continental-edge settings. Such bedding rhythms can result from variations in carbonate productivity, terrigenous dilution, redox conditions, or bottom currents. Each type of bedding cycle is expressed differently in the stratigraphic record but probably was caused by climatic cycles that are linked to variations in the Earth's orbital characteristics (Milankovitch cycles). Thus, pelagic carbonates of Cretaceous age acted as particularly sensitive recorders of orbitally induced changes in climate. Documentation of these bedding rhythms will permit detailed chronostratigraphic and lithostratigraphic correlations and will further illuminate depositional processes in Upper Cretaceous carbonate sequences.
    Type: Article , PeerReviewed
    Format: text
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  • 5
    Publication Date: 2014-08-27
    Description: The isotope composition of seawater sulfate is an important tracer of sulfur, carbon, and oxygen cycles in Earth’s deep past. Carbonate-associated sulfate (CAS) extracted by acid digestion is widely used as a proxy for sulfate in paleo-seawater from which the carbonate minerals precipitated. Early and late diagenesis, weathering, and laboratory processing can in some cases compromise original seawater sulfate signals. Here, we report that extracted CAS can also be severely contaminated by recent atmospheric sulfate, especially when the sampled carbonates are from outcrops in arid to semi-arid climates or in heavily polluted regions. Our evidence comes from triple oxygen isotope compositions of sequentially extracted water-leachable sulfate and acid-leachable sulfate from carbonates of diverse ages from northwestern and north-central China and southwestern North America. Independent of the age of the rocks, almost all the water-leachable sulfates and half of the acid-leachable sulfates bear positive 17 O anomalies, clearly distinguishable from those of typical seawater sulfate. Because secondary atmospheric sulfate (SAS) is the only source of sulfate known to bear positive 17 O anomalies, we conclude that sulfate extracted from carbonate outcrops in these regions has a significant component of SAS. Because SAS generally has a much lower 34 S value than paleo-seawater sulfate, it could shift the 34 S of the extracted CAS to lower values and in some cases even lower than that of the co-occurring pyrite, i.e., the "super-heavy pyrite" enigma reported in geological records. Our findings call for a re-evaluation of many published, outcrop-based CAS data and conclusions.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 6
    Publication Date: 2014-05-08
    Description: Blacks in comparison with whites are at risk for a more serious form of hypertension with high rates of complications. Greater sodium retention is thought to underlie the blood pressure (BP)-determining physiology of blacks, but specific mechanisms have not been identified. In a prospective observational study of BP, 226 black children and 314 white children (mean age, 10.6 years) were enrolled initially. Assessments were repeated in 85 blacks and 136 whites after reaching adulthood (mean age, 31 years). The relationship of BP to plasma aldosterone concentration in the context of the prevailing level of plasma renin activity was studied in blacks and whites. In a secondary interventional study, 9-α fludrocortisone was administered for 2 weeks to healthy adult blacks and whites to simulate hyperaldosteronism. BP responses in the 2 race groups were then compared. Although black children had lower levels of plasma renin activity and plasma aldosterone, their BP was positively associated with the plasma aldosterone concentration, an effect that increased as plasma renin activity decreased ( P =0.004). Data from black adults yielded similar results. No similar relationship was observed in whites. In the interventional study, 9-α fludrocortisone increased BP in blacks but not in whites. In conclusion, aldosterone sensitivity is a significant determinant of BP in young blacks. Although its role in establishing the risk of hypertension is not known, it could be as relevant as the actual level of aldosterone.
    Keywords: Epidemiology
    Print ISSN: 0194-911X
    Topics: Medicine
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