ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract A new rhodium(III) complex of an amine-phenol ligand N,NN′-bis-(2-hydroxybenzyl)1,3-diaminopropane was synthesized and characterized by X-ray diffraction studies. Diffraction data were collected by theθ-2θ scan method using MoKα. radiation. The structure was solved by conventional methods resulting in a final R factor of 0.037 for 1954 independent reflections (F o 〉2σ(F o )). The structure consists of a dinuclear complex with two μ-hydroxy bridges between the two Rh atoms. The overall charge of the molecule is neutral due to deprotonation of all phenolic groups. Crystal data: triclinic, space groupP¯1,a=7.308(3)Å;b=9.586(3)Å,c=12.686(5)Å, α=87.51(2), β=88.28(2), γ=71.70(3)°,V=866.6(6)Å3;Z=2.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01187273
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