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  • 1
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Petrographic and geochemical studies of peridotites from the South Sandwich forearc region provide new evidence for the evolution of the South Sandwich arc–basin system and for the nature of interactions between arc magma and oceanic lithosphere. Peridotites from the inner trench wall in the north-east corner of the forearc vary from clinopyroxene-bearing harzburgites, through samples transitional between harzburgites and dunites or wehrlites, to dunites. The harzburgites are LREE depleted with low incompatible element abundances and have chromites with intermediate Cr# (ca. 0.40). Modelling shows that they represent the residues from 15–20% melting at oxygen fugacities close to the QFM buffer. The dunites have U-shaped REE patterns, low incompatible element abundances and high Cr# (0.66–0.77). Petrography and geochemistry indicate that the latter are the product of intense interaction between peridotite and melt saturated with olivine under conditions of high oxygen fugacity (QFM + 2). The transitional samples are the product of lesser interaction between peridotite and melt saturated with olivine ± clinopyroxene. The data demonstrate that the harzburgites originated as the residue from melting at a ridge (probably the early East Scotia Sea spreading centre), and were subsequently modified to transitional peridotites and dunites by interaction with South Sandwich arc magmas. The second dredge locality, near the South Sandwich Trench–Fracture Zone intersection, yielded rocks ranging from lherzolite to harzburgite that could similarly have resulted from a two-stage melting and enrichment process, but involving a more fertile mantle residue and a reacting melt that is transitional between MORB and island arc tholeiite. The South Sandwich peridotites have a similar petrogenetic history to those from Conical Seamount in the Mariana forearc in the sense that both involved interaction between arc magma and pre-existing mantle lithosphere of different provenance. However, the precise compositions of the magma and mantle components vary from location to location according to the precise tectonic setting and tectonic history. Overall, therefore, data from the South Sandwich and Izu–Bonin–Mariana systems emphasise the potential significance of peridotite geochemistry in unravelling the complex tectonic histories of forearcs past and present.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2021-04-23
    Description: Oxygen minimum zones (OMZs) cover extensive areas of eastern boundary ocean regions and play an important role in the cycling of the essential micronutrient iron (Fe). The isotopic composition of dissolved Fe (dFe) in shelf and slope waters on the Senegalese margin was determined to investigate the processes leading to enhanced dFe concentrations (up to 2 nM) in this tropical North Atlantic OMZ. On the shelf, the delta Fe-56 value of dFe (relative to the reference material IRMM-014) was as low as -0.33 parts per thousand, which can be attributed to input of dFe from both reductive and nonreductive dissolution of sediments. Benthic inputs of dFe are subsequently upwelled to surface waters and recycled in the water column by biological uptake and remineralisation processes. Remineralised dFe is characterised by relatively high delta Fe-56 values (up to + 0.41 parts per thousand), and the contribution of remineralised Fe to the total dFe pool increases with distance from the shelf. Remineralisation plays an important role in the redistribution of dFe that is mainly supplied by benthic and atmospheric inputs, although dust inputs, estimated from dissolved aluminium concentrations, were low at the time of our study (2-9 nmol dFe m(-2) d(-1)). As OMZs are expected to expand as climate warms, our data provide important insights into Fe sources and Fe cycling in the tropical North Atlantic Ocean.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2015-09-04
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 4
    Publication Date: 2012-08-22
    Description: Cenozoic volcanism within Mongolia forms part of a large central Asian province of intra-plate magmatism. Numerous small-volume volcanic cones and alkali basalt lava flows have been formed since c . 30 Ma; from c . 12 Ma activity has been focused on the uplifted Hangai dome. A mechanism for melting beneath the dome has, however, thus far remained enigmatic. Some of the oldest basalts on the Hangai dome erupted at its centre at ~6 Ma and their geochemistry suggests a garnet lherzolite source region at 90–100 km depth. These lavas have Pb isotope compositions similar to those of depleted Indian mid-ocean ridge basalts (MORB) ( 206 Pb/ 204 Pb = 17·822, 207 Pb/ 204 Pb = 15·482, 208 Pb/ 204 Pb = 37·767), which may be indicative of the involvement of ambient asthenospheric mantle in their petrogenesis. Younger basalts exhibit a gradual shift in isotopic composition towards a source that has less radiogenic Pb and more radiogenic Sr, evidenced by the eruption of lavas with 206 Pb/ 204 Pb = 16·991 and 87 Sr/ 86 Sr = 0·704704. The youngest lavas, dated as younger than ~8 ka, have the highest K 2 O contents (up to 5·2 wt %) and are characterized by the most enriched trace-element signatures; they are interpreted to represent melting of a metasomatically altered sub-continental lithospheric mantle containing phlogopite. Concurrent with progressive melting of the lithosphere, melting appears to propagate outwards from the centre of the dome to its margins; by 0·7 Ma the marginal magmatism is interpreted to result from melting of a depleted MORB-source mantle component with a smaller contribution from the lithospheric mantle. The spatial and temporal variations in melting beneath the Hangai dome may be explained by either lithospheric delamination or the presence of a small-scale thermal anomaly in the upper mantle. Although it is not possible to distinguish between these models on the basis of geochemistry alone, the lack of a viable mechanism to generate small-scale upwelling lends support to a model involving delamination of the lithospheric mantle beneath the Hangai dome.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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