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  • 1
    Publication Date: 2023-12-07
    Description: Despite growing research on greenhouse gas (GHG) emissions from inland waters, few systematic efforts have been made to assess the regional-scale GHG emissions from Asian rivers under increasing anthropogenic stress. We examined factors controlling longitudinal and seasonal variations in the partial pressure of CO₂ (pCO₂), and CH₄ and N₂O concentrations in the Ganges, Mekong, and Yellow River (Huang He) by simultaneously measuring gas concentrations and stable C isotopes, and optical properties of dissolved organic matter (DOM) from 2016 to 2019. The levels of pCO₂ and CH₄ were distinctively higher in polluted tributaries and affected reaches of the Ganges and Mekong than in the Yellow River. The highest levels of N₂O were found in the Ganges, followed by Yellow River and Mekong. Across these basins, dry-season mean concentrations of CO₂, CH₄, and N₂O were 1.6, 2, and 7 times higher than those measured in the monsoon season, respectively. This seasonality was consistent with that of δ¹³C-CO₂, while δ¹³C-CH₄ showed an opposite pattern. The overall results suggest that neglecting localized pollution impacts on GHG emissions from increasingly urbanized river basins can result in inaccurate estimates of global riverine GHG emissions.
    Keywords: according to Huguet et al. (2009); according to Zsolnay et al. (1999); Air-water gas flux, river, Lauerwald et al. (2015); Biological index; Carbon, organic, dissolved; Carbon, organic, particulate; Carbon dioxide, flux, in mass carbon; Carbon dioxide (water) partial pressure; Conductivity, electrolytic; Date/Time of event; Distance; Event label; Fluorescence, dissolved organic matter; Fluorescence index; Fluorescence index, McKnight et al. (2001); Ganges_G1; Ganges_G10; Ganges_G11; Ganges_G11_1; Ganges_G11_2; Ganges_G12; Ganges_G13; Ganges_G13_1; Ganges_G14; Ganges_G14_1; Ganges_G2; Ganges_G2_1; Ganges_G3; Ganges_G3_1; Ganges_G4; Ganges_G5; Ganges_G6; Ganges_G7; Ganges_G7_1; Ganges_G8; Ganges_G9; Ganges_H1; Ganges_H1_1; Ganges_H2; Ganges_H3; Ganges_J1; Ganges_J2; Ganges_J3; Ganges_J3_1; Ganges_J3_2; Ganges_J4; Ganges_T1; Ganges_T1_1; Ganges_T2; Ganges_T2_1; Ganges_T3; Ganges_T3_1; Ganges_T4; Ganges_T4_1; Ganges_T4_2; Ganges_T5; Ganges_T6; Ganges_W1; Ganges_W2; Ganges_W3; Ganges_W4; Ganges_W4_1; Ganges_W5; Ganges_W6; Ganges_W6_1; Ganges_W7; Ganges_W7_1; Ganges_W8; Greenhouse gases; HAND; Humification index; Ion chromatography; Latitude of event; Longitude of event; Mekong_M1; Mekong_M10; Mekong_M10_1; Mekong_M11; Mekong_M11_1; Mekong_M2; Mekong_M2_1; Mekong_M3; Mekong_M3_1; Mekong_M4; Mekong_M5; Mekong_M5_1; Mekong_M6; Mekong_M6_1; Mekong_M7; Mekong_M7_1; Mekong_M8; Mekong_M8_1; Mekong_M9; Mekong_M9_1; Mekong_T1; Mekong_T2; Mekong_T2_1; Mekong_T3; Mekong_T3_1; Mekong_T4; Mekong_T4_1; Mekong_T5; Mekong_T5_1; Mekong_T6; Mekong_T6_1; Mekong_T7; Mekong_T7_1; Mekong_W1; Mekong_W1_1; Mekong_W2; Mekong_W2_1; Mekong_W3; Mekong_W4; Mekong_W5; Mekong_W5_1; Mekong_W6; Mekong_W6_1; Mekong_W7; Mekong_W7_1; Methane; Methane, flux, in mass carbon; Nitrogen, inorganic, dissolved; Nitrogen, organic, particulate; Nitrogen in ammonium; Nitrogen in nitrate; Nitrous oxide, dissolved; Nitrous oxide, flux, in mass nitrogen; organic matter; Oxygen, dissolved; Parallel factor analysis (PARAFAC); pH; Phosphorus in orthophosphate; River; Sample comment; Sample ID; Sampling by hand; Season; Specific ultraviolet absorbance normalized to DOC, 254 nm, per mass carbon; Specific UV absorbance 254nm, DOC normalised, Weishaar et al. (2003); Suspended matter, total; Temperature, water; water pollution; Yellow_T1; Yellow_T1_1; Yellow_T2; Yellow_T2_1; Yellow_Y1; Yellow_Y2; Yellow_Y3; Yellow_Y4; Yellow_Y4_1; Yellow_Y5; Yellow_Y6; Yellow_Y7; Yellow_Y8; δ13C; δ13C, carbon dioxide, dissolved; δ13C, methane, dissolved
    Type: Dataset
    Format: text/tab-separated-values, 3479 data points
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  • 2
    Publication Date: 2024-06-12
    Description: High-frequency sensor measurement was combined with dissolved organic matter (DOM) characterization to investigate diel and seasonal variations in the partial pressure of CO2 (pCO2) in the lower Ganges, near Hardinge Bridge (24°03'57.04 N, 89°01'42.85 E). Continuous measurement of pCO2 was conducted every month for 12–13 hours from May 2018 to April 2019, with an extended deployment of 48 hours continuous monitoring in March 2019. Water samples were also collected monthly to measure biodegradable dissolved organic carbon and optical properties of DOM including three fluorescent DOM components. CO2 flux and apparent oxygen utilization were calculated based on CO2 and dissolved oxygen measurements.
    Keywords: Biological index; Calculated from change in dissolved organic carbon concentration; Calculated from dissolved oxygen (Vachon et al., 2020); Calculated from pCO2 (Raymond et al., 2012); Carbon, organic, dissolved; Carbon, organic, dissolved, biodegradable; Carbon dioxide, flux; CO2 sensor (CARBOCAP®, GMT222, Vaisala); DATE/TIME; Fluorescence, dissolved organic matter; Fluorescence index; Ganges; Ganges, Bangladesh, Asia; Gas chromatography on an Agilent Technologies 7890A GC; Hardinge_Bridge; Humification index; MULT; Multi-Parameter Water Quality Sonde, YSI 6920 V2; Multiple investigations; organic matter; Oxygen, departure; Oxygen, dissolved; Partial pressure of carbon dioxide (ambient atmosphere); Partial pressure of carbon dioxide (water) at equilibrator temperature (wet air); pCO2; pH; Shimadzu TOC-VCPH total organic carbon analyzer; Specific ultraviolet absorbance normalized to DOC, 254 nm, per mass carbon; Spectrophotometer UV/VIS (Agilent 8453); Temperature, water; water quality; δ13C, carbon dioxide, dissolved
    Type: Dataset
    Format: text/tab-separated-values, 70121 data points
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2018. This is the author's version of the work. It is posted here under a nonexclusive, irrevocable, paid-up, worldwide license granted to WHOI. It is made available for personal use, not for redistribution. The definitive version was published in Ocean Science Journal 53 (2018): 239-249, doi:10.1007/s12601-018-0016-0.
    Description: The threespot wrasse (Halichoeres trimaculatus; Family Labridae) is a common coral reef species of the Indo-Pacific Ocean. Given that this species spawns daily at high tide (HT), we hypothesized that endocrine changes in relation to gonadal development are synchronized with the tidal cycle. To test this, we examined the transcript abundance of two cytochrome P450 aromatases (cyp19a and cyp19b) and two estrogen receptors (er and er) in the ovary and brain of this species in response to tidal change. When fish were collected around four tidal points [low tide (LT), flood tide (FT), high tide (HT), and ebb tide (ET)], gonadosomatic index and oocyte diameter increased around HT and FT, respectively. Ovulatory follicles were observed in ovaries around HT. Real-time quantitative polymerase-chain reaction revealed that mRNA abundance of cyp19a and er, but not er, in the ovary increased around ET and HT, respectively. On the other hand, mRNA levels of cyp19b in the forebrain were significantly higher around FT. Increases of er and er mRNA abundance around FT were observed in all areas of the brain and the midbrain, respectively. The changes in mRNA abundance of key genes involved in reproduction at specific tidal cycles, along with the development of the vitellogenic oocytes in the ovary, support our hypothesis that synchronization of endocrine changes to the tidal periodicity plays a role in the gonadal development of this species. We hypothesize that conversion of testosterone to E2 in the brain may be associated with the spawning behavior given that the wrasse exhibits group spawning with a territory-holding male around HT.
    Description: This study was supported partially by the 21st Century COE program “The Comprehensive Analyses on Biodiversity in Coral Reef and Island Ecosystems in Asian and Pacific Regions” from the Ministry of Education, Culture, Sports, Science and Technology, Japan, JSPS KAKENHI Grant number 16H05796, and the Natural Sciences and Engineering Research Council (NSERC, Canada) Discovery Grant program.
    Keywords: Aromatase ; Brain ; Estrogen receptor ; Ovary ; Tide ; Wrasse
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4943-4948 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We investigated the effect of C49-to-C54 conversion behavior on the agglomeration of Ti-silicide fabricated on subquarter micron polycrystalline Si lines by comparing pre-amorphized samples with conventional ones. Pre-amorphization of polycrystalline Si enhances the C49-to-C54 transformation on subquarter micron linewidths, however, it results in the early development of macroscopic grooves during the second rapid thermal annealing. From these results, we suggest the existence of an extra thermal budget during the second rapid thermal annealing of the pre-amorphized samples, which deteriorates the thermal stability of the C54-TiSi2 featured line. It is also shown that C49-to-C54 transformation on a 0.2 μm linewidth in the conventional samples has two kinds of competing factors when postannealing is added. One is the tendency of C54 transformation and the other is agglomeration of C49-TiSi2 grains. During high temperature annealing (〉850 °C), C49-TiSi2 has been agglomerated by a thinning mechanism instead of transformation into the C54 phase. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 73 (1998), S. 2284-2286 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The formation of CoSi2 spike in the Co/Si3N4/Si(100) system and its crystallographic structure have been investigated. An annealing at 1050 °C caused not only agglomeration of Co film but penetration of Co agglomerates through the Si3N4 layer. The CoSi2 spike of B type epitaxial and twinned orientation of CoSi2[110](parallel)Si[110], Si(111¯)(parallel)CoSi2(1¯11¯) and Si(1¯1¯1)(parallel)CoSi2(11¯1) was formed in the Si substrate by the penetrated Co source. The formation of the epitaxial CoSi2 spike can be explained by the fast diffusion of Co atoms along defects in Si such as dislocations resulting from stress between the Si3N4 layer and the Si substrate. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 73 (1998), S. 2302-2304 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We investigated the formation of CoSi2 for Ti capped Co on (100) Si substrate with emphasis on the Co–Ti interaction and its effect on thermal stability. A 15 nm thick Ti capping layer is shown to improve the interfacial roughness and thermal stability of CoSi2 film grown on Si substrate compared with TiN capping. The increased uniformity of silicide/Si(100) interface is speculated to result from retarded Co–Si reaction by the formation of CoTi binary phase. And the high thermal stability can be explained by the fact that the amount of Ti atoms in CoSi2 film for Ti capping is much higher than what is in TiN capping. It is likely that the surface Ti diffuses rapidly into CoSi2 grain boundaries and slows down the agglomeration process, thereby increasing thermal stability while Ti in TiN capping did not. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This letter describes the use of rapid thermal annealing (RTA) to form a barrier layer applicable to the gate electrode in dynamic random access memory devices with a stacked structure [tungsten nitride (WNx)/polycrystalline Si (poly-Si)]. After RTA, the reactively sputtered amorphous WNx film on the poly-Si was transformed to a low-resistive α-phase W and nitrogen-segregated layer. Most of the nitrogen in the WNx film was dissipated and a relatively small amount of the nitrogen was segregated at the interface of the α-phase W and poly-Si. The segregated layer was estimated to be 2 nm thick and revealed a silicon nitride (Si–N) bonding status. More importantly, we found that this thin segregated layer successfully protected the formation of tungsten silicide, even after RTA at 1000 °C for 2 min in a hydrogen environment. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 26 (1993), S. 404-406 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Biogeochemical responses to changing climate and atmospheric deposition were investigated using nitrogen (N) and sulfur (S) mass balances, including dry deposition and organic solutes in the Arbutus Lake watershed in the Adirondack Mountains, New York State. Long-term monitoring of wet-only precipitation (NADP/NTN, 1983–2001) and dry deposition (AIRMoN, 1990–2001) at sites adjacent to the watershed showed that concentrations of SO42− in precipitation, SO42− in particles,and SO2 vapor all declined substantially (P〈0.005) in contrast to no marked temporal changes observed for most N constituents (NH4+ in precipitation, HNO3 vapor, and particulate NO3−), except for NO3− in precipitation, which showed a small decrease in the late 1990s. From 1983 to 2001, concentrations of SO42− in the lake outlet significantly decreased (−2.1 μeq L−1 yr−1, P〈0.0001), whereas NO3− and dissolved organic N (DON) concentrations showed no consistent temporal trends. With the inclusion of dry deposition and DON fluxes into the mass balance, the retained portion of atmospheric N inputs within the main subcatchment increased from 37% to 60%. Sulfur outputs greatly exceeded inputs even with the inclusion of dry S deposition, while organic S flux represented another source of S output, implying substantial internal S sources. A significant relationship between the annual mean concentrations of SO42− in lake discharge and wet deposition over the last two decades (r=0.64, P〈0.01) suggested a considerable influence of declining S deposition on surface water SO42− concentrations, despite substantial internal S sources. By contrast, interannual variations in both NO3− concentrations and fluxes in lake discharge were significantly related to year-to-year changes in air temperature and runoff. Snowmelt responses to winter temperature fluctuations were crucial in explaining large portions of interannual variations in watershed NO3− export during the months preceding spring snowmelt (especially, January–March). Distinctive response patterns of monthly mean concentrations of NO3− and DON in the major lake inlet to seasonal changes in air temperature also suggested climatic regulation of seasonal patterns in watershed release of both N forms. The sensitive response of N drainage losses to climatic variability might explain the synchronous patterns of decadal variations in watershed NO3− export across the northeastern USA.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1546-1718
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Medicine
    Notes: [Auszug] Defects in the human Ca2+-sensing receptor gene have recently been shown to cause familial hypocalciuric hypercalcaemia and neonatal severe hyperparathyroidism. We now demonstrate that a missense mutation (Glu128Ala) in this gene causes familial hypocalcaemia in affected members of one family. ...
    Type of Medium: Electronic Resource
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