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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 57 (1985), S. 3043-3043 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The RRh3B2 (R=La to Gd) compounds form in the hexagonal CeCo3B2-type structure. The La containing compound in this series has been reported to be a superconductor while CeRh3B2 orders magnetically with Ce being in a nearly 3+ state. The magnetic ordering in CeRh3B2 is presumed to arise from the hybridization of nearly localized 4f electrons of Ce with sp conduction electrons or the 4d band of Rh or from the hybridization of the two. We have examined the magnetic behavior of the system Ce1−xLaxRh3B2 (x=0.0, 0.2, 0.4, 0.6, and 0.8). All these compounds (except LaRh3B2) also order magnetically. The Curie temperature decreases from about 115 K for pure Ce compound to 2.3 K for Ce0.2La0.8Rh3B2. The magnetic moments per formula unit remains nearly constant for 0〈x〈0.4 and then decreases with increasing x. From the values of the effective paramagnetic moments and the saturation moments we find that magnetism, having the same origin, persists in Ce1−xLaxRh3B2 for x ranging from 0.0 to 0.8. The La-rich side is being investigated for the occurrence of superconductivity. Details will be published elsewhere.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 57 (1985), S. 4136-4136 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Rapidly quenched rare-earth (R)-iron boron alloys show large magnetic hysteresis when annealed around 700 °C. The hard magnetic properties of these alloys have been attributed to the presence of an anisotropic tetragonal phase with composition R2Fe14B. However, it is not yet clear when this phase is formed and how it affects the hard magnetic properties. Thermal analysis data, show a crystallization temperature around 400 °C which is much lower than the annealing temperature for the optimum properties. X-ray diffraction data do not show any significant changes after crystallization. In the present study we have used the Mössbauer effect to probe the products of crystallization and their changes during further annealing. Analysis of the 57Fe Mössbauer data has been performed considering a distribution of hyperfine magnetic fields. It is found that the average field changes from 250 kG for the amorphous alloy to 285 kG for the alloy annealed at 450 °C to 240 kG for the alloy annealed at 700 °C. The distribution is narrowed on increasing the annealing temperature and the Mössbauer spectra are indicative of phase segregation.
    Type of Medium: Electronic Resource
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