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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 1821-1832 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electrical resistance of Al-1 wt % Si thin-film conductors has been measured as a function of time t, temperature, and current polarity in order to investigate both generation and recovery of (microstructural) damage caused by electromigration. The fractional change of electrical resistance ΔR/R is characterized by three distinct stages: (i) undetectable ΔR/R during an incubation period τ; (ii) linear increase of ΔR/R with t−τ; and (iii) abrupt decrease of ΔR/R when polarity is reversed, followed by gradual resumption of the previous linear increase. Examination of the conductor surface during these three stages by scanning electron microscopy reveals: (i) undetectable microstructural damage; (ii) generation of (first) holes and (then) hillocks; and (iii) recovery followed by further generation of microstructural damage. Results are interpreted by (i) generation of stress σ in grain boundaries; (ii) formation of holes when σ exceeds a critical tensile stress σ+c and hillocks when σ exceeds a critical compressive stress σ−c (||σ+c|| 〈 ||σ−c||), and (iii) interchange of tensile and compressive stress by polarity reversal. The last stage, in fact, represents superposition of a continuation of the linear increase (degradation) of ΔR/R due to the applied current and an exponential decrease (healing) of ΔR/R, characterized by τ, due to stress relaxation. In general, damage and subsequent healing by electromigration involve a delicate balance between applied current, time, and spatial distribution of (elastic) tensile and compressive stress, (anelastic) formation of holes, and (plastic) formation of hillocks, as dictated by the concomitant microstructure.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 1316-1319 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: GaSb undoped layers grown by molecular-beam epitaxy on GaSb or on semi-insulating GaAs substrates at temperatures between 600 and 630 °C are shown to have carrier concentrations in the low 1013 cm−3 range, corresponding to almost intrinsic conditions. The materials have been characterized using current-voltage, capacitance-voltage, Hall effect, photoluminescence, thermally stimulated current, and secondary-ion mass spectrometry. Bulk GaSb (n type) is also found to have converted to high-resistance p type after a heat treatment at 630 °C. Speculations are offered for the responsible mechanism, but a definitive explanation does not exist at this time.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 1320-1322 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: It is shown that when grown by molecular-beam epitaxy at high temperatures around 700 °C, undoped GaAs layers display high resistivity. Preliminary results seem to imply that Ga-related inclusions that produce internal Schottky diodes might be responsible for this effect rather than the presence of deep centers. It is proposed that Ga-related inclusions that produce internal Schottky diodes might possibly be responsible for this effect rather than the presence of deep centers.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 3510-3515 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of hydrogen plasma treatment and 300 keV proton implantation on the electrical properties of AlGaAsSb layers matched to GaSb are studied. It is shown that the hydrogen introduced from a plasma can form electrically neutral complexes with donors and acceptors in this material system. The results can be explained under the assumption that the hydrogen has an acceptor and a donor level in AlGaAsSb and an estimate of the depth of these levels as a function of composition is made. It is also shown that after heavy irradiation of AlGaAsSb with protons the material becomes p type with the hole concentration of about 1016 cm−3, independent of the initial doping level in the starting material.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 4411-4414 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Schottky barriers of Au, Al, and Sb on n- and p-type layers of Al0.5Ga0.5As0.05Sb0.95 have been studied. The Schottky barriers are high for Au (1.3 eV) and Al (1.2 eV) deposited on n-type material and very low for these metals on p-type layers. The behavior of Sb is unique with the barrier heights being 0.6–0.7 eV for both n- and p-type AlGaAsSb. The reason for the surface Fermi-level pinning for Au and Al could be related to a predominance of Ga-antisite–type native acceptors at the surface, which is not the case for Sb. Sulfur treatment of the surface is shown to decrease the barrier height for Au and to increase greatly the photosensitivity of Au Schottky diodes. The same effect is observed after treatment in a hydrogen plasma. In the latter case, changes in the Schottky barrier height are correlated with passivation of native acceptors in the bulk of the Al0.5Ga0.5As0.05Sb0.95.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 2882-2887 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects produced in InAs by hydrogen plasma treatment and proton implantation are discussed. It is shown that both treatments can produce an n-type layer at the surface of p-InAs. For the hydrogen plasma treatment the effect is explained by hydrogen donors complexing with the Be and Zn acceptors and rendering them electrically inactive, thus leaving the residual donors uncompensated. In proton implanted samples the p-n conversion is due to a creation of donor-type lattice defects.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 5588-5594 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: n-type GaAs specimens have been annealed in sealed quartz ampoules and characterized with electron-beam-induced current and photoresponse measurements, deep-level transient spectroscopy, and photoluminescence spectroscopy. By correlating changes in the concentrations of defects with minority-carrier diffusion length (Lp) it is shown that the dominant recombination center in this material is a hole trap termed HCX (Ev+0.29 eV). Increases in Lp of up to a factor of 3, which can be achieved by proximity annealing at 950 °C for 16 h, are related to the loss of As from the specimen surfaces during the early stages of annealing. The beneficial effect of the annealing is associated with a limited source diffusion process since the total amount of As loss is determined by the ratio of the ampoule volume to the GaAs surface area. Proximity protection of the surfaces is necessary to prevent the generation of a Ga vacancy-related hole trap HCZ (Ev+0.57 eV).
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of hydrogen treatment on electrical properties, luminescence spectra, and deep traps in InGaAlP and InGaP have been studied. It is shown that acceptors and donors (both shallow and deep) can be effectively passivated by hydrogen. The hydrogen is found not only to passivate the main electron and hole traps in our samples, but also to generate electron traps in n-InGaAlP and hole traps in p-InGaP. The influence of hydrogen treatment mode (direct plasma or a crossed-beams source in which the low-energy ion bombardment of the surface is effectively eliminated) on hydrogen concentration and hydrogen profiles in InGaAlP are discussed. © 1994 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 58 (1991), S. 2354-2356 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The formation and growth of holes and hillocks at grain boundary triple junctions in thin-film conductors of gold on gallium arsenide and thin-film conductors of aluminum-1 wt. % silicon on (oxidized) silicon during the early stages of electromigration have been investigated through measurement of fractional change of electrical resistance ΔR/R and microstructural characterization by scanning and transmission electron microscopy. Each grain boundary triple junction is characterized by a unique structure factor ΔY, which defines the degree of cumulative flux divergence and, consequently, the degree of susceptibility to formation and growth of holes or hillocks. Resultant holes are characterized by a shape factor f, which defines the degree of noncircularity and, consequently, relates fractional change of hole area to ΔR/R. Estimates of the upper limit for ΔY and the average value of f are in good agreement with measured values of ΔR/R and consistent with observed microstructure.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 3497-3504 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of isoelectronic doping of GaAs by In or Sb on the electron deep levels in n-GaAs grown by molecular-beam epitaxy have been investigated in the growth temperature range 500–600 °C for Si doping levels of 4–7×1016 cm−3 and As-stabilized conditions. The two dominant traps M3 and M6 are drastically reduced in concentration by up to three orders of magnitude for M3 (from 1015 cm−3 down to 〈1012 cm−3) and two and a half orders of magnitude for M6 by introducing 0.2–1 at.% In or Sb and increasing growth temperatures from 500 to 550 °C. The trap concentrations of M3 and M6 were also significantly reduced by increasing the growth temperature to 600 °C without In or Sb doping and by decreasing the growth rate from 1.0 to 0.3 μm/h. The incorporation coefficients of In and Sb have been measured and are found to decrease with increasing growth temperature. The growths with high M3 and M6 trap densities are shown to have short minority-carrier diffusion lengths. Indium isoelectronic doping, which is presumed to take place on a gallium sublattice site, and Sb doping, which is expected to take place on an arsenic sublattice site, appear to have rather similar effects in suppressing the concentration of the M3 and M6 electron traps. This suggest that both of these traps are in some way related to (VAsVGa) complexes or (VAsXVGa) complexes where X is different for M3 and M6 and might be interstitial or impurity related.
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