Keywords:
Organophosphorus compounds - Periodicals.
;
Electronic books.
Description / Table of Contents:
A concise but comprehensive annual survey of a vast field of study enabling the reader to rapidly keep abreast of the latest developments in this specialist area.
Type of Medium:
Online Resource
Pages:
1 online resource (363 pages)
Edition:
1st ed.
ISBN:
9781847554345
Series Statement:
Issn Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1185918
DDC:
547.07 21
Language:
English
Note:
Organophosphorus Chemistry -- Contents -- Chapter 1 Phosphines and Phosphonium Salts -- 1 Phosphines -- Preparation -- From Halogenophosphines and Organometallic Reagents -- From Metallated Phosphines -- By Addition of P-H to Unsaturated Compounds -- By Reduction -- Miscellaneous Methods -- Reactions -- Nucleophilic Attack at Carbon -- Nucleophilic Attack at Halogen -- Nucleophilic Attack at Other Atoms -- Miscellaneous Reactions -- 2 Phosphonium Salts -- Preparation -- Reactions -- Alkaline Hydrolysis -- Additions to Unsaturated Phosphonium Salts -- Miscellaneous Reactions -- 3 pπ-Bonded Phosphorus Compounds -- 4 Phospholes and Phosphorins -- Chapter 2 Quinquecovalent Phosphorus Compounds -- 1 Introduction -- 2 Structure, Bonding, and Reorganization of Ligands -- 3 Phosphoranes that contain a P-H Bond -- 4 Acyclic Phosphoranes -- 5 Four-membered-ring Phosphoranes -- 6 Five-membered-ring Phosphoranes -- 7 Six- and Seven-membered-ring Phosphoranes -- 8 Hexaco-ordinated Phosphorus Compounds -- Chapter 3 Halogenophosphines and Related Compounds -- 1 Introduction -- 2 Halogenophosphines -- Preparation -- Physical and Structural Aspects -- Reactions that lead to pπ Bonds to Phosphorus -- Reactions with Alkenes or Dienes -- Reactions with Carbanions -- Reactions with Carbonyl Compounds -- Reactions with Oxygen Nucleophiles -- Reactions with Phosphorus Nucleophiles -- Miscellaneous Reactions -- 3 Silylphosphines -- 4 Halogenophosphoranes -- Preparation -- Physical and Structural Aspects -- Reactions -- Chapter 4 Phosphine Oxides and Related Compounds -- 1 Introduction -- 2 Preparation of Acyclic Oxides -- 3 Preparation of Cyclic Oxides -- 4 Structural and Physical Aspects -- 5 Reactions at Phosphorus -- 6 Reactions of the Side-Chain -- 7 Phosphine Oxide Complexes and Extractants -- Chapter 5 Tervalent Phosphorus Acids -- 1 Introduction.
,
2 Phosphorous Acid and its Derivatives -- Nucleophilic Reactions -- Attack on Saturated Carbon -- Attack on Unsaturated Carbon -- Attack on Oxygen -- Attack on Halogen -- Electrophilic Reactions -- Reactions involving Two- co-ordinate Phosphorus -- Cyclic Esters of Phosphorous Acid -- Miscellaneous Reactions -- 3 Phosphonous and Phosphinous Acids and their Derivatives -- Chapter 6 Quinquevalent Phosphorus Acids -- 1 Synthesis -- General -- Phosphoric Acid and its Derivatives -- Phosphonic and Phosphinic Acids and their Derivatives -- 2 Reactions -- General -- Phosphoric Acid and its Derivatives -- Phosphonic and Phosphinic Acids and their Derivatives -- Chapter 7 Phosphates and Phosphonates of Biochemical Interest -- 1 Introduction -- 2 Coenzymes and Cofactors -- 3 Sugar Phosphates -- 4 Phospholipids -- 5 Phosphonates -- 6 Enzyme Mechanisms -- 7 Other Compounds of Biochemical Interest -- Chapter 8 Nucleotides and Nucleic Acids -- 1 Introduction -- 2 Mononucleotides -- Chemical Synthesis -- Cyclic Nucleotides -- Affinity Chromatography -- 3 Nucleoside Polyphosphates -- Chemical Synthesis -- Affinity Labelling -- 4 Oligo- and Poly-nucleotides -- Chemical Synthesis -- Enzymatic Synthesis -- Sequencing -- Other Studies -- 5 Analytical Techniques and Physical Methods -- Chapter 9 Ylides and Related Compounds -- 1 Introduction -- 2 Methylenephosphoranes -- Preparation and Structure -- Reactions -- Aldehydes -- Ketones -- Miscellaneous -- 3 Reactions of Phosphonate Anions -- 4 Selected Applications in Synthesis -- Carbohydrates -- Carotenoids and Related Compounds -- β-Lactam Antibiotics -- Leucotrienes and Related Compounds -- Pheromones -- Prostaglandins -- Miscellaneous Applications -- Chapter 10 Mass Spectrometry of Organophosphorus Compounds -- 1 Introduction -- 2 Techniques -- Chemical Ionization and 'In-Beam' Evaporation Techniques.
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Negative-ion Chemical Ionization -- Field Desorption and lonization by Energetic Particles -- Identification of Metastable Ions -- Liquid Chromatography -- 3 Natural Products -- Nucleotides -- Phospholipids -- Miscellaneous Natural Phosphates -- 4 Synthetic Compounds -- Organophosphorus Ester Pesticides -- Phosphates -- Phosphonates -- Phosphites -- Phosphinates -- Phosphines -- Phosphonium Salts -- Phosphazenes -- Miscellaneous -- Chapter 11 Physical Methods -- 1 Nuclear Magnetic Resonance Spectroscopy -- Biological, Analytical, and Instrumental Aspects -- Chemical Shifts and Shielding Effects -- Phosphorus-31 -- δp of n1 compounds -- δp of n2 compounds -- δp of n3 compounds -- δp of n4 compounds -- δp of n5 compounds -- Hydrogen-1, -2, and -3 -- Carbon-13 -- Oxygen-17 -- Fluorine-19 -- Studies of Equilibria, Hydrogen-Bonding, and Shift Reagents -- Variable-Temperature Studies: Inversion -- Restricted Rotation and Conformation -- Pseudorotation -- Spin-Spin Couplings -- J(PM) and J(PP) -- J(PF) -- J(PN) -- J(PC) -- 1J(PD) -- 2J(PCH) -- J(PCCnH) and J(POCnH) -- Relaxation, CIDNP, and N.Q.R. -- Relaxation -- CIDNP -- N.Q.R. -- 2 Electron Spin Resonance Spectroscopy -- 3 Vibrational and Rotational Spectroscopy -- Band Assignments and Absorptivity -- Bonding -- Stereochemistry -- Rotational Data -- 4 Electronic Spectroscopy -- Absorption Spectroscopy -- Photoelectron Spectroscopy -- Optical Rotation -- 5 Diffraction -- X-Ray Diffraction -- Electron Diffraction -- 6 Dipole Moments and Kerr Effects -- 7 Values of pKa and Thermochemical and Kinetic Studies -- 8 Chromatography and Surface Properties -- Gas-Liquid Chromatography -- Thin-Layer, Paper, and Gel Chromatographies -- High-Performance Liquid Chromatography -- Column Chromatography -- Surface Properties -- Author Index.
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