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  • 1
    Publication Date: 2021-02-17
    Description: The number concentrations and size distributions of aerosol particles 〉0.3 mm diameter were measured at the summit of Mount Etna and up to 10 km downwind from the degassing vents during July and August 2004. Aerosol number concentrations reached in excess of 9 106 L 1 at summit vents, compared to 4–8 104 L 1 in background air. Number concentrations of intermediate size particles were higher in emissions from the Northeast crater compared to other summit crater vents, and chemical composition measurements showed that Northeast crater aerosols contained a higher mineral cation content compared to those from Voragine or Bocca Nuova, attributed to Strombolian or gas puffing activity within the vent. Downwind from the summit the airborne plume was located using zenith sky ultraviolet spectroscopy. Simultaneous measurements indicated a coincidence of elevated ground level aerosol concentrations with overhead SO2, demonstrating rapid downward mixing of the plume onto the lower flanks of the volcano under certain meteorological conditions. At downwind sites the ground level particle number concentrations were elevated in all size fractions, notably in the 2.0–7.5 mm size range. These findings are relevant for assessing human health hazard and suggest that aerosol size distribution measurements may aid volcanic risk management.
    Description: Published
    Description: D10302
    Description: JCR Journal
    Description: reserved
    Keywords: aerosols ; Mount Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Improving the constraints on the atmospheric fate and depletion rates of acidic compounds persistently emitted by non-erupting (quiescent) volcanoes is important for quantitatively predicting the environmental impact of volcanic gas plumes. Here, we present new experimental data coupled with modelling studies to investigate the chemical processing of acidic volcanogenic species during tropospheric dispersion. Diffusive tube samplers were deployed at Mount Etna, a very active open-conduit basaltic volcano in eastern Sicily, and Vulcano Island, a closed-conduit quiescent volcano in the Aeolian Islands (northern Sicily). Sulphur dioxide (SO2), hydrogen sulphide (H2S), hydrogen chloride (HCl) and hydrogen fluoride (HF) concentrations in the volcanic plumes (typically several minutes to a few hours old) were repeatedly determined at distances from the summit vents ranging from 0.1 to 10 km, and under different environmental conditions. At both volcanoes, acidic gas concentrations were found to decrease exponentially with distance from the summit vents (e.g., SO2 decreases from 10 000 μg/m3 at 0.1 km from Etna’s vents down to 7 μg/m3 at 10 km distance), reflecting the atmospheric dilution of the plume within the acid gas-free background troposphere. Conversely, SO2/HCl, SO2/HF, and SO2/H2S ratios in the plume showed no systematic changes with plume aging, and fit source compositions within analytical error. Assuming that SO2 losses by reaction are small during short-range atmospheric transport within quiescent (ash-free) volcanic plumes, our observations suggest that, for these short transport distances, atmospheric reactions for H2S and halogens are also negligible. The one-dimensional model MISTRA was used to simulate quantitatively the evolution of halogen and sulphur compounds in the plume of Mt. Etna. Model predictions support the hypothesis of minor HCl chemical processing during plume transport, at least in cloud-free conditions. Larger variations in the modelled SO2/HCl ratios were predicted under cloudy conditions, due to heterogeneous chlorine cycling in the aerosol phase. The modelled evolution of the SO2/H2S ratios is found to be substantially dependent on whether or not the interactions of H2S with halogens are included in the model. In the former case, H2S is assumed to be oxidized in the atmosphere mainly by OH, which results in minor chemical loss for H2S during plume aging and produces a fair match between modelled and measured SO2/H2S ratios. In the latter case, fast oxidation of H2S by Cl leads to H2S chemical lifetimes in the early plume of a few seconds, and thus SO2 to H2S ratios that increase sharply during plume transport. This disagreement between modelled and observed plume compositions suggests that more in-detail kinetic investigations are required for a proper evaluation of H2S chemical processing in volcanic plumes.
    Description: Published
    Description: 11653–11680
    Description: open
    Keywords: tropospheric processing ; volcanic gas plumes ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Measuring Hg/SO2 ratios in volcanic emissions is essential for better apportioning the volcanic contribution to the global Hg atmospheric cycle. Here, we report the first real-time simultaneous measurement Hg and SO2 in a volcanic plume, based on Lumex and MultiGAS techniques, respectively. We demonstrate that the use of these novel techniques allows the measurements of Hg/SO2 ratios with a far better time resolution than possible with more conventional methods. The Hg/SO2 ratios in the plume of F0 fumarole on La Fossa Crater, Vulcano Island spanned an order of magnitude over a 30 minute monitoring period, but was on average in qualitative agreement with the Hg/SO2 ratio directly measured in the fumarole (mean plume and fumarole ratios being 1.09 x 10-6 and 2.9 x 10-6, respectively). The factor 2 difference between plume and fumarole compositions provides evidence for fast Hg chemical processing the plume.
    Description: Published
    Description: L21307
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: partially_open
    Keywords: Mercury ; Fumarolic condensates ; Volcanic emissions ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: Improving the constraints on the atmospheric fate and depletion rates of acidic compounds persistently emitted by non-erupting (quiescent) volcanoes is important for quantitatively predicting the environmental impact of volcanic gas plumes. Here, we present new experimental data coupled with modelling studies to investigate the chemical processing of acidic volcanogenic species during tropospheric dispersion. Diffusive tube samplers were deployed at Mount Etna, a very active open-conduit basaltic volcano in eastern Sicily, and Vulcano Island, a closed-conduit quiescent volcano in the Aeolian Islands (northern Sicily). Sulphur dioxide (SO2), hydrogen sulphide (H2S), hydrogen chloride (HCl) and hydrogen fluoride (HF) concentrations in the volcanic plumes (typically several minutes to a few hours old) were repeatedly determined at distances from the summit vents ranging from 0.1 to ~10 km, and under different environmental conditions. At both volcanoes, acidic gas concentrations were found to decrease exponentially with distance from the summit vents (e.g., SO2 decreases from ~10,000 μg/m3 at 0.1 km from Etna’s vents down to ~7 _μg/m3 at ~10km distance), reflecting the atmospheric dilution of the plume within the acid gas-free background troposphere. Conversely, SO2/HCl, SO2/HF, and SO2/H2S ratios in the plume showed no systematic changes with plume aging, and fit source compositions within analytical error. Assuming that SO2 losses by reaction are small during short-range atmospheric transport within quiescent (ash-free) volcanic plumes, our observations suggest that, for these short transport distances, atmospheric reactions for H2S and halogens are also negligible. The one-dimensional model MISTRA was used to simulate quantitatively the evolution of halogen and sulphur compounds in the plume of Mt. Etna. Model predictions support the hypothesis of minor HCl chemical processing during plume transport, at least in cloud-free conditions. Larger variations in the modelled SO2/HCl ratios were predicted under cloudy conditions, due to heterogeneous chlorine cycling in the aerosol phase. The modelled evolution of the SO2/H2S ratios is found to be substantially dependent on whether or not the interactions of H2S with halogens are included in the model. In the former case, H2S is assumed to be oxidized in the atmosphere mainly by OH, which results in minor chemical loss for H2S during plume aging and produces a fair match between modelled and measured SO2/H2S ratios. In the latter case, fast oxidation of H2S by Cl leads to H2S chemical lifetimes in the early plume of a few seconds, and thus SO2 to H2S ratios that increase sharply during plume transport. This disagreement between modelled and observed plume compositions suggests that more in-detail kinetic investigations are required for a proper evaluation of H2S chemical processing in volcanic plumes.
    Description: Published
    Description: 1441-1450
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: open
    Keywords: Mt. Etna ; volcanic gas plumes ; tropospheric processing ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: There is an urgent need to better constrain the global rates of mercury degassing from natural sources, including active volcanoes. Hitherto, estimates of volcanic fluxes have been limited by the poorly-determined speciation of Hg in volcanic emissions. Here, we present a systematic characterisation of mercury partitioning between gaseous (Hg(g)) and particulate (Hg(p)) forms in the volcanic plume of Mount Etna, the largest open-vent passively degassing volcano on Earth. We demonstrate that mercury transport is predominantly in the gas-phase, with a mean Hg(p)/Hg(g) ratio of ∼0.01 by mass. We also present the first simultaneous measurement of divalent gaseous mercury (HgII(g)) and total gaseous mercury (Hg(g)) in a volcanic plume, which suggests that Hg0(g) is the prevalent form of mercury in this context. These data are supported by the results of model simulations, carried out with HSC thermodynamic software. Based on a mean ‘bulk plume’ Hg/SO2 mass ratio of 8.7×10-6, and a contemporaneous volcanic SO2 flux of 0.8 Mt·yr-1, we estimate an Hg emission rate from Mt. Etna during passive degassing of 5.4 t·y-1 (range, 1.1-10 t·y-1). This corresponds to ~0.6% of global volcanic Hg emissions, and about 5% of Hg released from industrial activities in the Mediterranean area.
    Description: Published
    Description: 7377-7388
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Atmospheric mercury ; Volcanic degassing ; Gaseous and particulate mercury ; Atmospheric budgets ; 01. Atmosphere::01.01. Atmosphere::01.01.01. Composition and Structure ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: We report measurements of Hg, SO2, and halogens (HCl, HBr, HI) in volcanic gases from Masaya volcano, Nicaragua, and gaseous SO2 and halogens from Telica volcano, Nicaragua. Mercury measurements were made with a Lumex 915+ portable mercury vapor analyzer and gold traps, while halogens, CO2 and S species were monitored with a portable multi gas sensor and filter packs. Lumex Hg concentrations in the plume were consistently above background and ranged up to 350 ng/m3. Hg/SO2 mass ratios measured with the real-time instruments ranged from 1.1*10-7 to 3.5*10-5 (mean 2*10-5). Total gaseous mercury TGM)concentrations measured by gold trap ranged from 100 to 225 ng/m3. Reactive gaseous mercury accounted for 1% of TGM, while particulate mercury was 5% of the TGM. Field measurements of Masaya’s SO2 flux, combined with the Hg/SO2 ratio, indicate a Hg flux from Masaya of 7.2 Mg/a-1. At Masaya’s low temperature fumaroles, Hg/CO2 mass ratios were consistently around 2*10-8, lower than observed in the main vent (Hg/CO2 10-7). Low-temperature fumarole Hg fluxes from Masaya are insignificant (150 g a-1). Ratios of S, C and halogen species were also measured at Masaya and Telica volcanoes. CO2/SO2 ratios at Masaya ranged from 2.8 to 3.9, comparable to previously published values. At Masaya molar Br/SO2 was 3*10-4 and I/SO2 was 2*10-5, suggesting fluxes of 0.2–0.5 Mg HBr d-1 and 0.02–0.05 Mg HI d-1. At Telica the Br/SO2 ratio was also 3*10-4 and the I/SO2 ratio was 5.8*10-5, with corresponding fluxes of 0.2 Mg HBr d-1 and 0.06 Mg HI d-1. Gases at both volcanoes are enriched in I relative to Br and Cl, compared to gases from volcanoes elsewhere.
    Description: This work was funded by NERC grant NE/ C511180/1/.
    Description: Published
    Description: B06203
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mercury ; Halogen ; Volcanic emissions ; Masaya volcano ; Telica volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2017-04-04
    Description: Sweet chestnut leaves (Castanea sativa) collected from the flanks of Mt Etna volcano in 2005–2007 were analysed by inductively-coupled plasma mass spectrometry to investigate the spatial and temporal variability of element concentrations. The aim of this work was to determine whether these leaves are a bio-indicator for volcanic gas, aerosol and ash deposition and to gain new insights into the environmental effects of quiescent and eruptive volcanic plumes. Results show a positive correlation between sample variability in the concentration of elements in Castanea sativa and enrichment factors of elements in the plume. The spatial and temporal variability of chalcophilic elements (As, Cd, Cu, Mo, Tl, Zn) is consistent with prevailing winds transporting eruptive plumes to the south-east of the summit, resulting in enhanced plume deposition onto the flanks of the volcano. Similar spatial and temporal variability was found for the halideforming elements (Cs, K, Rb) and intermediate elements (Al, Co, Mn). The spatial variability of chalcophilic, intermediate and halide-forming elements during quiescent periods was diminished (relative to eruptive periods) and could not be explained by plume deposition. In contrast, the concentrations of lithophilic elements (Ba, Ca, Mg, Sr) did not show any clear spatial variability even during eruptive periods. Comparisons between enrichment factors for elements in Castanea sativa and literature values for enrichment factors of the volcanic plume, groundwater and lichen were made. Whilst Castanea sativa offers insights into the spatial and temporal variability of deposition, the species may not be a bio-indicator for plume composition due to biological fractionation.
    Description: Published
    Description: 107-119
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mt Etna ; vegetation ; Castanea sativa ; bio-indicator ; emission ; dispersion ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2012-02-03
    Description: We present results from a campaign in March 2009 to assess the current state of emissions from Masaya Volcano, Nicaragua. These results constitute one of the most comprehensive inventories to date of emissions from an active volcano and update the exceptional record of emissions from Masaya. Results from open‐path Fourier transform infrared spectroscopy and filter packs demonstrate that, in terms of H2O, SO2,CO2, HCl,and HF (molar H2O/SO2 = 63, CO2/SO2 = 2.7, SO2/HCl = 1.7, SO2/HF = 8.8), the 2009 gas composition was highly comparable to that from the 1998 to 2000 period,indicating stability of the shallow magma system. This continuity extends to certain aerosol species (molar SO2/SO42−= 190, Na+ /SO4 2−= 0.68, K+/SO4 2−= 0.71, Ca 2+/SO4 2−= 1.6 × 10−2,Mg2+/SO4 2− = 3.6 × 10−3) and, to a lesser extent, the heavy halogens (i.e., molar HCl/HBr = 2.4 × 103 , HCl/HI = 5.0 × 104). In contrast to an arlier study at Masaya, we did not detect HNO3.SO2 fluxes were low (690 Mg d−1 ), suggesting that Masaya was close to the minimum of its degassing cycle. By combining compositional results with the SO2 flux, we estimate a total volatile flux of 14,000 Mg d−1. This rate is consistent with 1−4 wt% volatile loss from a convective magma flux of 17,000–4000 kg s−1. These results will allow for a better understanding of degassing processes at Masaya and other basaltic volcanoes
    Description: NERC project “Magma dynamics at persistently degassing basaltic volcanoes: A novel approach to linking volcanic gases and magmatic volatiles within a physical model” (NE/F004222/1 and NE/F005342/1).
    Description: Published
    Description: B09215
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Masaya Volcano ; Degassing regime ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2017-04-04
    Description: Here we report results from a multidisciplinary field campaign at Villarrica volcano, Chile, in March 2009. A range of direct sampling and remote sensing techniqueswas employed to assess gas and aerosol emissions from the volcano, and extend the time series of measurements that have been made during recent years. Airborne traverses beneath the plume with an ultraviolet spectrometer yielded an average SO2 flux of 3.7 kg s−1. This value is similar to previous measurements made at Villarrica during periods of quiescent activity. The composition of the plume was measured at the crater rim using electrochemical sensors and, for the first time, open-path Fourier transforminfrared spectroscopy, yielding a composition of 90.5 mol% H2O, 5.7% CO2, 2.6%SO2, 0.9% HCl, 0.3% HF and b0.01% H2S. Comparison with previous gas measurements made between 2000 and 2004 shows a correlation between increased SO2/HCl ratios and periods of increased activity. Base-treated filter packs were also employed during our campaign, yielding molar ratios of HBr/SO2=1.1×10−4, HI/SO2=1.4×10−5 and HNO3/SO2=1.1×10−3 in the gas phase. Our data represent the most comprehensive gas inventory at Villarrica to date, and the first evaluation of HBr and HI emissions from a South American volcano. Sun photometry of the plume showed the near-source aerosol size distributions were bimodal with maxima at b0.1 and ~1 μm. These findings are consistent with results from analyses in 2003. Electron microscope analysis of particulatematter collected on filters showed an abundance of sphericalmicron-sized particles that are rich in Si, Mg and Al. Non-spherical, S-rich particles were also observed.
    Description: Antofagasta plc via the University of Cambridge Centre for Latin American Studies, NERC Field Spectroscopy Facility, NERC projectNE/F004222/1, “Volgaspec” projectANR-06-CATT-012-01 and from the NOVAC project. Istituto Nazionale di Geofisica e Vulcanologia and Dipartimento di Protezione Civile-Regione Sicilia. Christ's College, University of Cambridge, NERC IKIMP project, (NE/G001219/1) and NERC grantNE/G01700X/1 for financial support. NERC National Centre for EarthObservation (“Dynamic Earth and geohazards”)
    Description: Published
    Description: 62-75
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Villarrica ; FTIR ; SO2 flux ; DOAS ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2022-06-10
    Description: Between January 2011 and April 2012, Santorini volcano (Greece) experienced a period of unrest characterised by the onset of detectable seismicity and caldera-wide uplift. This episode of inflation represented the first sizeable intrusion of magma beneath Santorini in the past 50 years. We employ a new approach using 222 Rn– δ 13 C systematics to identify and quantify the source of diffuse degassing at Santorini during the period of renewed activity. Soil CO 2 flux measurements were made across a network of sites on Nea Kameni between September 2010 and January 2012. Gas samples were collected in April and September 2011 for isotopic analysis of CO 2 ( δ 13 C), and radon detectors were deployed during September 2011 to measure ( 222 Rn). Our results reveal a change in the pattern of degassing from the summit of the volcano (Nea Kameni) and suggest an increase in diffuse CO 2 emissions between September 2010 and January 2012. High-CO 2 -flux soil gas samples have δ 13 C ∼ 0 .Using this value and other evidence from the literature we conclude that these CO 2 emissions from Santorini were a mixture between CO 2 sourced from magma, and CO 2 released by the thermal or metamorphic breakdown of crustal limestone. We suggest that this mixing of magmatic and crustal carbonate sources may account more broadly for the typical range of δ 13 CvaluesofCO 2 (from ∼− 4 to ∼+ 1 )in diffuse volcanic and fumarole gas emissions around the Mediterranean, without the need to invoke unusual mantle source compositions. At Santorini a mixing model involving magmatic CO 2 (with δ 13 C of − 3 ± 2 and elevated ( 222 Rn)/CO 2 ratios ∼ 10 5 –10 6 Bqkg − 1 )andCO 2 released from decarbonation of crustal limestone (with ( 222 Rn)/CO 2 ∼ 30–300 Bqkg − 1 ,and δ 13 Cof + 5 ) can account for the δ 13 C and ( 222 Rn)/CO 2 characteristics of the ‘high flux’ gas source. This model suggests ∼ 60% of the carbon in the high flux deep CO 2 end member is of magmatic origin. This combination of δ 13 Cand( 222 Rn) measurements has potential to quantify magmatic and crustal contributions to the diffuse outgassing of CO 2 in volcanic areas, especially those where breakdown of crustal limestone is likely to contribute significantly to the CO 2 flux
    Description: Published
    Description: 180-190
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic unrest ; soil gas measurements ; carbon isotopic analysis ; magmatic degassing ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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