ISSN:
1434-1948
Keywords:
Stannaborate cluster
;
Transition metal complexes
;
Tin
;
Coordination modes
;
Clusters
;
Boron
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reactions of the stannaborate salt [NBu4]2[SnB11H11] (1) with the organometallic electrophiles [CpFe(CO)2Br], [(C7H7)Mo(CO)2I], and [CpNi(PPh3)Cl] resulted in substitution of the halide to give the stannaborate coordination products [NBu4][CpFe(CO)2(SnB11H11)] (2), [NBu4][(C7H7)Mo(CO)2(SnB11H11)] (3), and [NBu4][CpNi(PPh3)(SnB11H11)] (4) in high yields. Single crystals of the air- and moisture-stable products have been characterized by X-ray crystal structure analyses.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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