GLORIA

GEOMAR Library Ocean Research Information Access

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
Document type
Publisher
Years
  • 1
    Electronic Resource
    Electronic Resource
    Internal states distributions of NO thermally desorbed from Pt(111): Dependence on coverage and co-adsorbed CO (1986)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 84 (1986), S. 5131-5142 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The distribution of population in the internal energy levels of nitric oxide thermally desorbed from Pt(111) has been probed using laser excited fluorescence. The observed rotational distributions have been found to follow the Boltzmann distribution function, independent of NO coverage or the presence of pre- or post-adsorbed CO. Under all conditions of NO desorption, the observed NO was characterized by a temperature (0.95±0.05) times the surface temperature. No evidence of a preferred alignment of the rotational angular momentum vectors was observed, nor was there any difference between the two spin-orbit multiplets beyond that associated with the rotational temperature.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.450666
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    NO thermally desorbed from a saturation coverage on Pt(111): Internal state distributions (1985)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 1046-1048 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Internal state distributions were obtained by laser-excited fluorescence for NO desorbing from a saturation coverage on Pt(111). Two major peaks are observed in the thermal desorption spectrum at crystal temperatures Ts=200 and 340 K. The rotational state distributions for each desorption feature were Boltzmann, described by the rotational temperatures TR=195±10 K and 305±10 K, respectively. The two spin-orbit states were occupied to a degree consistent with equilibration between spin and rotational degrees of freedom, both Lambda doublet species were statistically populated and no molecular alignment was observed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.448525
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...