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  • 1
    Publication Date: 2012-02-23
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 2
    Publication Date: 2016-12-21
    Description: Dissolved Pb and Nd isotope ratios of seawater, as recorded by chemical marine precipitates such as hydrogenetic ferromanganese crusts, have been used as paleoenvironmental proxy tracers. For the North Pacific, however, all ferromanganese crusts studied so far have either been subject to phosphatization or hydrothermal influence in their old part, or only the young parts have been analyzed. Thus, the Pb and Nd isotope compositions of North Pacific deep waters prior to ∼20 Ma are not well constrained. We present new results for three ferromanganese crusts, one of which (CJ01) shows no phosphatization and is located far away from the EPR. Its age is inferred to be ∼75 Ma and thus provides for the first time an opportunity to trace the Nd and Pb isotope evolution of central North Pacific seawater back to the latest Cretaceous. The three crusts, no matter whether phosphatized or not, display very similar Pb and Nd isotope trends with age, suggesting no modification of the Pb and Nd isotope distribution by post-depositional phosphatization. Our data suggest that dissolved Pb in deep waters of the central North Pacific over the Cenozoic and latest Cretaceous has mainly been derived from eolian dust and only to a minor extent from weathering of island arcs. For Pb these trends broadly resemble the Pb isotope evolution of the eolian silicate dust fraction of core LL44-GPC3 in the central North Pacific. We suggest that the isotope evolution of dissolved Pb in central North Pacific seawater has been mainly controlled by Pb released from eolian dust from North America prior to 50 Ma and after 40 Ma from Asia. In contrast, the Nd isotope time series of the crusts are by no means similar to the Nd isotope evolution of the silicate dust fraction in core GPC3, suggesting a decoupling from the Pb and negligible contributions from dust to the dissolved Nd in the central North Pacific deep water. The rise of Nd isotope ratios of Pacific seawater during the Cenozoic has most likely been caused by the increasing volcanic activity and erosion of the volcanic arcs around the Pacific.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2016-11-14
    Description: Two ferromanganese crusts from the Indian Ocean and one from the Atlantic Ocean have been analysed for 10Be/9Be, 143Nd/144Nd and 208,207,206Pb/204Pb ratios as a function of depth beneath their growth surfaces. 10Be/9Be ratios provide growth rate estimates for these crusts between 1.55 and 2.82 mm Ma−1 and further suggest that 87Sr/86Sr in crusts do not in any case examined so far provide reliable estimates for growth rates. A crust ALV-539 from 35°N in the western N. Atlantic has ϵNd and Pb-isotope variations indistinguishable from crust BM-1969.05 from 39°N in the N. Atlantic [K.W. Burton, H.-F. Ling, R.K. O'Nions, Closure of the central American isthmus and its impact on North Atlantic deepwater circulation, Nature (London) 386 (1997) 382–385] when 10Be/10Be ratios are used to estimate growth rates. Both crusts provide evidence for a marked change in deepwater composition in the western N. Atlantic with a reduction in ϵNd and an increase in 206Pb/204Pb from ∼8 Ma ago towards the present day. The two crusts from the Indian Ocean show comparatively small variations in ϵNd between −8.0 and −7.0 over the last 20 Ma and do not show the large shift in ϵNd seen in the Atlantic crusts. Comparison of ϵNd in the crusts analysed here with those published previously [H.-F. Ling, K.W. Burton, R.K. O'Nions, B.S. Kamber, F. von Blanckenburg, A.J. Gibb, J.R. Hein, Evolution of Nd and Pb isotopes in central Pacific seawater from ferromanganese crusts, Earth Planet. Sci. Lett. 146 (1997) 1–12; K.W. Burton, H-F. Ling, R.K. O'Nions, Closure of the central American isthmus and its impact on North Atlantic deepwater circulation, Nature (London) 386 (1997) 382–385] shows that provinciality in the present-day ϵNd structure of the Pacific, Atlantic and Indian Oceans has been maintained over ∼20 Ma or more despite the palaeogeographic changes that have occurred within this period. These include the closure of the Panama gateway and the uplift of the Himalayas. Superimposed on this broad inter-ocean structure are changes in ϵNd of the western N. Atlantic which may relate to the Panama gateway closure and shifts in the ϵNd of equatorial Pacific deepwater from 3–5 Ma ago. The absence of any such structure in ϵNd of the southwest and central Indian Ocean suggests that Himalayan erosion products such as preserved in the Bengal Fan sediments have not contributed significantly to Indian Ocean deepwater over the last 20 Ma. There is no straightforward relationship between records of 87Sr/86Sr in the global ocean and ϵNd in ocean deepwater as would be expected if inputs of radiogenic Sr and unradiogenic Nd were coupled.
    Type: Article , PeerReviewed
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  • 4
    Publication Date: 2018-07-13
    Description: Rising oceanic and atmospheric oxygen levels through time have been crucial to enhanced habitability of surface Earth environments. Few redox proxies can track secular variations in dissolved oxygen concentrations around threshold levels for metazoan survival in the upper ocean. We present an extensive compilation of iodine-to-calcium ratios (I/Ca) in marine carbonates. Our record supports a major rise in the partial pressure of oxygen in the atmosphere at ~400 million years (Ma) ago and reveals a step change in the oxygenation of the upper ocean to relatively sustainable near-modern conditions at ~200 Ma ago. An Earth system model demonstrates that a shift in organic matter remineralization to greater depths, which may have been due to increasing size and biomineralization of eukaryotic plankton, likely drove the I/Ca signals at ~200 Ma ago.
    Keywords: Geochemistry, Geophysics
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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