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  • 1
    Online Resource
    Online Resource
    Singapore :Springer Singapore Pte. Limited,
    Keywords: Chemical bonds. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (132 pages)
    Edition: 1st ed.
    ISBN: 9789811604324
    Series Statement: SpringerBriefs in Molecular Science Series
    DDC: 541.395
    Language: English
    Note: Intro -- Preface -- Contents -- 1 Theoretical View of Rh-Catalyzed C-H Functionalization -- 1.1 A Brief History of Rh-Catalyzed C-H Functionalization -- 1.1.1 General View of Organometallic Chemistry -- 1.1.2 A Brief History of Rh-Catalyzed C-H Functionalization -- 1.2 Using Computational Tool to Study the Mechanism of Rh-Catalyzed C-H Functionalization -- 1.2.1 Mechanism of Rh-Catalyzed C-H Functionalization -- 1.2.2 Mechanistic Study of Rh-Catalyzed C-H Functionalization by Theoretical Methods -- References -- 2 Computational Methods in Rh-Catalyzed C-H Functionalization -- 2.1 DFT Method -- 2.1.1 Basis Set -- 2.1.2 Solvent Effect -- References -- 3 Theoretical Study of Rh-Catalyzed C-C Bond Formation Through C-H Activation -- 3.1 Rh-Catalyzed C-H Bond Arylation -- 3.1.1 C-H Bond Arylation with Electrophiles -- 3.2 Rh-Catalyzed C-H Bond Alkylation -- 3.2.1 C-H Bond Alkylation by Using Olefins -- 3.2.2 C-H Bond Alkylation by Using Alkynes -- 3.2.3 C-H Bond Alkylation by Using Diazo Compound -- 3.3 Rh-Catalyzed C-H Bond Alkenylation -- 3.3.1 C-H Bond Alkenylation by Using Olefins -- 3.3.2 C-H Bond Alkenylation by Using Alkynes -- 3.4 Rh-Catalyzed C-H Bond Alkynylation -- 3.5 Rh-Catalyzed C-H Bond Carbonylation -- 3.6 Rh-Catalyzed C-H Bond Annulation -- 3.6.1 Directing Group as Electrophile -- 3.6.2 Directing Group as Nucleophile -- 3.6.3 Directing Group as Internal Oxidants -- 3.7 Rh-Mediated Carbene Transfer -- 3.7.1 Outer-Sphere C-H Activation by Rh-Carbene Complex -- 3.7.2 Sequential C-H Activation and Inner-Sphere Carbene Insertion -- References -- 4 Theoretical View of Rh-Catalyzed C-H Functionalization for the Construction of C-X Bonds (X = O, N, B, Si, or Halide) -- 4.1 C-O Bond Formation -- 4.2 C-N Bond Formation -- 4.2.1 Rh-Mediated C-H Amination by Using Nitrene Precursor -- 4.2.2 C-H Bond Azidation Reaction. , 4.3 C-Halide Bond Formation -- 4.4 C-B Bond Formation -- 4.5 C-Si Bond Formation -- References.
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  • 2
    Online Resource
    Online Resource
    Oxford :Elsevier Science & Technology,
    Keywords: Lignite -- Australia -- Victoria. ; Coal -- Australia -- Victoria. ; Electronic books.
    Description / Table of Contents: Over the past decade, extensive research has been conducted on the subject of coal as one of the world's leading energy sources. The current and future status of this resource is a topic of considerable interest to the largest world economies, including the US, Japan, China and Europe. Advances in the Science of Victorian Brown Coal provides critical reviews of the information and research published over this time, giving the reader an authoritative overview of the science surrounding this important topic. · Critical review of recent research surrounding the utilization of brown coal. Key issues addressed include maximized efficiency and minimized environmental impacts. · Focuses on Victorian Brown Coal within the context of biomass and bituminous coal. · A critical thermodynamic overview of various advanced power generation technologies.
    Type of Medium: Online Resource
    Pages: 1 online resource (485 pages)
    Edition: 1st ed.
    ISBN: 9780080526447
    DDC: 553.2209945
    Language: English
    Note: Front Cover -- Advances in the Science of Victorian Brown Coal -- Copyright Page -- Contents -- Preface -- Foreword -- Chapter 1. Introduction -- 1.1. Importance of Victorian Brown Coal as an Energy Source -- 1.2. An Introduction to the Typical Properties of Victorian Brown Coal -- 1.3. An Introduction to the Major Utilisation of Victorian Brown Coal -- References -- Chapter 2. Structure and Properties of Victorian Brown Coal -- 2.1. Introduction -- 2.2. Petrography of Victorian Brown Coal -- 2.3. Physical Structure and Properties of Victorian Brown Coal -- 2.4. Chemical Structure and Properties of Victorian Brown Coal -- References -- Chapter 3. Water in Brown Coal and its Removal -- 3.1. Introduction -- 3.2. Physics, Chemistry and Analytical Aspects of Water in Brown Coal -- 3.3. Drying of Low Rank Coals -- 3.4. Moisture and Binderless Briquetting of Brown Coal -- 3.5. Conclusion -- References -- Chapter 4. Pyrolysis of Victorian Brown Coal -- 4.1. Introduction -- 4.2. Effects of Operating Variables on the Pyrolysis of Brown Coal -- 4.3. Flash Pyrolysis of Brown Coal for Producing Chemicals -- 4.4. Volatilisation of Alkali and Alkaline Earth Metallic Species -- 4.5. Models for Coal Pyrolysis -- 4.6. Concluding Remarks -- References -- Chapter 5. Gasification and Combustion of Brown Coal -- 5.1. Gasification of Brown Coal -- 5.2. Combustion -- References -- Chapter 6. Conversion of Coal-N and Coals During Pyrolysis, Gasification and Combustion -- 6.1. Nitrogen in Victorian Brown Coal -- 6.2. Pyrolysis of N-Containing Model Compounds -- 6.3. Reaction Pathways Involving Coal-N during the Pyrolysis of Victorian Brown Coal -- 6.4. Formation of NOx and NOx Precursors during Gasification and Combustion -- 6.5. Sulphur in Victorian Brown Coal and Its Conversion during Pyrolysis, Gasification and Combustion -- References. , Chapter 7. An Overview of Advanced Power Generation Technologies Using Brown Coal -- 7.1. Introduction -- 7.2. Key Processes in Advanced Power Generation Technologies - Impacts of Low-Rank Coal -- 7.3. Advanced Power Generation Processes -- 7.4. Comparison of Efficiencies of Various Processes -- 7.5. Thermo-Chemical Recuperation, Gasification-Fuel Cell Systems -- 7.6. Research and Development Needs -- References -- Chapter 8. Liquefaction of Victorian Brown Coal -- 8.1. Introduction -- 8.2. Basic Reactions of Brown Coals in Liquefaction -- 8.3. Effects of Pretreatments on Liquefaction -- 8.4. Design of New Liquefaction Solvent and Catalyst -- 8.5. Design and Development of Liquefaction Process for Brown Coals -- 8.6. Product Evaluation and Upgrading -- 8.7. Development and Operation of Large Scale Pilot Plant of Victorian Brown Coal Liquefaction -- 8.8. Current and Future Status of Coal Liquefaction -- References -- Index.
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 50 (1985), S. 778-785 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 57 (1992), S. 128-132 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 52 (1987), S. 3541-3552 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 5351-5354 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Using angle-resolved Auger electron spectroscopy, we show, nondestructively, a sequential variation of the composition from the outermost layer to the second layer of a Cu0.81Pt0.19 alloy and provide new evidence for ion bombardment-induced Gibbsian segregation in that alloy when it was sufficiently bombarded with 2.8-keV Ar ions at 10 and −80 °C.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 5215-5215 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The observation of transition-metal (TM) magnetic moments in thin films aligned perpendicular to the surface has focused theoretical and experimental attention on the origin of magnetic anisotropy in these exciting low-dimensional materials. In this paper we report on a study of the magnetic anisotropy of Fe and Co thin films originating from the spin-orbit interaction term of the fully relativistic Dirac equation. We employ a total energy second variation FLAPW method in which: (i) the electronic charge density is determined with the semirelativistic (no spin-orbit) FLAPW method; (ii) relativistic eigenvalues are calculated via a variational procedure using the semirelativistic wave functions as basis. The magnetic anisotropy energy of free-standing Fe(001) and Co(001) monolayers yields in-plane orientation of the spin moment. Semirelativistic calculations determined the magnetic moments of 1Fe/1Au, 1Fe/1Ag, or 1Fe/1Pd−all (001) slabs; the results agree well with those of monolayer Fe on thicker substrates. Magnetic anisotropy results1 for Fe monolayers on Au, Ag, and Pd(001) substrates give perpendicular anisotropy for these films, in agreement with experiment. Magnetic anisotropy calculations of Co thin films on CuPd and (001) and (111) substrates will also be presented. The origin of the magnetic anisotropy is discussed from a detailed analysis of the electronic structure (electronic bands, Fermi surface). Comparisons are given to the work of Gay and Richter and Fritsche et al.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 535-541 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Properties of transverse electric waves in the microwave frequency range on a plane interface between a nonlinear antiferromagnet and a linear ferromagnet are investigated. It is revealed that there are two different field distributions and powers. An exact analytical dispersion relation is obtained. On the basis of the dispersion relation, we have investigated the properties of surface waves in this waveguide and, theoretically, found that there exist passbands and stop bands, which can be controlled by varying the power in the nonlinear gyromagnetic waveguides. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Atomic force microscopy was employed to quantitatively study the surface relief accompanying martensite and bainite in a Cu–Zn–Al alloy. It is demonstrated that the surface relief angle associated with martensite is 14.3°, in good agreement with the theoretical result deduced from the phenomenal theory of martensite crystallography (PTMC). However, the surface relief angle associated with bainite is 2.0°–3.2°, which disagrees with the PTMC result. This indicates that the transformation mechanism of bainite is different from that of martensite. The fine structures of the surface relief associated with martensite and bainite are also investigated. The surface relief of martensite is composed of the small parallel relief caused by small martensite plates, and that of bainite is composed of small cells induced by subunits in bainite. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 5 (1966), S. 3443-3448 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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