ISSN:
1572-879X
Keywords:
Homogeneous catalyst
;
ruthenium complex
;
carbamate
;
formamide
;
alcohol
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract In the presence of a catalytic amount of RuCl2(PPh3)3, various alkyl N-arylcarbamates are obtained in 23–82% yields by dehydrogenative reaction of N-aryl substituted formamides with alcohols. The present reaction offers an alternative method for phosgene- and carbon monoxide-free synthesis of carbamates.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00767076
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