Keywords:
Surface chemistry.
;
Adsorption.
;
Electronic books.
Description / Table of Contents:
The objective in initiating this series in 1980 was to provide an in-depth review of advances made in the understanding key aspects of surface chemistry and physics through the application of new techniques to the study of well-defined surfaces. Since then the field of surface science has greatly matured, and further important techniques, particularly scanning probe microscopies, have been successfully assimilated into the applications armoury of the surface scientist. The present volume is a series of timely reviews by many of the current experts in the field of phase transitions and adsorbate-induced surface restructuring. No aspect of the science of solid surfaces can be fully understood without accounting for the structural diversity of surfaces, now revealed in atomic detail by techniques based on diffraction and scanning probe microscopies. For example, it is now clear to those working in heterogeneous catalysis that adsorbate-induced restructuring of surfaces can play a critical role in phenomena such as bistability, kinetic oscillations, and promotion and poisoning. Structural transitions at surfaces can also play a key role in determining the electronic properties of surfaces, reviewed in volume 5.
Type of Medium:
Online Resource
Pages:
1 online resource (660 pages)
Edition:
1st ed.
ISBN:
9780444600639
Series Statement:
Issn Series ; v.Volume 7
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1129957
DDC:
546/.3
Language:
English
Note:
Front Cover -- The Chemical Physics of Solid Surfaces -- Copyright Page -- Table of Contents -- Contributors to Volume 7 -- Preface -- Chapter 1. Principles of Phase Transitions in Two-dimensional Systems -- 1. Introduction -- 2. Surface reconstructions -- 3 Commensurate Incommensurate Transitions -- 4 Surface Roughening -- 5 Roughening and the missing row reconstruction -- References -- Chapter 2. Instabilities and Adsorbate Restructuring at W{ 100} -- 1 INTRODUCTION -- 2 CLEAN (√2 x√2)R45° → (1 x 1) RECONSTRUCTION -- 3 HYDROGEN-INDUCED RECONSTRUCTION -- 4 CONCLUSION -- REFERENCES -- Chapter 3. The Au(110) (1x2)< -- => -- (1x1) phase transition -- 1. INTRODUCTION -- 2. THE SURFACE STRUCTURE OF Au(110) -- 3. FUNDAMENTALS OF PHASE TRANSITIONS. -- 4. THE Au(110) TRANSITIONS -- 5. REFERENCES -- Chapter 4. Roughening, Preroughening, and Reconstruction Transitions in Crystal Surfaces -- 1. INTRODUCTION -- 2. SURFACE RECONSTRUCTION. -- 3. TOPOLOGY OF DOMAIN WALL EXCITATIONS -- 4. CELL SPIN MODELS -- 5. DOMAIN WALL ENTROPY -- 6. CHIRALITY -- 7. RECONSTRUCTED PHASES WITH PARTIAL DISORDER -- 8. FRACTALS AND CONFORMAL INVARIANCE -- 9. SURFACE ROUGHENING -- 10. ROUGHENING INDUCED DECONSTRUCTION -- 11. PREROUGHENING TRANSITIONS -- 12. DOF PHASE AND PARTICLE-HOLE SYMMETRY -- REFERENCES -- Chapter 5. Two-dimensional phase transitions in alkali-metal adlayers -- 1. INTRODUCTION -- 2. INTERACTIONS IN ALKALI METAL ADLAYERS -- 3. ATOMIC STRUCTURE OF ALKALI-METAL ADLAYERS -- 4. PHASE TRANSITIONS AND PHASE DIAGRAMS -- 5. EFFECT OF THE PHASE TRANSITIONS IN AM OVERLAYERS ON PHYSICO-CHEMICAL PROPERTIES OF COVERED SURFACES -- 6. CONCLUSION -- ACKNOWLEDGEMENTS -- REFERENCES -- Chapter 6. Growth Kinetics in Two-dimensional Phase Transitions -- 1. INTRODUCTION -- 2. THEORETICAL BACKGROUND -- 3. EXPERIMENTAL -- 4. EXPERIMENTAL RESULTS -- 5. CONCLUSIONS-FUTURE PROBLEMS.
,
7. REFERENCES -- Chapter 7. Surface melting: an experimental overview -- 1. INTRODUCTION -- 2. MACROSCOPIC OBSERVATIONS -- 3. MICROSCOPIC OBSERVATIONS -- 4. RELATED SURFACE BEHAVIOUR -- 5. SURFACE NON-MELTING AND BULK SUPERHEATING -- 6. CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES -- Chapter 8. Thermal roughening of surfaces : experimental aspects -- 1. INTRODUCTION : THERMAL RESTRUCTURING AT SURFACES -- 2. EQUILIBRIUM CRYSTAL SHAPE (ECS) AND SURFACE ROUGHENING -- 3. DETECTION OF STEPS AT SURFACES -- 4. ROUGHENING OF NONVICINAL SURFACES -- 5. ROUGHENING OF VICINAL SURFACES -- 6. CONSEQUENCES OF SURFACE ROUGHENING ON CRYSTAL GROWTH -- References -- Chapter 9. ROUGHENING, WETTING AND SURFACE MELTING: -- 1. Introduction -- 2. Roughening -- 3. Wetting -- 4. Surface melting -- 5. Appendix -- ACKNOWLEDGMENTS -- References -- Chapter 10. Computer simulation of atomic dynamics on metal surfaces -- 1. INTRODUCTION -- 2. SIMULATION METHODS -- 3. POTENTIALS FOR SIMULATIONS OF METALS -- 4. SIMULATIONS OF FLAT SURFACES -- 5. FACETING OF STEPPED SURFACES. -- 6. ADATOM DIFFUSION ON SURFACES. -- 7. DIFFUSION ON STEPPED SURFACES -- 8. INTERACTING SURFACES. -- 9. CONCLUSIONS. -- REFERENCES -- Chapter 11. Structural Fluctuations in Small Particles -- 1. INTRODUCTION -- 2. BACKGROUND -- 3. EXPERIMENTAL EVIDENCE FOR STRUCTURAL FLUCTUATIONS -- 4. KINETICS -- 5. DISCUSSION -- 6. ACKNOWLEDGEMENTS -- 7. REFERENCES -- Chapter 12. Adsorbate-induced restructuring of f.c.c. {100} surfaces -- 1. INTRODUCTION -- 2. ADSORBATE-INDUCED DISTORTIONS IN 'SIMPLE' ADSORPTION STRUCTURES -- 3. ADSORBATE-INDUCED PARALLEL DISTORTIONS -- p4g SPACE GROUP 'CLOCK' RECONSTRUCTIONS -- 4. LARGE MASS TRANSPORT RECONSTRUCTIONS -- MISSING ROWS -- 5. WIDER STABILITY OF SOME {100} ADSORPTION STRUCTURES? -- References -- Chapter 13. Adsorbate Induced Reconstruction of f.c.c.{110} Surfaces.
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1. INTRODUCTION -- 2. ALKALI METAL INDUCED SURFACE RECONSTRUCTION -- 3. HYDROGEN INDUCED SURFACE RECONSTRUCTIONS -- 4. SURFACE RECONSTRUCTION INDUCED BY OXYGEN, NITROGEN, CARBON AND SULPHUR -- 5. MOLECULARLY-INDUCED RECONSTRUCTION -- 6. CONCLUSIONS -- ACKNOWLEDGEMENTS -- REFERENCES -- Chapter 14. Microscopic Studies of Adsorbate Restructuring at Metal Surfaces -- 1. INTRODUCTION -- 2. STM IMAGING -- 3. ADSORBATE-MEDIATED RECONSTRUCTIVE TRANSFORMATIONS -- 4. GENERAL TRENDS -- 5. SUMMARY -- 6. ACKNOWLEDGMENTS -- REFERENCES -- Index.
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