Note: Organometallic Chemistry -- Contents -- CHAPTER 1 Group I: The Alkali and Coinage Metals -- 1 Alkali Metals -- 1.1 General -- 1.2 Alkyl Compounds -- 1.3 Alkenyl Compounds -- 1.4 Allylic Compounds -- 1.5 Allenyl / Propargylic Compounds -- 1.6 Alkynyl Compounds -- 1.7 Cyclopentadienyl Compounds -- 1.8 Benzyl Compounds -- 1.9 Aryl Compounds -- 2 Copper, Silver and Gold -- 2.1 π-Complexes -- 2.2 σ-Bonded Copper Compounds -- 2.3 σ-Bonded Silver and Gold Compounds -- References -- CHAPTER 2 Group II: The Alkaline Earths and Zinc and its Congeners -- 1 Beryllium -- 2 Magnesium -- 3 Calcium, Strontium and Barium -- 4 Zinc -- 5 Cadmium -- 6 Mercury -- References -- CHAPTER 3 Carbaboranes, Including their Metal Complexes -- 1 Introduction -- 2 Theoretical and Spectroscopic Studies -- 3 Rings and Ring Stacking -- 4 Composition CB4 and C2B3 (Excluding Rings) -- 5 Composition C2B4 -- 6 Composition C5B6 -- 7 Composition CB7 -- 8 Composition C3B7 and C3B8 -- 9 Composition C2B9 -- 10 Composition CB10 and CB11 -- 11 Composition C2B10 -- 12 Studies Relating to BNCT -- References -- CHAPTER 4 Group III: Boron, Aluminium, Gallium, Indium, and Thallium -- 1 Boron -- 1.1 General -- 1.2 Compounds Containing Nitrogen -- 1.3 Compounds Containing Oxygen or Sulfur -- 1.4 Metal-Containing Compounds -- 2 Aluminium -- 2.1 General -- 2.2 Compounds Containing a Group 15 Element -- 2.3 Compounds Containing a Group 16 Element -- 2.4 Compounds Containing Other Metals alongside Aluminium -- 3 Gallium -- 3.1 General -- 3.2 Compounds Containing a Group 15 Element -- 3.3 Compounds Containing a Group 16 Element -- 3.4 Compounds Containing Other Metals alongside Gallium -- 4 Indium -- 5 Thallium -- References -- CHAPTER 5 Group IV: The Silicon Group -- 1 Introduction -- 2 The Carbon-Metalloid Bond -- 3 Catenation -- 4 Hydrides -- 5 Radicals, Anions, and Metal Derivatives. , 6 Nitrogen Derivatives -- 7 Phosphorus, Arsenic and Antimony Derivatives -- 8 Oxygen Derivatives -- 9 Sulphur, Selenium, and Tellurium Derivatives -- 10 Halogen Derivatives -- 11 Complexes -- 12 Medical and Environmental Studies -- References -- CHAPTER 6 Group V: Arsenic, Antimony, and Bismuth -- 1 Arene Complexes -- 2 Tervalent Compounds -- 3 Quinquevalent Compounds -- References -- CHAPTER 7 Metal Carbonyls -- 1 Introduction -- 2 Reviews -- 3 Theoretical, Spectroscopic, and General Studies -- 3.1 Theoretical Studies -- 3.2 Spectroscopic Studies -- 3.3 General -- 4 Chemistry of Metal Carbonyls -- 4.1 Titanium, Zirconium, and Hafnium -- 4.2 Vanadium, Niobium, and Tantalum -- 4.3 Chromium, Molybdenum, and Tungsten -- 4.4 Manganese, Technetium, and Rhenium -- 4.5 Iron, Ruthenium, and Osmium -- 4.6 Cobalt, Rhodium, and Iridium -- 4.7 Nickel, Palladium, and Platinum -- 4.8 Copper, Silver, and Gold -- 4.9 Mixed Metal Carbonyls -- 5 Metal Carbonyls as Catalysts -- 6 Analysis of Literature Sources -- References -- CHAPTER 8 Organometallic Cluster Complexes of the Transition Metals -- 1 Introduction, Reviews and General Studies -- 1.1 Reviews -- 1.2 Theoretical Studies -- 1.3 Structural Studies -- 1.4 Spectroscopic Studies -- 2 Homometallic Clusters -- 2.1 Groups 3, 4 and 5 -- 2.2 Chromium, Molybdenum and Tungsten -- 2.3 Manganese and Rhenium -- 2.4 Iron -- 2.5 Ruthenium -- 2.5.1 Polynuclear Carbonyls -- 2.5.2 Carbon Ligands -- 2.5.3 Alkynes -- 2.5.4 Cyclic Hydrocarbons -- 2.5.5 Arenes -- 2.5.6 Group 15 Ligands -- 2.5.7 Group 16 Ligands -- 2.5.8 Carbonyl-free Cyclopentadienyl Clusters -- 2.6 Osmium -- 2.6.1 Carbonyls -- 2.6.2 Carbon Ligands -- 2.6.3 Alkenes and Alkynes -- 2.6.4 Cyclic Hydrocarbons and Akenes -- 2.6.5 Group 15 Ligands -- 2.6.6 Group 16 Ligands -- 2.6.7 Polynuclear Carbonyls -- 2.6.8 Group 14 Ligands. , 2.7 Heterometallic Clusters of the Iron Sub-group -- 2.8 Group 8 Clusters in Synthesis and Catalysis -- 2.9 Cobalt -- 2.9.1 Carbonyls -- 2.9.2 Co3(μ3-CR)(CO)3 -- 2.9.3 Co3Cp3 Clusters -- 2.10 Rhodium and Iridium -- 2.11 Nickel -- 2.12 Palladium and Platinum -- 2.13 Copper, Silver and Gold -- 3 Heterometallic Clusters -- 3.1 Cr, W-Re -- 3.2 Mo-Fe -- 3.3 Mo, W-Ru, Os -- 3.4 Mo, W-Co -- 3.5 Mn, Re-Fe -- 3.6 Mn, Re-Rh -- 3.7 Re-Pd, Pt -- 3.8 Fe-Co, Rh -- 3.9 Ru, Os-Co, Rh -- 3.10 Ru-Ni, Pt -- 3.11 Os-Pd, Pt -- 4 Heterometallic Clusters Containing Group 11 Metals -- 5 Complexes Containing Three Different Metals -- References -- CHAPTER 9 Complexes Containing Metal-Carbon σ-Bonds ofthe Groups Scandium to Manganese, Including Carbenes and Carbynes -- 1 Reviews and General Material -- 2 Group 3 -- 3 Group 4 -- 4 Group 5 -- 5 Group 6 -- 6 Group 7 -- References -- CHAPTER 10 Complexes Containing Metal-Carbon σ-Bonds of the Groups Iron, Cobalt, and Nickel, Including Carbenes and Carbynes -- 1 Introduction, Reviews and Articles of General Interest -- 2 Metal-Carbon σ-Bonds Involving Group 8, 9, and 10 Metals -- 2.1 The Iron Triad -- 2.2 The Cobalt Triad -- 2.3 The Nickel Triad -- 3 Carbene and Carbyne Complexes of Groups 8, 9, and 10 Metals -- References -- CHAPTER 11 Hydrocarbon-Metal π-Complexes, Other than π-Cyclopentadienyl and π-Arene Complexes -- 1 Reviews -- 2 Allyl Complexes and Complexes Derived from Monoalkenes -- 2.1 Cr, Mo and W -- 2.2 Fe, Ru and Os -- 2.3 Co, Rh and Ir -- 2.4 Ni, Pd and Pt -- 2.5 Other Metals -- 3 Complexes Derived from Unconjugated Dienes -- 3.1 Cr, Mo and W -- Fe, Ru and Os -- 3.2 Co, Rh and Ir -- 3.3 Ni, Pd and Pt -- 4 Complexes Derived from Conjugated Dienes -- 4.1 Cr, Mo and W -- 4.2 Fe, Ru and Os -- 4.2.1 Acyclic Dienes -- 4.2.2 Cyclic Dienes -- 4.3 Co, Rh, and Ir -- 4.4 Other Metals -- 5 Alkyne Complexes. , 6 Bimetallic Complexes -- References -- CHAPTER 12 π-Cyclopentadienyl, π-Arene and Related Complexes -- 1 Introduction -- 2 Monocyclopentadienyls -- 2.1 Main Group, Lanthanide and Actinides -- 2.2 Titanium, Zirconium and Hafnium -- 2.3 Vanadium, Niobium and Tantalum -- 2.4 Chromium, Molybdenum and Tungsten -- 2.5 Manganese, Rhenium and Technetium -- 2.6 Iron, Ruthenium and Osmium -- 2.7 Cobalt, Rhodium and Iridium -- 2.8 Nickel, Palladium and Platinum -- 3 Bis-cyclopentadienyl Derivatives -- 3.1 Main Group and Lanthanides and Actinides -- 3.2 Titanium, Zirconium and Hafnium -- 3.3 Vanadium, Niobium and Tantalum -- 3.4 Chromium, Molybdenum and Tungsten -- 3.5 Iron, Ruthenium and Osmium -- 3.6 Cobalt, Rhodium and Iridium -- 3.7 Nickel -- 4 Arenes -- 4.1 Chromium -- 4.2 Manganese -- 4.3 Iron, Ruthenium and Osmium -- 4.4 Other Arenes -- References.

Note: Organometallic Chemistry -- Contents -- Chapter 1 Group 1: The Alkali and Coinage Metals -- 1 Alkali Metals -- 1.1 Introduction: Organisation and Major Advances -- 1.2 Alkyl Derivatives -- 1.3 Alkenyl, Allyl, Vinyl, Alkynyl and Related Derivatives -- 1.4 Aryl Derivatives -- 1.5 Cyclopentadienyl and Related Derivatives -- 2 Copper, Silver and Gold -- 2.1 Introduction: Organisation and Major Advances -- 2.2 Copper Compounds -- 2.3 Silver Compounds -- 2.4 Gold Compounds -- References -- Chapter 2 Group 2 (Be-Ba) and Group 12 (Zn-Hg) -- 1 Introduction -- 2 Synthetic and Structural Studies -- 2.1 Group 2 -- 2.2 Group 12 -- 2.3 Group 2 and Group 12 Organometallics Containing Borane and Carborane Ligands -- References -- Chapter 3 Scandium, Yttrium and the Lanthanides -- 1 Introduction -- 2 Theoretical and Spectroscopic Studies -- 3 Gas Phase Chemistry -- 4 New Compounds -- 4.1 Cp3Ln Compounds -- 4.2 Cp2LnX Compounds -- 4.3 CpLnX2 Compounds -- 4.4 Pentamethylcyclopentadienyl Chemistry -- 4.5 Substituted Cp Ligands -- 4.6 Metal Amides and Derivatives as Ancillary Ligands -- 4.7 Other Organometallics -- 5 Catalysis -- 5.1 Hydrogenation, Hydrosilylation and Cyclization -- 5.2 Olefin Polymerization -- 6 Lanthanides in Organic Synthesis -- 7 Endohedral Fullerenes (EF) -- References -- Chapter 4 Carbaboranes, Including Their Metal Complexes -- 1 Introduction -- 2 Theoretical and Spectroscopic Studies -- 3 Rings and Ring Stacking -- 4 Composition C4Bx, and C3Bx, -- 5 Composition C2B4 -- 6 Composition C2B6 and C2B7 -- 7 Composition CB8 and C2B8 -- 8 Composition CB9 and C2B9 -- 9 Composition CB10 and CB11 -- 10 Composition C2B10 -- 11 Macropolyhedral Species -- 12 Studies Relating Specifically to BNCT and Other Medical Applications -- References -- Chapter 5 Group 13: Boron, Aluminium, Gallium, Indium and Thallium -- 1 Boron -- 1.1 General. , 1.2 Compounds Containing Nitrogen, Phosphorus, Oxygen or Sulfur -- 1.3 Metal-containing Compounds -- 2 Aluminium -- 2.1 General -- 2.2 Compounds Containing a Group 15 Element -- 2.3 Compounds Containing a Group 16 Element -- 2.4 Compounds Containing a Metal other than Aluminium -- 3 Gallium -- 3.1 General -- 3.2 Compounds Containing a Group 15 Element -- 3.3 Compounds Containing a Group 16 Element -- 3.4 Compounds Containing a Metal other than Gallium -- 4 Indium -- 5 Thallium -- References -- Chapter 6 Group 14 Silicon, Germanium, Tin and Lead -- 1 Introduction -- 2 The Carbon-Metalloid Bond -- 3 Catenation -- 4 Hydrides -- 5 Radicals, Ions and Metal Derivatives -- 6 Nitrogen Derivatives -- 7 Phosphorus, Arsenic, Antimony and Bismuth Derivatives -- 8 Oxygen Derivatives -- 9 Sulfur, Selenium and Tellurium Derivatives -- 10 Halogen Derivatives -- 11 Organotin-Oxygen Compounds and Complexes -- References -- Chapter 7 Organometallic Chemistry of Group 15 Elements -- 1 Phosphorus -- 2 Arsenic, Antimony and Bismuth -- References -- Chapter 8 Organic Aspects of Organometallic Chemistry -- 1 Introduction -- 2 Coupling Reactions -- 2.1 Catalysed Carbon-Heteroatom Bond Formation -- 2.2 Cross-coupling Reactions -- 2.3 Allylic Substitution Reactions -- 2.4 Heck Cyclisations and Related Reactions -- 2.5 Cyclisation Reactions Involving Alkynes -- 2.6 Benzannulation Reactions -- 3 Carbonylation Reactions -- 3.1 Pauson-Khand Cyclisation -- 4 Organometallic Methods of C-C Bond Formation -- 4.1 Transition Metal Templates -- 4.2 Alkene Metathesis -- 4.3 [4+2]-Cycloaddition -- 5 Emerging Areas of Organometallic-dependent Organic Synthesis -- 5.1 Catalytic Asymmetric Aminohydroxylation -- 5.2 Asymmetric Reduction of Ketones -- 5.3 Reactions Catalysed by Scandium Triflate -- 5.4 Organometallic Nucleophilic Catalysts -- 5.5 Dynamic Resolution Reactions. , 5.6 Combinatorial Synthesis -- 5.7 Combinatorial Catalysis -- References -- Chapter 9 Metal Carbonyls -- 1 Introduction -- 2 Reviews -- 3 Theoretical, Spectroscopic and General Studies -- 3.1 Theoretical Studies -- 3.2 Spectroscopic Studies -- 3.3 General -- 4 Chemistry of the Metal Carbonyls -- 4.1 Titanium, Zirconium and Hafnium -- 4.2 Vanadium, Niobium and Tantalum -- 4.3 Chromium, Molybdenum and Tungsten -- 4.4 Manganese, Technetium and Rhenium -- 4.5 Iron, Ruthenium and Osmium -- 4.6 Cobalt, Rhodium and Iridium -- 4.7 Nickel, Palladium and Platinum -- 4.8 Copper, Silver and Gold -- 4.9 Mixed Metal Carbonyls -- References -- Chapter 10 Organo-Transition Metal Cluster Compounds -- 1 Introduction -- 2 General Reviews -- 3 Spectroscopic Studies -- 3.1 Nuclear Magnetic Resonance -- 3.2 Mass Spectrometry -- 4 Structural Studies -- 5 Theoretical Studies -- 6 Group 4 -- 7 Group 5 -- 8 Group 6 -- 9 Group 7 -- 10 Group 8 -- 10.1 The M3(CO)12 Problem -- 10.2 Iron -- 10.3 Ruthenium -- 10.3.1 Ru3 and Ru4 Clusters -- 10.3.2 Complexes of Higher Nuclearity -- 10.3.3 Synthesis of Lower Nuclearity Species -- 10.4 Osmium -- 11 Group 9 -- 11.1 Cobalt -- 11.2 Rhodium -- 11.3 Iridium -- 12 Group 10 -- 12.1 Nickel -- 12.2 Palladium -- 12.3 Platinum -- 13 Group 11 -- 14 Heterometallic Clusters -- 14.1 Zr-Fe, Ru, Co -- 14.2 Ti-Rh -- 14.3 Mo, W-Re -- 14.4 Cr, Mo, W-Fe -- 14.5 Mo-Ru -- 14.6 W-Ru -- 14.7 W-Os -- 14.8 Cr-Rh -- 14.9 Mo-Co -- 14.10 W-Ir -- 14.11 Mo, W-Ni -- 14.12 Mn, Re-Fe -- 14.13 Mn, Re-Ru -- 14.14 Re-Rh -- 14.15 Re-Pt -- 14.16 Fe-Ru -- 14.17 Fe-Co -- 14.18 Ru-Co -- 14.19 Ru-Rh, Ir -- 14.20 Fe-Pt -- 14.21 Os-Pd, Pt -- 14.22 Co-Pd -- 14.23 Rh, Ir-Pt -- 14.24 Ni-Pd -- 15 Heterometallic Clusters Containing Group 11 Metals -- 15.1 Nb, Ta -- 15.2 Mo, W -- 15.3 Mn, Re -- 15.4 Fe, Ru, Os -- 15.5 Co, Rh, Ir -- 15.6 Pt -- 16 Clusters Containing Group 12 Metals. , 17 Clusters Containing Three Different Metal Atoms -- 18 Metal Cluster Complexes in Catalysis -- References -- Chapter 11 Complexes Containing Metal-Carbon σ-Bonds of the Groups Titanium to Manganese, Including Carbenes and Carbynes -- Part I: Group 4 -- References -- Part II: Group 5 -- 1 Reviews -- 2 Alkyl Complexes -- 3 Alkyne Complexes -- 4 Alkylidene Complexes -- 5 Aryl Oxides and Other Oxygen Containing Complexes -- 6 Nitrogen Containing Complexes -- 7 Other Complexes -- References -- Part III: Group 6 -- References -- Part IV: Group 7 -- References -- Chapter 12 Complexes Containing Metal-Carbon σ-Bonds of the Groups Iron, Cobalt and Nickel, Including Carbenes and Carbynes -- 1 Introduction, Reviews and Articles of General Interest -- 2 Metal-Carbon σ-Bonds Involving Group 8, 9 or 10 Metals -- 2.1 The Iron Triad -- 2.2 The Cobalt Triad -- 2.3 The Nickel Triad -- 3 Carbene and Carbyne Compounds of Groups 8, 9 and 10 -- References -- Chapter 13 Hydrocarbon Transition Metal π-Complexes Other Than η-C5H5 and η-Arene Complexes -- 1 Introduction -- 2 Reviews -- 3 Allyl Complexes and Complexes Derived from Monoalkenes -- 3.1 Cr, Mo and W -- 3.2 Fe, Ru and Os -- 3.3 Co, Rh and Ir -- 3.4 Ni, Pd and Pt -- 3.5 Other Metals -- 4 Complexes Derived from Unconjugated Alkenes -- 5 Complexes Derived from Cyclic Conjugated Alkenes -- 5.1 Cr, Mo and W -- 5.2 Fe, Ru and Os -- 5.3 Other Metals -- 6 Complexes Containing Acyclic Alkenes -- 7 Alkyne Complexes -- 8 Polymetallic Complexes -- 8.1 Bimetallic Complexes -- 8.2 Multimetallic Complexes -- 8.3 Ferrocenyl Containing Complexes -- References -- Chapter 14 η-C5H5 and η-Arene Substituted Transition Metal Complexes -- 1 Introduction -- 1.1 General and Main Group -- 2 Monocyclopentadienyls -- 2.1 Lanthanides and Actinides -- 2.2 Titanium, Zirconium and Hafnium -- 2.3 Vanadium, Niobium and Tantalum. , 2.4 Chromium, Molybdenum and Tungsten -- 2.5 Manganese, Rhenium and Technetium -- 2.6 Iron, Ruthenium and Osmium -- 2.6.1 General -- 2.6.2 Synthesis -- 2.6.3 Reactions -- 2.6.4 General, Chirality Catalysis -- 2.7 Cobalt, Rhodium and Iridium -- 2.8 Nickel, Palladium and Platinum -- 3 Bis-Cyclopentadienyls -- 3.1 Main Group, Lanthanides and Actinides -- 3.2 Titanium, Zirconium and Hafnium -- 3.2.1 General Synthesis -- 3.2.2 Ansa and Chiral Metallocenes -- 3.2.3 Polymerisation -- 3.3 Vanadium, Niobium and Tantalum -- 3.4 Chroniun, Molybdenum and Tungsten -- 3.5 Iron, Ruthenium and Osmium -- 3.5.1 Electrochemistry/Redox Processes -- 3.5.2 Complexes -- 3.5.3 Chiral -- 3.5.4 Biferrocenes - Electron Transfer -- 3.5.5 Ligands -- 3.5.6 Ring Opening -- 3.6 Cobalt, Rhodium and Iridium -- 3.7 Nickel, Palladium and Platinum -- 4 Bis-Arenes -- 4.1 Chromium -- 4.2 Manganese -- 4.3 Iron -- 4.4 General Arenes -- References -- Author Index.

Note: Organometallic Chemistry -- Contents -- CHAPTER 1 Group I: The Alkali and Coinage Metals -- 1 Alkali Metals -- 1.1 General -- 1.2 Alkyl Derivatives -- 1.3 Aryl Derivatives -- 1.4 Cyclopentadienyl and Related Derivatives -- 1.5 Benzyl and Related Derivatives -- 1.6 Alkenyl and Related Derivatives -- 2 Copper, Silver and Gold -- 2.1 π-Complexes of Copper, Silver and Gold -- 2.2 σ-Compounds of Copper -- 2.3 σ-Bonded Compounds of Silver and Gold -- References -- CHAPTER 2 Group II: The Alkaline Earths and Zinc and its Congeners -- 1 General -- 2 Beryllium -- 3 Magnesium -- 4 Calcium, Strontium and Barium -- 5 Zinc -- 6 Cadmium -- 7 Mercury -- References -- CHAPTER 3 Carbaboranes, Including their Metal Complexes -- 1 Introduction -- 2 Theoretical and Spectroscopic Studies -- 3 Composition C4B, C4B2, C3B2 and C2B3 (including ring stacking) -- 4 Composition CB4 -- 5 Composition C2B4 -- 6 Composition C2B5, and C3B5 -- 7 Composition CB6, CB7 and CB8 -- 8 Composition C2B6 and C2B7 -- 9 Composition C2B8 -- 10 Composition CB9 and CB11 -- 11 Composition C2B9 -- 12 Composition C2B10 -- 13 Studies Relating to BNCT -- References -- CHAPTER 4 Group III: Boron, Aluminium, Gallium, Indium, and Thallium -- 1 Boron -- 1.1 Non-cyclic Compounds -- 1.2 Ring and Cage Structures -- 2 Aluminium, Gallium, and Indium -- 2.1 Simple Organometallics and Organometallic Halides -- 2.2 Compounds Containing M-Group 15 Element Bonds -- 2.3 Compounds Containing M-Group 16 Element Bonds -- 2.4 Derivatives Containing Transition Metals -- 2.5 Material Science -- 3 Thallium -- 3.1 Thallium(III) -- 3.2 Thallium(I) -- References -- CHAPTER 5 Group IV: The Silicon Group -- 1 Introduction -- 2 The Carbon-Metalloid Bond -- 3 Catenation -- 4 Hydrides -- 5 Radicals, Anions, and Metal Derivatives -- 6 Nitrogen Derivatives -- 7 Phosphorus and Arsenic Derivatives -- 8 Oxygen Derivatives. , 9 Sulphur, Selenium, and Tellurium Derivatives -- 10 Halogen Derivatives -- 11 Complexes -- References -- CHAPTER 6 Group V: Arsenic, Antimony, and Bismuth -- 1 Tervalent Compounds -- 2 Quinquevalent Species -- References -- CHAPTER 7 Metal Carbonyls -- 1 Introduction -- 2 Reviews -- 3 Theoretical, Spectroscopic, and General Studies -- 3.1 Theoretical Studies -- 3.2 Spectroscopic Studies -- 3.3 General -- 4 Chemistry of Metal Carbonyls -- 4.1 Titanium, Zirconium, and Hafnium -- 4.2 Vanadium, Niobium, and Tantalum -- 4.3 Chromium, Molybdenum, and Tungsten -- 4.4 Manganese, Technetium, and Rhenium -- 4.5 Iron, Ruthenium, and Osmium -- 4.6 Cobalt, Rhodium, and Iridium -- 4.7 Nickel, Palladium, and Platinum -- 4.8 Copper, Silver, and Gold -- 4.9 Mixed Metal Carbonyls -- 5 Metal Carbonyls as Catalysts -- 6 Analysis of Literature Sources -- References -- CHAPTER 8 Organometallic Compounds Containing Metal-Metal Bonds -- 1 Introduction -- 1.1 Reviews -- 1.2 Theoretical Studies -- 1.3 Physical Studies -- 2 Compounds with Homonuclear Transition Metal Bonds -- 2.1 Group 4 -- 2.2 Group 5 -- 2.3 Group 6 -- 2.4 Group 7 -- 2.5 Iron -- 2.6 Ruthenium -- 2.7 Osmium -- 2.8 Cobalt -- 2.9 Rhodium and Iridium -- 2.10 Group 10 -- 2.11 Group 11 -- 3 Compounds with Heteronuclear Transition Metal Bonds -- 3.1 Binuclear Complexes -- 3.2 Tri and Higher Nuclearity Complexes -- 4 Compounds with Bonds Between Transition and Main Group Metals -- 4.1 Group 12 -- 4.2 Group 13 -- 4.3 Group 14 -- 4.4 Group 15 -- References -- CHAPTER 9 Complexes Containing Metal-Carbon σ-Bonds of the Groups Scandium to Manganese, Including Carbenes and Carbynes -- 1 Reviews and General Material -- 2 Group 3 -- 3 Group 4 -- 4 Group 5 -- 5 Group 6 -- 6 Group 7 -- References -- CHAPTER 10 Complexes Containing Metal-Carbon σ-Bonds of the Groups Iron, Cobalt, and Nickel, Including Carbenes and Carbynes. , 1 Introduction, Reviews and Articles of General Interest -- 2 Metal-Carbon σ-Bonds Involving Group 8, 9, and 10 Metals -- 2.1 The Iron Triad -- 2.2 The Cobalt Triad -- 2.3 The Nickel Triad -- 3 Carbene and Carbyne Complexes of Groups 8, 9, and 10 Metals -- References -- CHAPTER 11 Hydrocarbon-Metal π-Complexes, Other than π-Cyclopentadienyl and π-Arene Complexes -- 1 Reviews -- 2 Allyl Complexes and Complexes Derived from Monoalkenes -- 2.1 Cr, Mo, and W -- 2.2 Fe, Ru, and Os -- 2.3 Co, Rh, and Ir -- 2.4 Ni, Pd, and Pt -- 2.5 Other Metals -- 3 Complexes Derived from Unconjugated Dienes -- 3.1 Cr, Mo, and W -- Fe, Ru, and Os -- 3.2 Co, Rh, and Ir -- 3.3 Ni, Pd, and Pt -- 4 Complexes Derived from Conjugated Dienes -- 4.1 Cr, Mo, and W -- 4.2 Fe, Ru, and Os -- 4.2.1 Acyclic Dienes -- 4.2.2 Cyclic Dienes -- 4.3 Co, Rh, and Ir -- 4.4 Other Metals -- 5 Alkyne Complexes -- 6 Polynuclear Complexes -- 6.1 Bimetallic Complexes -- 6.2 Polymetallic Complexes -- References -- CHAPTER 12 π-Cyclopentadienyl, π-Arene and Related Complexes -- 1 Introduction -- 2 Monocyclopentadienyls -- 2.1 Main Group, Lanthanide and Actinides -- 2.2 Titanium, Zirconium, and Hafnium -- 2.3 Vanadium, Niobium, and Tantalum -- 2.4 Chromium, Molybdenum, and Tungsten -- 2.5 Manganese, Rhenium, and Technetium -- 2.6 Iron, Ruthenium, and Osmium -- 2.7 Cobalt, Rhodium, and Iridium -- 2.8 Nickel, Palladium, and Platinum -- 2.9 Copper -- 3 Bis-cyclopentadienyl Derivatives -- 3.1 Lanthanides and Actinides -- 3.2 Titanium, Zirconium, and Hafnium -- 3.3 Vanadium, Niobium, and Tantalum -- 3.4 Chromium, Molybdenum, and Tungsten -- 3.5 Iron, Ruthenium, and Osmium -- 3.6 Cobalt, Rhodium, and Iridium -- 3.7 Nickel -- 4 Arenes -- 4.1 Chromium -- 4.2 Manganese -- 4.3 Iron, Ruthenium, and Osmium -- 4.4 Other Arenes -- References.

Note: Organometallic Chemistry -- Contents -- CHAPTER 1 Group I: The Alkali and Coinage Metals -- 1 Alkali Metals -- 1.1 General -- 1.2 Alkyl Species -- 1.3 Benzyl Species -- 1.4 Aryl Derivatives -- 2 Copper -- 2.1 General -- 2.2 π-Complexes -- 2.3 σ-Bonded Compounds -- 3 Silver -- 4 Gold -- References -- CHAPTER 2 Group II: The Alkaline Earths and Zinc and its Congeners -- 1 Beryllium -- 2 Magnesium -- 3 Calcium, Strontium and Barium -- 4 Zinc -- 5 Cadmium -- 6 Mercury -- References -- CHAPTER 3 Carbaboranes, Including their Metal Complexes -- 1 Introduction -- 2 Theoretical and Spectroscopic Studies -- 3 Rings with Composition C5B, C3B2 and C2B3-Ring Stacking -- 4 Composition C2B4 -- 5 Composition C2B5 -- 6 Composition C3B4, C3B6 and C3B7 -- 7 Composition C2B6 -- 8 Composition C4B6 -- 9 Composition CB8 and C2B8 -- 10 Composition C4B8 -- 11 Composition CB4 -- 12 Composition C2B9 -- 13 Composition CBI0 -- 14 Composition C2B10 -- 15 Composition CB11 -- 16 Compounds with Potential Uses in BNCT -- References -- CHAPTER 4 Group III: Boron, Aluminium, Gallium, Indium, and Thallium -- 1 Boron -- 1.1 Non-cyclic Compounds -- 1.2 Ring and Cage Structures -- 2 Aluminium, Gallium, and Indium -- 2.1 Simple Organometallics and Organometallic Halides -- 2.2 Compounds Containing M-Group 15 Element Bonds -- 2.3 Compounds Containing M-Group 16 Element Bonds -- 2.4 Derivatives Containing Transition Metals -- 2.5 Material Science -- 3 Thallium -- 3.1 Thallium(III) -- 3.2 Thallium(I) -- References -- CHAPTER 5 Group IV: The Silicon Group -- 1 Introduction -- 2 The Carbon-Metalloid Bond -- 3 Catenation -- 4 Hydrides -- 5 Radicals, Anions, and Metal Derivatives -- 6 Nitrogen Derivatives -- 7 Phosphorus, Arsenic, and Antimony Derivatives -- 8 Oxygen Derivatives -- 9 Sulphur, Selenium, and Tellurium Derivatives -- 10 Halogen Derivatives. , 11 Complexes and Environmental Activity -- References -- CHAPTER 6 Group V: Arsenic, Antimony, and Bismuth -- 1 Tervalent Compounds -- 2 Pentavalent Species -- References -- CHAPTER 7 Metal Carbonyls -- 1 Introduction -- 2 Reviews -- 3 Theoretical, Spectroscopic, and General Studies -- 3.1 Theoretical Studies -- 3.2 Spectroscopic Studies -- 3.3 General -- 4 Chemistry of Metal Carbonyls -- 4.1 Titanium, Zirconium, and Hafnium -- 4.2 Vanadium, Niobium, and Tantalum -- 4.3 Chromium, Molybdenum, and Tungsten -- 4.4 Manganese, Technetium, and Rhenium -- 4.5 Iron, Ruthenium, and Osmium -- 4.6 Cobalt, Rhodium, and Iridium -- 4.7 Nickel, Palladium, and Platinum -- 4.8 Copper, Silver, and Gold -- 4.9 Mixed Metal Carbonyls -- 5 Metal Carbonyls as Catalysts -- 6 Analysis of Literature Sources -- References -- CHAPTER 8 Organometallic Compounds Containing Metal-Metal Bonds -- 1 Introduction -- 1.1 Reviews -- 1.2 Theoretical Studies -- 1.3 Physical Studies -- 2 Compounds with Homonuclear Transition Metal Bonds -- 2.1 Group 4 -- 2.2 Group 5 -- 2.3 Group 6 -- 2.4 Group 7 -- 2.5 Iron -- 2.6 Ruthenium and Osmium -- 2.7 Cobalt -- 2.8 Rhodium and Iridium -- 2.9 Nickel -- 2.10 Palladium and Platinum -- 2.11 Group 11 -- 3 Compounds with Heteronuclear Transition Metal Bonds -- 3.1 Binuclear Complexes -- 3.2 Tri and Higher Nuclearity Complexes -- 4 Compounds with Bonds Between Transition and Main Group Metals -- 4.1 Group 12 -- 4.2 Group 13 -- 4.3 Group 14 -- 4.4 Group 15 -- References -- CHAPTER 9 Complexes Containing Metal-Carbon σ-Bonds of the Groups Scandium to Manganese, Including Carbenes and Carbynes -- 1 Reviews and General Material -- 2 Group 3 -- 3 Group 4 -- 4 Group 5 -- 5 Group 6 -- 6 Group 7 -- References -- CHAPTER 10 Complexes Containing Metal-Carbon σ-Bonds of the Groups Iron, Cobalt, and Nickel, Including Carbenes and Carbynes. , 1 Introduction, Reviews and Articles of General Interest -- 2 Metal-Carbon σ-Bonds Involving Group 8, 9, and 10 Metals -- 2.1 The Iron Triad -- 2.2 The Cobalt Triad -- 2.3 The Nickel Triad -- 3 Carbene and Carbyne Complexes of Groups 8, 9, and 10 Metals -- References -- CHAPTER 11 Hydrocarbon-Metal π-Complexes, Other than π-Cyclopentadienyl and π-Arene Complexes -- 1 Reviews -- 2 Allyl Complexes and Complexes Derived from Monoalkenes -- 2.1 Cr, Mo, andW -- 2.2 Fe, Ru, and Os -- 2.3 Co, Rh, and Ir -- 2.4 Ni, Pd, and Pt -- 2.5 Other Metals -- 3 Complexes Derived from Unconjugated Dienes -- 3.1 Cr, Mo, and W -- Fe, Ru, and Os -- 3.2 Co, Rh, and Ir -- 3.3 Ni, Pd, and Pt -- 4 Complexes Derived from Conjugated Dienes -- 4.1 Cr, Mo, and W -- 4.2 Fe, Ru, and Os -- 4.2.1 Acyclic Dienes -- 4.2.2 Cyclic Dienes -- 4.3 Co, Rh, and Ir -- 4.4 Other Metals -- 5 Alkyne Complexes -- 6 Polynuclear Complexes -- 6.1 Bimetallic Complexes -- 6.2 Polymetallic Complexes -- References -- CHAPTER 12 π-Cyclopentadienyl, π-Arene and Related Complexes -- 1 Introduction -- 2 Monocyclopentadienyls -- 2.1 Main Group, Lanthanide and Actinides -- 2.2 Titanium, Zirconium, and Hafnium -- 2.3 Vanadium, Niobium, and Tantalum -- 2.4 Chromium, Molybdenum, and Tungsten -- 2.5 Manganese, Rhenium, and Technetium -- 2.6 Iron, Ruthenium, and Osmium -- 2.7 Cobalt, Rhodium, and Iridium -- 2.8 Nickel, Palladium, and Platinum -- 3 Bis-cyclopentadienyl Derivatives -- 3.1 Lanthanides and Actinides -- 3.2 Titanium, Zirconium, and Hafnium -- 3.3 Vanadium, Niobium, and Tantalum -- 3.4 Chromium, Molybdenum, and Tungsten -- 3.5 Iron, Ruthenium, and Osmium -- 3.6 Cobalt, Rhodium, and Iridium -- 4 Arenes -- 4.1 Chromium -- 4.2 Manganese -- 4.3 Ruthenium -- 4.4 Other Arenes -- References.