Note: Intro -- Title Page -- Copyright Page -- Contents -- Preface -- Contributors -- 1 An Overview -- I. Some Philosophy -- II. Progress and Prognosis -- III. So Much Nomenclature, So Much Jargon -- Bibliography -- 2 Fundamental Concepts of Analytical Electrochemistry -- I. Introduction -- II. Mass Transport: Linear Diffusion -- III. The Charged Interphase -- IV. The Nernst Equation and Electrochemical Reversibility -- V. Coupled Chemical Reactions and Chemical Reversibility -- VI. Liquid-Solid Adsorption -- VII. Conclusion -- References -- 3 Large-Amplitude Controlled-Potential Techniques -- I. Introduction -- II. Potential-Step Techniques in Stationary Solution -- III. Potential-Scan Techniques in Stationary Solution -- IV. Controlled-Potential Techniques in Flowing Solution 110 -- References -- 4 Large-Amplitude Controlled-Current Techniques -- I. Controlled-Current Techniques in Stationary Solution -- II. Controlled-Current Techniques in Flowing Solution -- References -- 5 Small-Amplitude Controlled-Potential Techniques -- I. Introduction -- II. Faradaic Impedance -- III. Sinusoidal Alternating-Current Voltammetry -- IV. Cyclic Alternating-Current Voltammetry -- V. Tensammetry -- VI. Step-Based Methods -- VII. Staircase Voltammetry -- VIII. Differential Pulse Methods -- IX. Square-Wave Methods -- X. Differential "Normal Pulse" Voltammetry -- XI. Conclusion -- References -- 6 Introduction to Analog Instrumentation -- I. Classical Controlled-Potential Instrumentation -- II. Controlled-Potential Instrumentation Based on Operational Amplifiers -- III. Classical Controlled-Current Instrumentation -- IV. Controlled-Current Instrumentation Based on Operational Amplifiers -- V. Microprocessor-Based Electrochemical Instrumentation -- VI. Conclusion -- Reference -- 7 Overcoming Solution Resistance with Stability and Grace in Potentiostatic Circuits. , I. Introduction -- II. Input-Output Relations of Cells and Potentiostats -- III. Stability of Potentiostat-Cell Circuits and the Role of Ru -- IV. Compensation for iRu by Positive Feedback -- V. Achieving Stability Through Gain-Frequency Shaping -- VI. Real Systems -- Appendix -- Bibliography -- 8 Conductivity and Conductometry -- I. Some Basic Relationships -- II. DC Contact Measurement of Conductance -- III. Capacitive Contact Measurement of Conductance -- References -- 9 Electrochemical Cells -- I. Design Concepts -- II. Stationary-Solution Experiments -- III. Convected-Solution Experiments -- IV. Thin-Layer Cell Design -- V. Cells for Spectroelectrochemistry -- References -- 10 Carbon Electrodes -- I. Introduction -- II. Performance Criteria -- III. Carbon Electrode Materials Properties -- IV. Common Carbon Electrode Materials -- V. Selection of Carbon Electrodes for Analytical Applications -- References -- 11 Film Electrodes -- I. Introduction -- II. Applications of Thin-Film Electrodes -- III. Properties of Film Electrodes -- IV. Metal Film Electrodes -- V. Carbon Film Electrodes -- VI. Semiconductor Film Electrodes -- VII. Techniques of Cell Design Based on Film Electrodes -- VIII. Prospects for Disposable, Integrated Sensor Systems -- References -- 12 Microelectrodes -- I. Introduction -- II. Construction of Microelectrodes -- III. Diffusion at Microelectrodes -- IV. High-Speed Cyclic Voltammetry -- V. Ohmic Drop at Microelectrodes -- VI. Very Small Electrodes -- VII. Conclusions -- 13 Chemically Modified Electrodes -- I. Introduction -- II. Methods for Preparing Chemically Modified Electrodes -- III. Electrochemistry at Chemically Modified Electrodes -- IV. Characterization and Analysis of Chemically Modified Electrodes -- V. Applications of Chemically Modified Electrodes -- VI. Conclusions -- References -- 14 Mercury Electrodes. , I. Introduction -- II. Dropping Mercury Electrode -- III. Hanging Mercury Drop Electrode -- IV. Static Mercury Drop Electrode -- V. Streaming Mercury Electrodes -- VI. Mercury Film and Other Types of Mercury Electrodes -- References -- 15 Solvents and Supporting Electrolytes -- I. Introduction -- II. Recommended Solvents and Electrolytes -- III. Some Other Solvents -- IV. Solvent- and Electrolyte-Dependent Phenomena -- V. Experimental Procedures -- Appendix: Other Literature -- References -- 16 Electrochemical Studies at Reduced Temperature -- I. Introduction -- II. Motivations for Variation of the Temperature in Electrochemical Studies -- III. Examples of the Study of the Rates of Coupled Chemical Reactions -- IV. Practical Aspects of Electrochemical Studies at Low Temperatures -- References -- 17 Electroanalytical Chemistry in Molten Salts -- I. Introduction -- II. Molten Salt Systems -- III. Apparatus and Techniques -- References -- 18 Vacuum-Line Techniques -- I. Introduction -- II. Vacuum Line -- III. Electrochemical Glassware for the Vacuum Line -- References -- 19 Electrochemistry in the Dry Box -- I. Introduction -- II. Choosing an Inert-Atmosphere System -- III. Experimental Procedures -- Appendix -- References -- 20 Digital Simulation of Electrochemical Problems -- I. Introduction -- II. The Finite Difference Representation of Fick's Laws -- III. The Model Diffusion Coefficient: Defining At and Ax -- IV. Establishing Initial and Boundary Conditions -- V. Dimensionless Parameters -- VI. A Sample BASIC Program -- VII. Chronocoulometry -- VIII. Other Nernstian Electrode Boundary Conditions -- IX. Homogeneous Kinetics -- X. Parametric Substitutions -- XI. Electrogenerated Chemiluminescence -- XII. Chronopotentiometry -- XIII. Linear Sweep and Cyclic Voltammetry -- XIV. Simulation of Rotating Disk Hydrodynamics. , XV. Simulation of Rotating Ring Disk Behavior -- XVI. The Steady-State Assumption -- XVII. Beyond the Basics -- References -- 21 Evaluation of Mechanisms of Organic Reactions -- I. Introduction -- II. Reduction of p-Chlorobenzonitrile -- III. Oxidation of Adrenaline -- IV. Oxidation of a-Tocopherol -- V. Concluding Remarks -- References -- 22 Electroorganic Synthesis -- I. What Is Electroorganic Synthesis? -- II. Advantages and Disadvantages of Electroorganic Reactions -- III. Technically Interesting Processes -- IV. Classification of Electroorganic Reactions -- V. Experimental Factors and Techniques -- References -- 23 Instructional Examples of Electrode Mechanisms of Transition Metal Complexes -- I. Electrode Mechanisms -- II. Obtaining High-Quality Data -- III. Mechanistic Studies -- IV. Examples of Selected Mechanisms -- V. Comments on Second-Order Homogeneous Reactions -- References -- 24 Electrochemical Preconcentration -- I. Why Preconcentration? -- II. Stripping Analysis -- III. Electrochemical Preconcentration for Spectroscopic Analysis -- References -- 25 Controlled-Current Coulometry -- I. Introduction -- II. Coulometric Generation of Reagents -- III. Coulometric Titrations -- References -- 26 Electrochemistry in Pharmaceutical Analysis -- I. Introduction -- II. Coulometric Methods -- III. Voltammetric Methods -- References -- 27 Electrochemical Detection in Liquid Chromatography and Capillary Electrophoresis -- I. Introduction -- II. Transducer Design -- III. Waveforms -- IV. Applications Review -- V. Capillary Electrophoresis/Electrochemistry -- VI. Conclusions -- VII. Performance Criteria for Electrochemical Detectors -- References -- 28 Photonic Electrochemistry -- I. Introduction -- II. Photoelectrochemistry& -- #x2014 -- Semiconductor/Electrolyte Interfaces -- III. Photoemission from Metal Electrodes. , IV. Electrochemical Monitoring of Photolytic Intermediates -- V. Electrochemiluminescence -- Appendix: Structures of Cited Molecules -- References -- 29 Principles and Techniques of Electrochemical-Electron Paramagnetic Resonance Experiments -- I. Magnetic Resonance in Electrochemical Studies -- II. Molecular Orbitals in Electrochemistry and EPR -- III. Principles of EPR -- IV. EPR Instrumentation -- V. Experimental Methods of EPR-Electrochemical Studies -- VI. Selected Applications of EPR and Electrochemical Measurements -- Appendix I: Selected Bibliography -- Appendix II: Units -- References -- Index.