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  • 1
    Keywords: Forschungsbericht
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource (51 Seiten, 9,29 MB) , Illustrationen, Diagramme
    Language: German
    Note: Förderkennzeichen BMBF 03F0755B [richtig] - 03F0755A [falsch]. - Verbund-Nummer 01171990 , Unterschiede zwischen dem gedruckten Dokument und der elektronischen Ressource können nicht ausgeschlossen werden
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  • 2
    Publication Date: 2023-02-08
    Description: MILAN was a multidisciplinary, international study examining how the diel variability of sea-surface microlayer biogeochemical properties potentially impacts ocean-atmosphere interaction, in order to improve our understanding of this globally important process. The sea-surface microlayer (SML) at the air-sea interface is 〈 1 mm deep but it is physically, chemically and biologically distinct from the underlying water and the atmosphere above. Wind-driven turbulence and solar radiation are important drivers of SML physical and biogeochemical properties. Given that the SML is involved in all ocean-atmosphere exchanges of mass and energy, its response to solar radiation, especially in relation to how it regulates the air-sea exchange of climate-relevant gases and aerosols, is surprisingly poorly characterised. MILAN (sea-surface MIcroLAyer at Night) was an international, multidisciplinary campaign designed to specifically address this issue. In spring 2017, we deployed diverse sampling platforms (research vessels, radio-controlled catamaran, free-drifting buoy) to study full diel cycles in the coastal North Sea SML and in underlying water, and installed a land-based aerosol sampler. We also carried out concurrent ex situ experiments using several microsensors, a laboratory gas exchange tank, a solar simulator, and a sea spray simulation chamber. In this paper we outline the diversity of approaches employed and some initial results obtained during MILAN. Our observations of diel SML variability, e.g. the influence of changing solar radiation on the quantity and quality of organic material, and diel changes in wind intensity primarily forcing air-sea CO2 exchange, underline the value and the need of multidisciplinary campaigns for integrating SML complexity into the context of air-sea interaction.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 3
    Publication Date: 2022-11-07
    Description: Microplastics (MP) are defined as synthetic organic pollutants sized 〈5 mm and have been recorded in various environments worldwide. Due to their small size, they pose a potential risk for many organisms throughout the food web. However, little is known about MP distribution patterns and associated transport mechanisms. Rivers may act as pathways for MP into marine environments. In this study, we investigate the occurrence of MP in the estuary and lower stretch of the second-largest German River, the Weser, representative of a significant interface between fresh water and marine environments. The aim of the study was to enhance the general understanding by providing novel, comprehensive data and suggestions for future studies on estuarine systems. Surface water samples of two different size classes were collected by ship using an on-board filtration system (11-500 µm fraction) and net sampling (500-5000 µm fraction). After a thorough sample preparation, all samples were analysed with Focal Plane Array (FPA) Fourier Transform Infrared (FTIR) spectroscopy and Attenuated Total Reflection (ATR) FTIR spectroscopy in order to obtain information on MP concentrations, polymer composition and size distribution. Our findings show highest concentrations in the 11-500 µm fraction (2.3 × 101 − 9.7 × 103 m−3), with the polymer cluster acrylates/polyurethanes/varnish being dominant. The 〉500 µm fraction was dominated by polyethylene. Estimated MP concentrations generally increased in the Turbidity Maximum Zone (TMZ) and decreased towards the open sea. This study contributes to the current research by providing novel insights into the MP pollution of the estuary and lower stretch of an important European river and provides implications for future MP monitoring measures.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 4
    Publication Date: 2023-06-10
    Description: In order to assess pollution with small microplastics (S-MP, 11-500 µm) in the Lower Weser and transition to the German North Sea, surface water samples were collected with the RV Otzum (ICBM, Institute for Chemistry and Biology of the Marine Environment), as well as with the RV Uthörn (AWI, Alfred-Wegener-Institute) in April 2018. Sampling was performed using a pumping system containing of a floating suction basket (mesh size: 500 µm) for pre-filtration, followed by the concentration onto a 15 µm stainless steel screen. Samples were isolated from the filter screens in the laboratory, thoroughly processed and measured via µFTIR imaging. Dominant polymer type in the S-MP sample fraction was acrylates/polyurethanes/varnish, and concentrations ranged between 2.3 × 10¹ and 9.7 × 10³ m⁻³, with maximum values in the area of the turbidity Maximum Zone of the River Weser.
    Keywords: Acrylates, polyurethanes, varnish; Acrylonitrile butadiene; Cellulose chemical modified; Chlorinated polyethylene; DATE/TIME; Duration; Ethylene-vinyl acetate; Event label; Freshwater system; ICBM_Ot1804; Infrared Spectroscopy; Jade Bay; LATITUDE; Location; LONGITUDE; Method comment; Microplastic abundance; Microplastics; Mikroplastikkontamination im Modellsystem Weser – Nationalpark Wattenmeer: ein ökosystemübergreifender Ansatz; Nitrile rubber; North Sea margin; O_10_16; O_10_18; O_10_37; O_10_39; O_10_41; O_10_43; O_10_45; O_10_47; O_10_48; O_10_49; O_10_50; O_10_51; O_10_52; O_10_53; Otzum; Plastic pollution; PLAWES; Polyamide; Polycaprolactone; Polycarbonate; Polyester; Polyether ether ketone; Polyethylene; Polylactic acid; Polyoxymethylene; Polypropylene; Polystyrene; Polysulfone; Polyvinyl chloride; Project; river; Rubber; Sample volume; U_10_19; U_10_20; U_10_30; U_10_30a; U_10_30b; U_10_30d; U_10_31; U_10_33; U_10_34; UT04/2018; Uthörn; Water sample; Weser, Germany, Europe; WS
    Type: Dataset
    Format: text/tab-separated-values, 598 data points
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  • 5
    Publication Date: 2024-02-26
    Description: In order to assess pollution with large microplastics (L-MP, 500-5000 µm) in the Lower Weser and transition to the German North Sea, surface water samples were collected with the RV Otzum (ICBM, Institute for Chemistry and Biology of the Marine Environment), as well as with the RV Uthörn (AWI, Alfred-Wegener-Institute) in April 2018. Sampling was performed using a microplastic net (mesh size: 300 µm), followed by filtration in the laboratory over a 500 µm stainless steel sieve. Putative MP items in the size range 500-5000 µm were analysed by means of Attenuated Total Reflection - FTIR in order to determine the underlying synthetic polymer. Dominant polymer type in the L-MP sample fraction was polyethylene. Concentrations ranged between 1 × 10⁻² m⁻³ and 9.8 × 10⁻¹ m⁻³. The highest MP concentration was measured upstream the Weser Weir.
    Keywords: Acrylates, polyurethanes, varnish; Attenuated Total Reflection – Fourier Transform Infrared Spectroscopy (ATR-FTIR); DATE/TIME; Duration; Ethylene-propylene; Ethylene-vinyl acetate; Ethylene vinyl alcohol; Event label; Freshwater system; ICBM_Ot1804; Infrared Spectroscopy; Jade Bay; LATITUDE; Location; LONGITUDE; Method comment; Microplastic abundance; Microplastics; Mikroplastikkontamination im Modellsystem Weser – Nationalpark Wattenmeer: ein ökosystemübergreifender Ansatz; North Sea margin; O_300_16; O_300_18; O_300_37; O_300_39; O_300_41; O_300_43; O_300_45; O_300_47; O_300_48; O_300_49; O_300_50; O_300_51; O_300_52; O_300_53; Otzum; Plastic pollution; PLAWES; Polyamide; Polyester; Polyethylene; Polyethylene oxidized; Polymer, other; Polypropylene; Polystyrene; Project; river; Rubber; Sample volume; U_300_19; U_300_20; U_300_30; U_300_30a; U_300_30b; U_300_30d; U_300_31; U_300_33; U_300_34; UT04/2018; Uthörn; Water sample; Weser, Germany, Europe; WS
    Type: Dataset
    Format: text/tab-separated-values, 414 data points
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