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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Archives of dermatological research 30 (1895), S. 130-159 
    ISSN: 1432-069X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2011-11-23
    Description: Water vapor in the subtropical troposphere plays an important role in the radiative balance, the distribution of precipitation, and the chemistry of the Earth's atmosphere. Measurements of the water vapor mixing ratio paired with stable isotope ratios provide unique information on transport processes and moisture sources that is not available with mixing ratio data alone. Measurements of the D/H isotope ratio of water vapor from Mauna Loa Observatory over 4 weeks in October–November 2008 were used to identify components of the regional hydrological cycle. A mixing model exploits the isotope information to identify water fluxes from time series data. Mixing is associated with exchange between marine boundary layer air and tropospheric air on diurnal time scales and between different tropospheric air masses with characteristics that evolve on the synoptic time scale. Diurnal variations are associated with upslope flow and the transition from nighttime air above the marine trade inversion to marine boundary layer air during daytime. During easterly trade wind conditions, growth and decay of the boundary layer are largely conservative in a regional context but contribute ∼12% of the nighttime water vapor at Mauna Loa. Tropospheric moisture is associated with convective outflow and exchange with drier air originating from higher latitude or higher altitude. During the passage of a moist filament, boundary layer exchange is enhanced. Isotopic data reflect the combination of processes that control the water balance, which highlights the utility for baseline measurements of water vapor isotopologues in monitoring the response of the hydrological cycle to climate change.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
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  • 3
    Publication Date: 2016-05-24
    Description: Late Cenozoic surface uplift of the southern Sierra Nevada (Sierra; California, United States) is widely debated. Recent interpretations of lee-side isotope records from the southern Sierra suggest that the elevation of the southern Sierra has been sufficiently high to induce atmospheric flow patterns similar to modern patterns since the mid-Miocene, at ca. 12 Ma. The tendency for flow to deflect around a topographic barrier can be determined by the atmospheric stability, barrier height, and incoming wind speed. We test the sensitivity of flow deflection to elevation to determine what elevation would have been sufficiently high to establish modern flow patterns in the mid-Miocene. Using global paleoclimate models and idealized regional weather models, we find that the Miocene atmosphere was more stable than modern. We suggest that in a Miocene climate, flow patterns similar to modern patterns could have been achieved for elevations as low as 2 km, and that while Miocene lee-side isotope records from the southern Sierra may indicate that the southern Sierra has been a longstanding topographic feature, they may not have changed significantly in response to proposed late Cenozoic surface uplift of the southern Sierra.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 4
    Publication Date: 2016-08-23
    Description: The measurement and simulation of water vapor isotopic composition has matured rapidly over the last decade, with long-term datasets and comprehensive modeling capabilities now available. Theories for water vapor isotopic composition have been developed by extending the theories that have been used for the isotopic composition of precipitation to include a more nuanced understanding of evaporation, large-scale mixing, deep convection, and kinetic fractionation. The technologies for in-situ and remote sensing measurements of water vapor isotopic composition have developed especially rapidly over the last decade, with discrete water vapor sampling methods, based on mass spectroscopy, giving way to laser spectroscopic methods and satellite- and ground-based infrared absorption techniques. The simulation of water vapor isotopic composition has evolved from General Circulation Model (GCM) methods for simulating precipitation isotopic composition to sophisticated isotope-enabled microphysics schemes using higher-order moments for water- and ice-size distributions. The incorporation of isotopes into GCMs has enabled more detailed diagnostics of the water cycle and has led to improvements in its simulation. The combination of improved measurement and modeling of water vapor isotopic composition opens the door to new advances in our understanding of the atmospheric water cycle, in processes ranging from the marine boundary layer, through deep convection and tropospheric mixing, and into the water cycle of the stratosphere. Finally, studies of the processes governing modern water vapor isotopic composition provide an improved framework for the interpretation of paleoclimate proxy records of the hydrological cycle.
    Print ISSN: 8755-1209
    Topics: Geosciences
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  • 5
    Publication Date: 2011-09-07
    Description: Simultaneous, real-time measurements of atmospheric water vapor mixing ratio and isotopic composition (δD and δ18O) were obtained using cavity ringdown spectroscopy on the arid Chajnantor Plateau in the subtropical Chilean Andes (elevation 5080 m or 550 hPa; latitude 23°S) during July and August 2010. The measurements show surface water vapor mixing ratio as low as 215 ppmv, δD values as low as −540‰, and δ18O values as low as −68‰, which are the lowest atmospheric water vapor δ values reported from Earth's surface. The results are consistent with previous measurements from the base of the tropical tropopause layer (TTL) and suggest large-scale subsidence of air masses from the upper troposphere to the Earth's surface. The range of measurements is consistent with condensation under conditions of ice supersaturation and mixing with moister air from the lower troposphere that has been processed through shallow convection. Diagnostics using reanalysis data show that the extreme aridity of the Chajnantor Plateau is controlled by condensation in the upper tropical troposphere.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
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  • 6
    Publication Date: 2017-11-08
    Description: The development of relief may generate leeside rain shadows where precipitation δ 18 O values are lower due to rainout on the windward side. The magnitude of lowering in paleo-δ 18 O sampled from the leeside of a mountain range should, at least in principle, be related to the elevation of the mountain range. In order for leeside proxies to record the highest elevations, the majority of air masses need to travel up and over the ridge crest before raining out on the leeside. If atmospheric flow patterns around the mountain range are dominated by flow deflection, air masses that reach the leeside are less likely to record the highest elevations. Using the Weather Research and Forecasting model and Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model, we demonstrate that modern atmospheric flow patterns in the Southern Alps of New Zealand are not dominated by flow deflection. The lack of flow deflection around the Southern Alps and the relatively low relief throughout the uplift history supports the use of leeside isotope records to constrain the timing of uplift, and that uplift likely occurred ~5 Ma based on leeside isotope records. In contrast, orogens that are characterized by high elevations and strong flow deflection, like the Sierra Nevada of California, may not be good candidates for leeside isotope-based paleoaltimetry studies. Ideal candidates for such studies should be characterized by relatively low elevations, low atmospheric flow deflection, and relatively low relief throughout the period of uplift.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
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  • 7
    Publication Date: 2013-01-30
    Description: Stable isotope paleoaltimetry studies often implicitly assume that atmospheric flow interactions with topography can be simply modeled as a Rayleigh distillation process in which air parcels consistently ascend topographic barriers. We present a modern (A.D. 1979–2010) air parcel trajectory analysis using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model that shows that this fundamental assumption is often violated in the Sierra Nevada region of the western United States. Observed trajectory patterns and scaling calculations indicate that windward orographic blocking frequently occurs when trajectories encounter high elevations (〉2.5 km) in the central and southern Sierra Nevada. As a result, trajectories reaching the Sierran lee commonly travel around, rather than over, the highest range elevations. Redirection effects are particularly pronounced at leeward sites distal (〉150 km) to the Sierran crest, but are also evident in trajectory patterns in the northern Sierra Nevada. This trajectory analysis improves the interpretability of regional meteoric water and proxy isotopic records and has particular relevance to stable isotope–based reconstructions of Sierran paleoelevations. Specifically, stable isotope methods alone provide only limited insight into the elevation history of the Sierra Nevada and are likely insufficient to resolve proposed late Cenozoic elevation gains on the order of 1–2 km that may have raised the Sierra to its modern elevations.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 8
    Publication Date: 2014-11-26
    Description: Water vapor measured continuously by cavity ring-down spectroscopy from July 2012 to March 2013 on the hyperarid Chajnantor Plateau, northern Chile (elevation = 5080 m, pressure ≈ 550 hPa), has a mean deuterium excess (d-excess = δD - 8*δ18O) of 46‰ + 5‰ and frequently exceeds 100‰ at low water vapor mixing ratios (q 〈 500 ppmv). These measurements provide empirical support for theoretical predictions of free troposphere d-excess. The d-excess measured at this site can be understood in terms of supersaturation with respect to ice at relative humidities between 100% and 130%, followed by mixing with moist mid- or lower-tropospheric air en route to the plateau. The d-excess measured at Chajnantor is consistent with predictions for d-excess in the upper troposphere from isotope-enabled general circulation models and with high vapor saturation over ice in cloud-resolving and microphysical models.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
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  • 9
    Publication Date: 2014-09-05
    Description: The interaction of the subsiding limb of the Hadley circulation and the easterly North Pacific Trade Winds establishes a persistent thermal inversion at about 2000 m above sea level in the subtropical Pacific. The inversion restricts convective rainfall to the lower elevations of the windward flank of the island of Hawaii, creating an order-of-magnitude vertical rainfall gradient, as well as high inter-basin variability in precipitation. In the high-rainfall zone, streams are incised 10s to 100 s of meters below the surface of the volcanic shield. We use a digital elevation model and 1-D numerical modeling to assess whether deep incision on the flank of Mauna Kea is tied to the elevation of the trade wind inversion. The 83 channels examined can be well-fit in aggregate by all models that account for differences in precipitation between basins; specifically, the maximum depth of incision in each drainage is a power function of precipitation-weighted drainage area with an exponent of ~ ½. Individual longitudinal stream profiles are generally better-fit by models that acknowledge both along-channel precipitation variability and the subsidence of the island through that gradient, but this relationship is not clearly demonstrable for many channels. We argue that island subsidence through the dry-to-wet precipitation gradient has resulted in less cumulative discharge in the lower reaches of the drainages over their lifetime, relative to a non-subsiding case. This reduces differential erosion between the wet and dry reaches by 20-30% over 300 ky, making the longitudinal profiles less sensitive to the very strong climate gradient.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
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  • 10
    Publication Date: 2014-08-05
    Description: Measurements of water vapor isotopic composition in stratospheric air intrusions can be used to constrain the dilution of the intrusion as it mixes into the middle troposphere. The intrusion studied here occurred on 17-18 August 2012 with measurements obtained at an altitude of 5 km in the Chilean Andes at the Atacama Large Millimeter Array (ALMA) astronomical observatory on the Chajnantor Plateau. Surface ozone concentrations rose 16 ppb in 6 hours and were associated with a potential vorticity intrusion on the 330 K isentropic surface. A simulated stratospheric ozone tracer reaching Chajnantor also supports the interpretation of a stratospheric intrusion. Beginning around 18:00 UTC on August 17th, the mixing ratio dropped from 3000 ppmv to 430 ppmv as the water vapor δ D values dropped from −153 to −438 over 13 hours while the δ 18 O values dropped from -20 ‰ to -63 ‰. The average mixing ratio, δ D, and δ 18 O values during August 2012 were measured to be 1500 ppmv, −250‰, and -34‰, respectively. The minimum water vapor concentration during the intrusion was in the driest 5% of measurements made during that month, while the minimum δ D and δ 18 O values were within the lowest 0.5% of measurements made during that month. Simple two-component models of mixing between stratospheric or upper tropospheric air with boundary layer air fail to reproduce observations, but a three-component mixing model, in which the stratospheric intrusion mixes with an upper tropospheric background airmass as it mixes with boundary layer air on Chajnantor matches the observations.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
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