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  • 1
    Publication Date: 2023-07-29
    Description: A concomitant effect of a hydraulic fracturing experimenting is frequently fluid permeation into the rock matrix, with the injected fluid permeating through the porous rock matrix (leak-off) rather than contributing to the buildup of borehole pressure, thereby slowing down or impeding the hydro-fracturing process. Different parameters, such as low fluid viscosity, low injection rate and high rock permeability, contribute to fluid permeation. This effect is particularly prominent in highly permeable materials, therefore, making sleeve fracturing tests (where an internal jacket separates the injected fluid in the borehole from the porous rock matrix) necessary to generate hydraulic fractures. The side effect, however, is an increase in pressure breakdown, which results in higher volume of injected fluid and in higher seismic activity. To better understand this phenomenon, we report data from a new comparative study from a suite of micro-hydraulic fracturing experiments on highly permeable and on low-permeability rock samples. Experiments were conducted in both sleeve fracture and direct fluid fracture modes using two different injection rates. Consistent with previous studies, our results show that hydraulic fracturing occurred only with low permeation, either due to the intrinsic low permeability or due to the presence of an inner silicon rubber sleeve. In particular, due to the presence of quasi-impermeable inner sleeve or borehole skin in the sleeve fracturing experiment, fracturing occurs, with the breakdown pressure supporting the linear elastic approach considering poroelastic effects, therefore, with low stress drop and consequently low microseismicity. Rock matrix permeability also controls the presence of precursory Acoustic Emission activity, as this is linked to the infiltration of fluids and consequent expansion of the pore space. Finally, permeability is shown to mainly control fracturing speed, because the permeation of fluid into the newly created fracture via the highly permeable rock matrix slows down its full development. The application of these results to the field may help to reduce induced seismicity and to conduct well stimulation in a more efficient way.
    Description: Petroleum Technology Development Fund http://dx.doi.org/10.13039/501100009614
    Description: Niedersächsische Ministerium für Wissenschaft und Kultur (DE)
    Description: Georg-August-Universität Göttingen (1018)
    Keywords: ddc:550.724 ; Permeability ; Hydraulic fracturing ; Acoustic emissions ; Fracture propagation speed ; Fluid permeation ; Leak-off
    Language: English
    Type: doc-type:article
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electrophoresis 13 (1992), S. 690-697 
    ISSN: 0173-0835
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: ‘Syrupy’ solutions of liquid linear polyacrylamide (≥ 10%T, 0%C) appear to be excellent for fractionation of oligonucleotides and potentially, for DNA sequencing. For such analyses, the silica wall must be coated by covalently bound strings of polyacrylamide; otherwise, the electroosmotic flow will slowly pump out the viscous electrolyte solution. Due to the enormous viscosity (100 Pa s for an 8 %T solution) the polymer strings must be prepared in situ, by filling the capillary with the appropriate monomer solution. The reaction, however, cannot be driven to better than 80-85% conversion: in 10%T, the concentration of unreacted monomers will thus be 200-300 mM. This will give a substantial background absorbance (even at 254 nm) and leave a huge amount of potentially harmful reacting species in the background electrolyte. A chemical scavenging method is proposed here: after polymerization, a 100 mM solution of cysteine is driven in from the cathode and allowed to react for up to 10 h. At the end of the reaction period, the excess cysteine and its acrylamido adduct are driven out electrophoretically and the column is reconstituted with its normal background electrolyte. Columns thus preconditioned have been found to perform extremely well and to last as long as the inner coating (and the linear polymer filling) will last. No ‘carry over’ from run to run was experienced.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0173-0835
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Matrices for electrokinetic separations, based on a unique class of mono- and disubstituted (on the amido nitrogen) acrylamides such as e.g., N-acryloylaminoethoxyethanol (AAEE) and acrylamido-N,N-diethoxyethanol, offer the following advantages: (i) strong resistance to alkaline hydrolysis (most zone separations occurring at basic pH values), (ii) high hydrophilicity and (iii) greater porosity, due to the higher molecular weight of the monomers. When compared with conventional poly(acrylamide), a poly(AAEE) matrix, when subjected to mild alkaline hydrolysis (0.1 N NaOH, 70°C) appears to be 500 times more stable. Such stability is also confirmed under strong alkaline hydrolysis (1 N NaOH, 100°C) as well as under mild and strong acidic hydrolysis. Mildly hydrolyzed poly(AAEE) matrices still perform extremely well in both conventional isoelectric focusing and immobilized pH gradients, techniques which are quite sensitive to traces of acrylate in the polymer coil. Conversely, mildly hydrolyzed poly(acrylamide) matrices, when used in isoelectric focusing, generate pH gradients between pH 4 and 5, having an inflection point (pH 4.6) equivalent to the pK value of acrylic acid. This novel class of monomers shows great promise for future applications in all electrokinetic methodologies.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2020-11-25
    Description: Volcanic activity is often preceded or accompanied by different types of seismo-volcanic signals. Among these signals, the so-called tornillo (Spanish for "screw") events are considered to belong to a unique class of volcano-seismicity characterised by a long-duration coda, amplitude modulation and high-quality factor. These data constitute important evidence for the gas fraction inside magmatic fluids. However, the mechanism behind this unique signal remains not fully understood. Here we report new laboratory evidence showing that two different processes have either scale-invariant or scale-dependent effects in generating tornillo-like events. These processes are respectively the gas pressure gradient, which triggers the event and regulates the slow decaying coda, and the fluid resonance into small scale structures which, in turn, control the frequency content of the signal. Considering that the gas pressure gradient is proportional to the fluid flow, these new findings, as applied to volcanoes, provide new information to better quantify both gas rate and volume, and the dimension of the resonator.
    Description: Published
    Description: id 7338
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2013-10-26
    Description: Author(s): Marco Gibertini, Rosario Fazio, Marco Polini, and Fabio Taddei We study adiabatic pumping at a normal metal/class- D superconductor hybrid interface when superconductivity is induced through the proximity effect in a spin-orbit coupled nanowire in the presence of a tilted Zeeman field. When the induced order parameter in the nanowire is nonuniform, the phase dia... [Phys. Rev. B 88, 140508] Published Fri Oct 25, 2013
    Keywords: Superfluidity and superconductivity
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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