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  • 1
    Online Resource
    Online Resource
    La Vergne :Royal Society of Chemistry, The,
    Keywords: Environmental chemistry. ; Electronic books.
    Description / Table of Contents: Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.
    Type of Medium: Online Resource
    Pages: 1 online resource (214 pages)
    Edition: 1st ed.
    ISBN: 9781847555984
    Series Statement: Issn Series
    DDC: 574.5/2
    Language: English
    Note: Environmental Chemistry -- Contents -- Chapter 1 Stable Isotope Studies and Biological Element Cycling -- 1 Introduction -- 2 Carbon -- Biological Cycling -- 3 Sulphur -- Biological Cycling -- 4 Nitrogen -- Biological Cycling -- 5 Hydrogen -- 6 Oxygen -- 7 General Conclusions -- Chapter 2 Environmental Organic Chemistry of Rivers and Lakes, Both Water and Sediment -- 1 Introduction -- Economic Significance -- Nature of the Freshwater Environment -- 2 Sources of Organic Matter -- 3 Organic Matter in Water -- Particulate Fraction -- Dissolved Organic Matter -- Simple Lipids -- Carbohydrates -- Organic Nitrogen Compounds -- Vitamins -- Compounds Responsible for Odours in Waters -- Coloured Organic Substances -- Release of Dissolved Organic Material -- 4 Organic Matter in Sediments -- Hydrocarbons -- Fatty Acids -- Alcohols and Sterols -- Ketones -- Carbohydrates -- Amino-acids -- Pigments -- Sedimentary Humus -- 5 Organophosphorus Compounds in Water and Sediments -- 6 Chemical Pollution of the Aquatic Environment -- Pesticides -- Stability and Fate of Pesticides -- Industrial and Domestic Pollutants and Sewage Effluents -- Organic Mercury Derivatives -- 7 Stability of Organic Matter in Aquatic Environments -- Steady-state Model of the Environment -- 8 Stable Carbon Isotope Distribution -- Chapter 3 Environmental Organic Chemistry of Bogs, Marshes, and Swamps -- 1 Introduction: Characteristics of Wetland Environments -- 2 Some Ecological Aspects -- 3 Water in Peats -- 4 Organic-Inorganic Interactions in Peats -- Ion-Exchange Behaviour -- Trace Elements -- Sulphur -- 5 Organic Constituents of Wetland Peats -- Phenols and Humic Acids -- Alkanes, Fatty Acids, and Sterols -- Amino-Acids -- Carbohydrates -- 6 The Effect of Human Activities on Wetland Environments -- 7 The Preservation of Organic Matter in Wetlands. , Chapter 4 Environmental Organic Chemistry of Oceans, Fjords, and Anoxic Basins -- 1 Introduction -- 2 Waters -- Organic Carbon -- Lipids -- Fatty Acids -- Hydrocarbons -- Sterols -- Amino-acids -- Carbohydrates -- Vitamins -- 3 Sediments -- Lipids -- Amino-acids -- Carbohydrates -- Pigments -- Humic Acids -- Vitamins -- 4 Anoxic Basins and Fjords -- 5 Water-Atmosphere Interface -- 6 Water-Sediment Interface -- Microbial Activity -- Sediment-Soluble Organic Compounds Associations -- Chapter 5 Hydrocarbons in the Marine Environment -- 1 Introduction -- 2 Origin of Hydrocarbons -- Biosynthesis -- Geochemical Processes -- Anthropogenic Inputs -- 3 Analysis of Petroleum Hydrocarbons and Biosynthesized Hydrocarbons -- Comparison of the Composition of Petroleum Hydrocarbons and Biosynthesized Hydrocarbons -- Petroleum Hydrocarbons -- n-Alkanes -- Branched alkanes -- Cycloalkanes (naphthenes) -- Aromatic hydrocarbons -- Alkenes (olefins) -- Recently Biosyntliesized or Native Hydrocarbons -- n-Alkanes -- Branched alkanes -- Alkenes (olefins) -- Cycloalkanes and cycloalkenes -- Aromatic hydrocarbons -- Summary -- Characteristics of Petroleum Hydrocarbons Useful for Detecting Petroleum Contamination -- Sampling and Analysis -- Sample Contamination -- Intercalibration and Comparison of Data -- Extraction -- Saponification -- Separation of Hydrocarbons from other Lipids -- Analysis of Hydrocarbons -- Infrared Spectrometry -- U.v. absorption and u.v. fluorescence spectrometry -- Gas chromatography -- Mass spectrometry and gas chromatography-mass spectrometry -- Computer-interfaced mass spectrometry and gas chromatography-mass spectrometry -- Quantification -- Application of the methods of analysis -- Reporting results of analyses -- 4 Distribution of Hydrocarbons -- Marine Organisms -- Sea-water -- 'Tarballs' and Tar Particles -- Slicks -- Surface Sediments. , Marine Atmosphere -- Concentrations of Hydrocarbons in Sea-water, Sediments, and Organisms -- Sea-water -- Organisms -- Sediments -- Oil-polluted samples -- Processes Controlling the Distribution of Hydrocarbons -- Physical-chemical -- Biological -- 5 Fate of Hydrocarbons in the Marine Environment -- Incorporation into Sediments -- Transfer to the Atmosphere -- Biochemical Alteration -- 6 Oil spills -- 7 Summary -- Chapter 6 The Fate of DDT and PCB's in the Marine Environment -- 1 Introduction -- 2 Laboratory Studies of Biological Degradation of DDT and PCB's -- Aquatic Plants -- Fish -- Micro-organisms -- 3 Transport of DDT and PCB's to the Marine Environment -- Transport -- Sewage Sludge -- 4 Distribution of DDT and PCB's in the Marine Environment -- Sea-water -- Sea Surface -- Organisms -- 5 Uptake of Pesticide Residues by Organisms -- Laboratory Studies -- Biological Magnification -- Field Studies -- 6 Analysis of Chlorinated Hydrocarbons -- Chapter 7 Environmental Organic Chemistry of 2,4-Dichlorophenoxyacetic Acid -- 1 Introduction -- 2 Synthesis -- 3 Distribution of 2,4-D in the Environment -- Plants -- Animals -- 4 Fate of 2,4-D in the Environment -- Plants -- Soil -- Water -- 5 Analysis -- Extraction -- Isolation -- Quantitative Estimation -- 6 Conclusion -- Author Index.
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  • 2
    Online Resource
    Online Resource
    La Vergne :RSC,
    Keywords: Electronic books.
    Description / Table of Contents: Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.
    Type of Medium: Online Resource
    Pages: 1 online resource (214 pages)
    Edition: 1st ed.
    ISBN: 9781847555984
    Series Statement: ISSN Series
    Language: English
    Location Call Number Limitation Availability
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  • 3
    Type of Medium: Book
    Pages: [12] S
    Series Statement: Reference / Woods Hole Oceanographic Institution 71,47
    Language: English
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  • 4
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    European journal of soil science 47 (1996), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: A combination of radiocarbon (14C) dating and biomarker analyses of the aliphatic hydrocarbons in soil lipids is proposed as a novel and improved method for studying the environmental history of peaty soils. The radiocarbon concentration of unfractionated bulk organic matter, hydrolysed soil residues and two lipid fractions (the aliphatic hydrocarbons and carboxylic acids) recovered from a stagnohumic gley soil, were compared using AMS (accelerator mass spectrometry) and radiometric 14C dating techniques. The radiocarbon ages recorded by the aliphatic hydrocarbon fractions were consistently older than those measured from the unfractionated soil, and were in most cases older than the residues remaining after acid hydrolysis. This pattern was observed at three different depths in the soil profile. The apparent age difference between the hydrocarbon fraction and its unfractionated substrate increased with depth. An abundance of long–chain n–alkanes, similar to those found in higher plant waxes, characterized the aliphatic hydrocarbon fraction from the deepest soil (at 21.5–24.5–cm depth). The radiocarbon age of this basal organic component (13470± 170 years bp) indicated that it derived from the initial re–establishment of vegetation on the local deglaciated landscape with the onset of the Windermere Interstadial (c. 14000–13000 14C years bp). Bulk organic detritus within the basal horizon dated at some 3000 years younger, and presumably as a result of the downward penetration and retention of some mobile organic residues produced later in the development of the soil profile. The survival and apparent stratigraphical stability of these recoverable aliphatic hydrocarbons provides the opportunity, via the development of AMS dating, to measure an unambiguous radiocarbon age for the origin of organic residues retained in soils and sediments.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: We have sought to understand the molecular mechanisms by which dissolved organic matter (DOM) forms and soil organic matter (SOM) degrades in upland peaty gley soil under grass. Pyrolysis mass spectrometry (Py-MS) and pyrolysis gas chromatography mass spectrometry (Py-GC/MS) were applied to characterize the DOM collected from lysimeters and its parent SOM. The macromolecular organic matter in the litter and fermentation (Lf) horizon of the soil consists primarily of little decomposed lignocellulose from grass, whereas the humus (Oh) horizon is characterized by an accumulation of selectively decomposed lignocellulose material, microbial metabolites and bound fatty acids. The mineral horizon produced a relative enrichment of furan structures derived from microbial reworking of plant polysaccharides but virtually no lignin signals. A series of exceptional long chain C43 to C53 fatty acids with odd over even predominance, probably derived from mycobacteria, were also identified in the Oh horizon. Side-chain oxidation and shortening, increase of carboxyl functionality and selective removal of syringyl (S) 〉 guaiacyl (G) 〉 p-hydroxyphenyl (P) lignin units were the main reactions when lignin degraded. Compared with SOM, the DOM shows a large accumulation of more oxidized lignin and aromatic structures, especially those containing carboxylic and dicarboxylic acid functionalities and with shorter side-chain length. The polysaccharide-type compounds in the DOM were more modified (greater abundance of furan structures in pyrolysis products), and had significantly lower molecular weight and more diverse polymeric structures than did those in soils. Increased temperature and rainfall appeared to result in greater relative abundance of lignin degradation products and aromatic compounds in DOM.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Energy & fuels 6 (1992), S. 215-225 
    ISSN: 1520-5029
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 47 (1975), S. 415-419 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1520-5029
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 308 (1984), S. 439-442 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Dinoflagellates are major primary producers in the oceans7,8, differing from other classes of both marine and lacustrine algae with respect to the dominance of 4a-methylsterols among their sterol components and the uniqueness of certain of these 4a-methylsterol structures. As the principal sterol ...
    Type of Medium: Electronic Resource
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