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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Spectroscopic ellipsometry (SE) characterization of several complex SixGe1−x/Si heterostructures prepared for device fabrication, including structures for heterojunction bipolar transistors (HBT), p- and n-type heterostructure modulation-doped field-effect transistors, has been performed. It is shown that SE can simultaneously determine all active layer thicknesses, SixGe1−x compositions, and the oxide overlayer thickness, with only a general knowledge of the structure topology needed a priori. The characterization of HBT material includes the SE analysis of a SixGe1−x layer deeply buried (600 nm) under the silicon emitter and cap layers. In the SE analysis of n-type heterostructures, a silicon layer under tensile strain was examined. It was found that an excellent fit can be obtained using optical constants of unstrained silicon to represent the strained silicon conduction layer. SE was also used to measure lateral sample homogeneity, providing quantitative identification of the inhomogeneous layer. Surface overlayers resulting from prior sample processing were also detected and measured quantitatively. These results should allow SE to be used extensively as a nondestructive means of characterizing SixGe1−x/Si heterostructures prior to device fabrication and testing.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 53 (1988), S. 514-516 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Superconducting thin films (500–1000 A(ring) in thickness) of A15 V3Si have been grown on (111)Si substrates through molecular beam epitaxial techniques. V and Si are codeposited in a feedback-stabilized, 3:1 flux ratio from dual e-beam evaporators onto clean, heated Si substrates in an ultrahigh vacuum chamber. For the first time, the superconducting A15 V3Si phase is metastably fabricated directly on a crystalline Si substrate without the formation of thermodynamically favored Si-rich VxSiy phases. Our films exhibit superconductivity only within a narrow range of intermediate growth temperatures (centered near 400 °C), with an optimum Tc of 12.5 K. X-ray diffraction shows the superconducting films to be polycrystalline A15 V3Si. For slightly higher growth temperatures (≈530 °C), Auger profile, x-ray, and transmission electron microscopy measurements indicate the appearance of an intermediate layer of roughly 1:1 V:Si composition. Our observations demonstrate that a growth temperature near 400 °C results in successful nucleation of the superconducting A15 phase while minimizing solid phase reaction with the substrate during V3Si growth.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 56 (1990), S. 569-571 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have used x-ray photoelectron spectroscopy to measure the valence-band offset in situ for strained Si/Ge (100) heterojunctions grown by molecular beam epitaxy. Si 2p and Ge 3d core level to valence-band-edge binding energies and Si 2p to Ge 3d core level energy separations were measured as functions of strain, and strain configurations in all samples were determined using x-ray diffraction. Our measurements yield valence-band offset values of 0.83±0.11 eV and 0.22±0.13 eV for Ge on Si (100) and Si on Ge (100), respectively. If we assume that the offset between the weighted averages of the light hole, heavy hole, and spin-orbit valence bands in Si and Ge is independent of strain, we obtain a discontinuity in the average valence-band edge of 0.49±0.13 eV.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 56 (1990), S. 367-369 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: High quality, coherently strained Si1−xGex alloy layers are studied using high-resolution x-ray diffraction (HRXRD) and ex situ transmission electron diffraction. Several samples were grown at extremely low temperatures (310–330 °C) by molecular beam epitaxy. Sample thicknesses and alloy concentrations were chosen to span a range beginning just below to significantly above critical thicknesses previously reported for this system. HRXRD observations demonstrate a high degree of coherency in the as-grown structures since measurements of the lattice constant parallel to the sample surface (a(parallel)) consistently yield the value for the (100)Si substrate. HRXRD from (004) planes used to measure a⊥ typically yield a spectrum with several peaks for growths in excess of the critical thickness and single peaks for those below the critical thickness. The high degree of coherency observed in these samples suggests that chemical segregation is responsible for the observed x-ray peaks.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 62 (1993), S. 1626-1628 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present an ellipsometric study of two Si0.5Ge0.5/Si strained-layer superlattices grown by MBE at low temperature (500 °C), and compare our results with x-ray diffraction (XRD) estimates. Excellent agreement is obtained between target values, XRD, and ellipsometry when one of two available SixGe1−x databases is used. We show that ellipsometry can be used to nondestructively determine the number of superlattice periods, layer thicknesses, SixGe1−x composition, and oxide thickness without resorting to additional sources of information. We also note that we do not observe any strain effect on the E1 critical point.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 2530-2532 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Si/Si0.97C0.03 superlattices were grown on Si(001) substrates by molecular beam epitaxy (MBE) to study the use of Sb as a surfactant during Si1−yCy growth. In situ reflection high energy electron diffraction (RHEED) shows that while carbon easily disrupts the two-dimensional growth of homoepitaxial Si, such disruption is suppressed for layers grown on Sb-terminated Si(001) surfaces. Cross-sectional transmission electron microscopy (TEM) reveals that for samples grown without the use of Sb, the Si/Si0.97C0.03 interfaces (Si0.97C0.03 on Si) were much more abrupt than Si0.97C0.03/Si interfaces. In the case of Sb-mediated growth, differences in abruptness between the two types of interfaces were not readily observable. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 1310-1312 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The dependence of substitutional C fraction on growth temperature and substrate orientation is measured for Si1−yCy alloy films grown on (001) and (118) Si by molecular-beam epitaxy. Secondary ion mass spectrometry and high-resolution x-ray diffraction were used to measure the total C and the substitutional C concentrations, respectively, in several samples prepared at temperatures between 450 and 650 °C. The substitutional C fraction decreased rapidly with increasing temperature in this range, regardless of orientation, and was slightly lower for growth on (118) Si. Cross-sectional transmission electron microscopy on (118)-oriented samples revealed a tendency for C to concentrate periodically on (001) facets which formed immediately after initiation of Si1−yCy growth. A kinetic Monte Carlo simulation based upon enhanced diffusion of Si dimers in the presence of subsurface C predicted a step instability leading to step bunching and the formation of periodic surface features, as well as the accumulation of high C concentrations on nearly (001) planes. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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