ISSN:
1435-1536
Keywords:
Poly(isobutyl cyanoacrylate)
;
monolayers
;
isotherms
;
thermodynamic parameters
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract Poly(isobutyl cyanoacrylate) (PIBCA) monolayers, unlike those of most substances, respond to increased temperature with a decrease in area per monomer unit and a fall in the surface pressures at which surface phase transition and collapse occur. These effects are associated with an increase in entropy during isothermal compression of the film, and are attributed to the rise in temperature causing loss of solvation water, rather than to increased solubility of PIBCA.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00655674
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