Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
85 (1986), S. 3732-3734
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Single vibronic level fluorescence spectra from the 6112 level in 1B2u benzene and benzene-d6 in a free jet expansion include sharp transitions to S0 levels identified as high normal mode overtones of the C–C ring breathing mode up to 10 000 cm−1. For these levels, and for the reported method of state preparation, the upper bound for the rate of intramolecular vibrational redistribution is kIVR 〈1012 s−1. This rate is several times smaller than for C–H or C–D stretch local mode levels of similar energy when they are prepared via overtone absorption from the ground state.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.450945
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