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  • 1
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung Arsenkies-Goldmineralisation in altpaläozoischen Serien der ostlichen Pyrenäen tritt in zwei Typen auf: Disseminiert in Hercynischen Metasedimenten, und in Gängen, die die Haupt-Foliation durchschlagen. In den Zentralpyrenäen wurden goldführende Arsenkies-Mineralisationen vor kurzem in Skarnen längs des SW-Kontaktes des Andorra-Granites entdeckt. Die Erzminerale sind ähnlich denen in den Gängen, wobei Gold mit Arsenkies, Wismut und Sulfiden assoziiert ist. Der spät-hercynische Andorra-Granit intrudierte paläozoische Metasedimente von Prä-Caradoc bis Karbon-Alter. Im Kontaktbereich Granit/Devonische Kalke kommen sechs Typen von Skarnen vor. Nur drei davon führen Sulflde, nämlich die Hedenbergit-, Magnetkies- und Arsenkiesskarne. Goldgehalte in diesen Skarnen schwanken von weniger als 0,8 g/t in Magnetkiesskarnen bis zu 7 g/t in Arsenkiesskarnen. Das ö34 S von Arsenopyrit in disseminierten und Gang-Mineralisationen schwankt von 11-15%o, und dies weist auf eine Schwefelquelle in der Kruste hin. Gangsulflde haben sich auch nach einer metamorphen Remobilisierung der Sulfid-reichen Disseminationen in den paläozoischen Serien gebildet. Die Schwefelisotopenzusammensetzung der Skarnsulfide schwankt: Magnetkies aus Magnetkiesskarnen hat ö34 S Werte von ≈ +4%o, dies weist auf magmatischen Ursprung hin. Ihre Goldgehalte sind sehr niedrig (〈0,8 0,8 g/t). Die schwereren Isotopen von Arsenkies in Arsenkies-Skarnen (δ 34S+ 10%o) und von Bleiglanz und Zinkblende aus den Hedenbergit-Skarnen (δ 34S+ 7%o) lassen sich mit höheren Goldgehalten (7 und 5 g/t) korrelieren. Dies wird Fluiden zugeschrieben, die reich an Schwefel aus den Nebengesteinen sind und durch die thermale Metamorphose der Arsenkies-führenden Metasedimente (δS ≈ + 12%o) während der Skarnbildung, oder durch Assimilation von Nebengestein durch den Granit wahrend seiner Platznahme entstanden sind. Die wirtschaftliche Bedeutung dieser Skarne scheint in einer direkten Beziehung zur Menge krustaler Fluide zu stehen.
    Notes: Summary Arsenopyrite-gold mineralization in the lower Paleozoic series of the eastern Pyrenees is of two types: disseminated in Hercynian metasediments, and veins cross-cutting the main foliation. In the central Pyrenees, gold-bearing arsenopyrite mineralizations have recently been discovered in skarns along the SW contact of the Andorra granite. The ore minerals are similar to those of the veins, with gold also being associated with arsenopyrite, bismuth and sulphides. The late Hercynian Andorra granite intruded Paleozoic metasediments of pre-Caradocian to Carboniferous age. Six types of skarns have developed at or close to the contact between the granite and Devonian limestones. Only three of these, the hedenbergite, pyrrhotite and arsenopyrite skarns, are sulphide-bearing. Gold grades in these skarns range from less than 0.8 g/t in pyrrhotite skarns to 7 g/t in arsenopyrite skarns. The Δ34S of arsenopyrite from disseminated and vein mineralizations show values from 11 to 15‰, indicating a sulphur source of crustal origin. Vein sulphides are considered to have formed after a metamorphic remobilization of the sulphide rich disseminations in the Paleozoic series. Sulphur isotopic composition of skarn sulphides is variable: pyrrhotite from pyrrhotite skarns has a Δ34S ≈ +‰, suggesting a sulphur of magmatic origin. Their gold grades are very low (〉0.8 g/t). The heavier values of arsenopyrite from arsenopyrite skarns (δ34S ≈ + 10‰) and of galena and sphalerite from hedenbergite skarns (Δ34S ≈ + 7‰) correlate with the higher gold grades (7 and 5 g/t, respectively). This is interpreted to reflect a contribution of wall-rock sulphur-rich fluids generated from the thermal metamorphism of arsenopyrite-bearing wall-rock metasediments (δ34S ≈ + 12%o) during skarn formation or by assimilation of country rock by the granitic intrusion during its emplacement. The economic importance of these skarns appears to be related to the amount of crustal fluid involved in skarn formation.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Mineralium deposita 16 (1981), S. 195-204 
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Vein mineralisation with no preferred orientation, cutting lower Palaeozoic rocks, and local replacement deposits in dolomite show a zoning in tungsten-bismuth, arsenic and antimony minerals away from the adjacent late-Hercynian Costabona granite. A local reversed zoning is related to higher temperatures indicated by fluid inclusion study. Many of the minerals have not previously been reported from this area.
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  • 3
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Several varieties of skarn outcrop have been found to develop along the contact between the Andorra granite and the Devonian limestones. The skarns contain variable amounts of gold ranging up to 5 g/t, always associated with sulphides. The sulphides in the skarn include arsenopyrite and pyrrhotite with lesser amounts of chalcopyrite, galena, sphalerite and Bi-minerals. Geothermometric and geobarometric data indicate the skarns formed at about 2 kbar and temperatures ranging from 500 ° to 350 °C from CO2-free polysaline brines at a slightly acidic pH and oxygen fugacity which decreases with time from the pyrite-pyrrhotite-magnetite towards the QFM buffer. Available data on gold solubility suggest that sufficient quantities of gold to form an ore deposit could have been transported as AuCl 2 - at the high temperatures and salinities under which the skarns formed. Both gold deposition and sulphide precipitation could have occurred due to a decrease in temperature and/or oxygen fugacity.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Mineralium deposita 32 (1997), S. 243-249 
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The lead isotopic composition of galenas from low-temperature veins of the Catalonian Coastal Ranges (NE Spain) displays a small but distinct range of values: 18.318 ≤206Pb/204Pb ≤ 18.678; 15.678 ≤207Pb/204Pb ≤ 15.767 and 38.534 ≤ 208Pb/204Pb ≤ 39.189. The data define a linear trend in the 208Pb/204Pb versus 206Pb/204Pb diagram that can be interpreted in terms of mixing of lead from different reservoirs. The lead appears to be derived from a solution that preferentially leached granites of Late-Hercynian age. Sulphur isotopic compositions of the galenas range from −8.5 to + 7.3‰ but variations in a single deposit are small (1–2‰), pointing to different sources of sulphur. In a δ34S versus 206Pb/204Pb plot no clear correlation trends appear. Lead isotope data from deposits of similar characteristics situated within the Hercynian orogenic belt as the Linares-La Carolina district (S Spain) and the Inglesiente-Sulcis area (Sardinia) show slight differences indicating a source area of similar lead isotopic composition. In the CCR and Linares-La Carolina districts, the main source of lead is related to the Hercynian granites of each area, although small contributions from metasediments cannot be ruled out. The contribution of lead from metasedimentary rocks is particularly seen in the Sardinian (Hercynian vein-type) ores.
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  • 5
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The Rocabruna and Coll de Pal barite deposits, located in the eastern Pyrenees of Spain, fill karstic cavities within carbonate rocks of Cambrian and Devonian age, respectively. The deposits contain barite, chalcopyrite, tetrahedrite, pyrite and minor sphalerite and galena with saddle dolomite and quartz as gangue. Fluid inclusion data from Coll de Pal quartz and dolomite indicate that the mineralizing fluid was a polysaline CaCl2-rich brine, with temperatures between 125 and 150 °C. C and O isotopic compositions of carbonates in both deposits are consistent with a progressive increase in temperature during deposition. The 34S values of barite, which range from 14.2 to 15.9‰ in Coll de Pal, and from 13.9 to 19.3‰ in Rocabruna, together with 87Sr/86Sr ratios ranging from 0.7118 to 0.7168 in Rocabruna, and from 0.7115 to 0.7136 in Coll de Pal, indicate two different fluid sources. We propose that these deposits formed as a result of mixing between a Ba-rich, sulfate-poor hot fluid, and sulfate-rich solutions of surficial origin. The different Sr isotope ratios in the deposits indicate that the hot Ba-rich fluids involved in each deposit were equilibrated with different rock types (carbonates and shales), in agreement with the geology of the two areas.
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  • 6
    Publication Date: 2014-02-11
    Description: Partially dolomitized carbonate rocks of the Middle East and North America host large hydrocarbon reserves. The origin of some of these dolomites has been attributed to a hydrothermal mechanism. The Benicàssim area (Maestrat Basin, eastern Spain) constitutes an excellent field analogue for fault-controlled stratabound hydrothermal dolomitization: dolostone geobodies are well exposed and extend over several kilometres away from seismic-scale faults. This work investigates the main controls on the formation of stratabound versus massive dolomitization in carbonate sequences by means of two-dimensional (2D) reactive transport models applied to the Benicàssim case study. Simulation results suggest that the dolomitization capacity of Mg-rich fluids reaches a maximum at temperatures around 100 °C and a minimum at 25 °C (studied temperature range: 25–150 °C). It takes of the order of hundreds of thousands to millions of years to completely dolomitize kilometre-long limestone sections, with solutions flowing laterally through strata at velocities of metres per year (m/a). Permeability differences of two orders of magnitude between layers are required to form stratabound dolomitization. The kilometre-long stratabound dolostone geobodies of Benicàssim must have formed under a regime of lateral flux greater than metres per year over about a million years. As long-term dolomitization tends to produce massive dolostone bodies not seen at Benicàssim, the dolomitizing process there must have been limited by the availability of fluid volume or the flow-driving mechanism. Reactive transport simulations have proven a useful tool to quantify aspects of the Benicàssim genetic model of hydrothermal dolomitization.
    Print ISSN: 1354-0793
    Topics: Chemistry and Pharmacology , Geosciences
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  • 7
    Publication Date: 2016-02-23
    Description: Cerro Quema (Azuero Peninsula, southwest Panama) is a high-sulfidation epithermal Au-Cu deposit hosted by a dacite dome complex of the Río Quema Formation (late Campanian to Maastrichtian), a fore-arc basin sequence. Mineral resource estimates (indicated + inferred) are 30.86 Mt at 0.73 g/t Au, containing 728,000 oz Au (including 76.900 oz Au equiv of Cu ore). Hydrothermal alteration and mineralization are controlled by an E-trending regional fault system. Hydrothermal alteration consists of an inner zone of vuggy quartz with locally developed advanced argillic alteration, enclosed by a well-developed zone of argillic alteration, grading to an external halo of propylitic alteration. Mineralization produced disseminations and microveinlets of pyrite and minor chalcopyrite, enargite, and tennantite, with traces of sphalerite, crosscut by late-stage base metal veins. New 40 Ar/ 39 Ar data of igneous rocks combined with biostratigraphic ages of the volcanic sequence indicate a maximum age of lower Eocene (~55–49 Ma) for the Cerro Quema deposit. It was probably triggered by the emplacement of an underlying porphyry-like intrusion associated with the Valle Rico batholith. The geologic model suggests that in the Azuero Peninsula high-sulfidation epithermal mineralization occurs in the Cretaceous-Paleogene fore arc. This consideration should be taken into account when exploring for this deposit type in similar geologic terranes.
    Print ISSN: 0361-0128
    Topics: Geosciences
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  • 8
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    In:  2nd CNES CCT workshop on passive reflectometry using radiocom space signals (Calais, France 2011)
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/conferenceObject
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  • 9
    Publication Date: 2020-02-12
    Type: info:eu-repo/semantics/report
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  • 10
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/conferenceObject
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