Notes: Upper Pliocene dolomites (‘white earth’) from La Roda, Spain, offer a good opportunity to evaluate the process of dolomite formation in lakes. The relatively young nature of the deposits could allow a link between dolomites precipitated in modern lake systems and those present in older lacustrine formations. The La Roda Mg-carbonates (dolomite unit) occur as a 3·5- to 4-m-thick package of poorly indurated, white, massive dolomite beds with interbedded thin deposits of porous carbonate displaying root and desiccation traces as well as local lenticular gypsum moulds. The massive dolomite beds consist mainly of loosely packed 1- to 2-μm-sized aggregates of dolomite crystals exhibiting poorly developed faces, which usually results in a subrounded morphology of the crystals. Minute rhombs of dolomite are sparse within the aggregates. Both knobbly textures and clumps of spherical bodies covering the crystal surfaces indicate that bacteria were involved in the formation of the dolomites. In addition, aggregates of euhedral dolomite crystals are usually present in some more clayey (sepiolite) interbeds. The thin porous carbonate (mostly dolomite) beds exhibit both euhedral and subrounded, bacterially induced dolomite crystals. The carbonate is mainly Ca-dolomite (51–54 mol% CaCO3), showing a low degree of ordering (degree of ordering ranges from 0·27 to 0·48). Calcite is present as a subordinate mineral in some samples. Sr, Mn and Fe contents show very low correlation coefficients with Mg/Ca ratios, whereas SiO2 and K contents are highly correlated. δ18O- and δ13C-values in dolomites range from −3·07‰ to 5·40‰ PDB (mean=0·06, σ=1·75) and from −6·34‰ to −0·39‰ PDB (mean=−3·55, σ=1·33) respectively. Samples containing significant amounts of both dolomite and calcite do not in general show significant enrichment or depletion in 18O and 13C between the two minerals. The correlation coefficient between δ18O and δ13C for dolomite is extremely low and negative (r=−0·05), whereas it is higher and positive (r=0·47) for calcite. The lacustrine dolomite deposit from La Roda is interpreted mainly as a result of primary precipitation of dolomite in a shallow, hydrologically closed perennial lake. The lake was supplied by highly saturated HCO3−/CO32− groundwater that leached dolomitic Mesozoic formations. Precipitation of dolomite from alkaline lake waters took place under a semi-arid to arid climate. However, according to our isotopic data, strong evaporative conditions were not required for the formation of the La Roda dolomite. A significant contribution by bacteria to the formation of the dolomites is assumed in view of both petrographic and geochemical evidence.

Notes: Abstract The Miocene sedimentary record of the Madrid Basin displays several examples of palaeokarstic surfaces sculpted within evaporite formations. One of these palaeokarstic surfaces represents the boundary between two main lithostratigraphic units, the Miocene Lower and Intermediate units of the Madrid Basin. The palaeokarst formed in lacustrine gypsum deposits of Aragonian age and corresponds to a surface palaeokarst (epikarst), further buried by terrigenous deposits of the overlying unit. Karst features are recognized up to 5·5 m beneath the gypsum surface. Exokarst and endokarst zones are distinguished by the spatial distribution of solution features, i.e. karren, dolines, pits, conduits and caves, and collapse breccias, sedimentary fills and alteration of the original gypsum across the karst profiles. The development of the gypsum palaeokarst began after drying out of a saline lake basin, as supported by recognition of root tubes, later converted to cylindrical and funnel-shaped pits, at the top of the karstic profiles. The existence of a shallow water table along with low hydraulic gradients was the main factor controlling the karst evolution, and explains the limited depth reached by both exokarst and endokarst features. Synsedimentary fill of the karst system by roughly laminated to massive clay mudstone with subordinate carbonate and clastic gypsum reflects a punctuated sedimentation regime probably related to episodic heavy rainfalls typical of arid to semi-arid climates. Duration of karstification is of the order of several thousands of years, which is consistent with previous statements that gypsum karstification can develop rapidly over geologically short time periods.

Notes: The middle Miocene sedimentary fill of the Calatayud Basin in north-eastern Spain consists of proximal to distal alluvial fan-floodplain and shallow lacustrine deposits. Four main facies groups characteristic of different sedimentary environments are recognized: (1) proximal and medial alluvial fan facies that comprise clast-supported gravel and subordinate sandstone and mudstone, the latter exhibiting incipient pedogenic features; (2) distal alluvial fan facies, formed mainly of massive mudstone, carbonate-rich palaeosols and local carbonate pond deposits; (3) lake margin facies, which show two distinct lithofacies associations depending on their distribution relative to the alluvial fan system, i.e. front (lithofacies A), comprising massive siliciclastic mudstone and tabular carbonates, or lateral (lithofacies B) showing laminated and/or massive siliciclastic mudstone alternating with tabular and/or laminated carbonate beds; and (4) mudflat–shallow lake facies showing a remarkable cyclical alternation of green-grey and/or red siliciclastic mudstone units and white dolomitic carbonate beds. The cyclic mudflat–shallow lake succession, as exposed in the Orera composite section (OCS), is dominantly composed of small-scale mudstone–carbonate/dolomite cycles. The mudstone intervals of the sedimentary cycles are interpreted as a result of sedimentation from suspension by distal sheet floods, the deposits evolving either under subaerial exposure or water-saturated conditions, depending on their location on the lacustrine mudflat and on climate. The dolomite intervals accumulated during lake-level highstands with Mg-rich waters becoming increasingly concentrated. Lowstand to highstand lake-level changes indicated by the mudstone/dolomite units of the small-scale cycles reflect a climate control (from dry to wet conditions) on the sedimentation in the area. The spatial distribution of the different lithofacies implies that deposition of the small-scale cycles took place in a low-gradient, shallow lake basin located in an interfan zone. The development of the basin was constrained by gradual alluvial fan aggradation. Additional support for the palaeoenvironmental interpretation is derived from the isotopic compositions of carbonates from the various lithofacies that show a wide range of δ18O and δ13C values varying from −7·9 to 3·0‰ PDB and from −9·2 to −1·7‰ PDB respectively. More negative δ18O and δ13C values are from carbonate-rich palaeosols and lake-margin carbonates, which extended in front of the alluvial fan systems, whereas more positive values correspond to dolomite beds deposited in the shallow lacustrine environment. The results show a clear trend of δ18O enrichment in the carbonates from lake margin to the centre of the shallow lake basin, thereby also demonstrating that the lake evolved under hydrologically closed conditions.

Notes: Lacustrine laminated sediments (laminites) present in Late Miocene formations of the Híjar Basin, SE Spain, display well developed loop bedding, a structure consisting of bundles of laminae that are sharply constricted at intervals, giving a morphology of loops or links of a chain. The laminite sequences, which are interbedded with turbidite marlstones, were accumulated on the bottom of a permanently stratified lake developed in a rapidly subsiding basin limited by 010° and 105° normal faults. As deduced from both macro- and microdeformational analyses, the basin evolved under an extensional stress field throughout the Late Miocene. Four main types of loops, simple and complex loops with subcategories, have been recognized within the laminite sequence. Simple loops of type 1 show the best definite pattern, quite similar to ‘pinch and swell structures’, a type of boudinage typical of stretching of alternating beds where the competence contrast is not strongly marked. The remaining loop types display contortion and occasional breakage of laminae (microfaulted edges) indicative of microdeformation near the boundary between the ductile-brittle deformational fields. The distribution of the various loop types across the laminite sequence reflects an interplay between progressive lithification of the laminites as sedimentation progressed and tectonic stresses which affected the sediment sequence. Accordingly, a mechanism of deformation under an extensional stress field, ultimately related to the creep movement of the main basin faults which resulted in successive seismic shocks of low magnitude, is proposed to explain the formation of loop bedding in the laminites.