GLORIA

GEOMAR Library Ocean Research Information Access

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
Document type
Language
  • 1
    Online Resource
    Online Resource
    Amsterdam :IOS Press, Incorporated,
    Keywords: Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (263 pages)
    Edition: 1st ed.
    ISBN: 9781614995074
    Series Statement: International School of Physics Enrico Fermi Series ; v.187
    Language: English
    Note: Title page -- Contents -- Preface -- Course group shot -- Experimental tests of the liquid-liquid phase transition hypothesis -- Water and its relatives: The stable, supercooled and particularly the stretched regimes -- Introduction -- Liquid domains and stable states -- Hydrogen bonds and anomalies of water -- High pressure -- Properties of supercooled water and solutions -- The second-critical-point hypothesis and the problem of its location -- Validity of the second-critical-point hypothesis -- Is water unique? Brothers and cousins -- Stretched water: negative-pressure investigations -- Hard data in the negative-pressure domain -- A modified van der Waals model for stretched liquids -- Concluding commentary -- Atmospheric water -- Introduction -- General structure of the Earth's atmosphere -- Condensed phases of water in the atmosphere -- Pure water phases -- Introduction to aerosol particles -- Phase transitions of water -- Cooling processes leading to supersaturation -- Gas-to-liquid transition: liquid-water droplets from water vapor -- Liquid-to-ice transition: ice crystals from supercooled water droplets -- Homogeneous ice nucleation in pure water -- Heterogeneous ice nucleation in pure water -- Implications: the Wegener-Bergeron-Findeisen process -- Ice nucleation in haze particles -- Homogeneous ice nucleation -- Heterogeneous ice nucleation (immersion freezing) -- Kinetic state diagram of atmospheric humidity -- X-ray spectroscopy, scattering and simulation studies of instantaneous structures in water -- The inhomogeneous structure hypothesis -- Two local distinct structures -- X-ray spectroscopy -- Connecting XAS/XRS and XES -- Peak shifts with temperature -- Comparing effects of temperature with adding salts -- Consistency with vibrational spectroscopy -- The nature of the distorted species -- understanding XAS/XRS -- The pre-edge. , The main edge -- Interpretation of XAS/XRS: Newns-Anderson model -- The inherent structure in MD simulations -- Density fluctuations -- Normal and anomalous contributions to kappa_T -- Compressibility in MD models -- Density inhomogeneities and Small-Angle X-ray Scattering -- Small-Angle X-ray Scattering (SAXS) -- Qualitative understanding of SAXS data -- The relation between correlation length and spatial extent -- Anticorrelation between tetrahedrality and density -- Wide-angle scattering and pair-correlation functions g_OO(r) -- Correlations at intermediate range (6-15 angstrom) -- Temperature dependence of intermediate-range correlations -- The first O-O peak -- The HDL local structure -- Concluding remarks -- Spectroscopy and modeling of aqueous interfaces -- SHG as a surface probe -- Langmuir models for interfacial adsorption -- The 1:1 exchange model -- The effects of water exchange in the exchange model -- An alternative approach -- Langmuir adsorption modeling including cations -- SHG/Langmuir fitting procedures -- Applications -- Water and ice structure in the range 220-365K from radiation total scattering experiments -- Introduction -- Experimental -- X-ray scattering experiment -- Neutron scattering experiment -- Empirical Potential Structure Refinement -- Results -- Fits to the data -- Other derived quantities -- Discussion -- Conclusion -- Crystalline and amorphous ices -- Introduction -- Crystalline ices -- Stable phases, metastable phases and the melting line -- Ice I: cubic ice and hexagonal ice -- Proton order-disorder transitions -- Ice X and post-ice X phases -- Negative pressure -- Summary: crystalline ices -- Amorphous ices -- Motivation -- Formation/preparation -- Atomistic structure of amorphous ices -- Liquid-liquid phase transition hypothesis -- Glass transitions in amorphous ices -- Glass transition in ASW. , Glass transition in HGW -- Glass transition in LDA -- Glass transition in HDA -- Summary: amorphous ices -- Water in confined geometries -- Introduction -- The structure of confined water -- Water confined in porous Vycor-glass -- Water confined in MCM41 silica cylindrical pores -- Water in water/oil emulsions -- Water in a charge colloidal suspension -- Conclusions -- NMR studies of water -- Introduction -- The dynamical crossover in supercooled water -- The clustering dynamics of water/methanol solution -- The folding/unfolding process of hydrated lysozyme -- Conclusions -- List of participants.
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 4227-4228 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 9859-9867 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A molecular dynamics simulation of water confined in a silica pore is performed in order to compare it with recent experimental results on water confined in porous Vycor glass at room temperature. A cylindrical pore of 40 Å is created inside a vitreous SiO2 cell, obtained by computer simulation. The resulting cavity offers water a rough hydrophilic surface and its geometry and size are similar to those of a typical pore in porous Vycor glass. The site-site distribution functions of water inside the pore are evaluated and compared with bulk water results. We find that the modifications of the site-site distribution functions, induced by confinement, are in qualitative agreement with the recent neutron diffraction experiment, confirming that the disturbance to the microscopic structure of water mainly concerns orientational arrangement of neighboring molecules. A layer analysis of MD results indicates that, while the geometrical constraint gives an almost constant density profile up to the layers closest to the interface, with a uniform average number of hydrogen bonds (HB), the hydrophilic interaction produces the wetting of the pore surface at the expenses of the adjacent water layers. Moreover, the orientational disorder together with a reduction of the average number of HB persists in the layers close to the interface, while water molecules cluster in the middle of the pore at a density and with a coordination similar to bulk water. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 8056-8063 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Using the technique of hydrogen and deuterium substitution, the structure of water in concentrated NaOH solution (10 M) is explored. It is found that major changes in water structure occur both in the liquid phase at T=300 K and in the glassy phase at T=173 K. In particular the 4.4 Å peak in the OO pair correlation function of pure water, which is normally viewed as indicating tetrahedral short-range coordination in water, is totally absent in the NaOH solution at room temperature, and shows up only as a small feature in the NaOH solution in the glassy state. Corresponding changes occur in the OH and HH correlation functions: The hydrogen bond peak position is shifted from 1.85 Å in pure water to 1.65 Å for both the liquid and glassy NaOH, with a reduced number of hydrogen bonds in the glassy phase. The intramolecular HH distance, 1.5 Å, of the water molecule is unaffected by the presence of the solute, but the positions of the peaks in the HH function at 2.4 and 3.8 Å, due to the orientational correlation between neighboring pure water molecules, are respectively, shifted to 2.15 and 3.5 Å. The above findings indicate that ions in aqueous solutions induce a change in water structure equivalent to the application of high pressures. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biophysical Chemistry 37 (1990), S. 165-170 
    ISSN: 0301-4622
    Keywords: Hydration ; Proton ; Tunneling
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 6
    ISSN: 0884-3996
    Keywords: common variable immunodeficiency ; cellular immunity ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Common variable immunodeficiency is a primary immunodeficiency characterized by a failure of antibody synthesis, whose fundamental immunologic abnormality is still unknown. In our study, we evaluated some immune functions using chemiluminescence in a 32-year-old woman affected by common variable immunodeficiency. In particular, we showed an impairment of her lymphomonocyte proliferative response which was evaluated using a method based on the bioluminescent measurement of ATP. Besides, we found a reducton of her lymphomonocyte IL2 and IL4 production: the IL4 production was evaluated through an ELISA method, whereas the IL2 activity was determined by its ability to support the IL2-dependent murine T-cell line (CTLL) proliferation which was established through a method based on the bioluminescent measurement of ATP. Finally, we evaluated both yeast-induced and fMLP-induced polymorphonuclear and monocyte oxidative metabolism through a luminol-amplified chemiluminescence; these functions were within normal values. Therefore, in our patient affected by common variable immunodeficiency, we demonstrated an impairment of cellular immunity, which might contribute to the pathogenesis of the disease. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 7
    Publication Date: 2011-12-14
    Description: Studies of liquid water in its supercooled region have helped us better understand the structure and behavior of water. Bulk water freezes at its homogeneous nucleation temperature (approximately 235 K), but protein hydration water avoids this crystallization because each water molecule binds to a protein. Here, we study the dynamics of the hydrogen bond (HB) network of a percolating layer of water molecules and compare the measurements of a hydrated globular protein with the results of a coarse-grained model that successfully reproduces the properties of hydration water. Using dielectric spectroscopy, we measure the temperature dependence of the relaxation time of proton charge fluctuations. These fluctuations are associated with the dynamics of the HB network of water molecules adsorbed on the protein surface. Using Monte Carlo simulations and mean-field calculations, we study the dynamics and thermodynamics of the model. Both experimental and model analyses are consistent with the interesting possibility of two dynamic crossovers, (i) at approximately 252 K and (ii) at approximately 181 K. Because the experiments agree with the model, we can relate the two crossovers to the presence at ambient pressure of two specific heat maxima. The first is caused by fluctuations in the HB formation, and the second, at a lower temperature, is due to the cooperative reordering of the HB network.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2014-11-07
    Description: The p.N478D missense mutation in human mitochondrial poly(A) polymerase (mtPAP) has previously been implicated in a form of spastic ataxia with optic atrophy. In this study, we have investigated fibroblast cell lines established from family members. The homozygous mutation resulted in the loss of polyadenylation of all mitochondrial transcripts assessed; however, oligoadenylation was retained. Interestingly, this had differential effects on transcript stability that were dependent on the particular species of transcript. These changes were accompanied by a severe loss of oxidative phosphorylation complexes I and IV, and perturbation of de novo mitochondrial protein synthesis. Decreases in transcript polyadenylation and in respiratory chain complexes were effectively rescued by overexpression of wild-type mtPAP. Both mutated and wild-type mtPAP localized to the mitochondrial RNA-processing granules thereby eliminating mislocalization as a cause of defective polyadenylation. In vitro polyadenylation assays revealed severely compromised activity by the mutated protein, which generated only short oligo(A) extensions on RNA substrates, irrespective of RNA secondary structure. The addition of LRPPRC/SLIRP, a mitochondrial RNA-binding complex, enhanced activity of the wild-type mtPAP resulting in increased overall tail length. The LRPPRC/SLIRP effect although present was less marked with mutated mtPAP, independent of RNA secondary structure. We conclude that (i) the polymerase activity of mtPAP can be modulated by the presence of LRPPRC/SLIRP, (ii) N478D mtPAP mutation decreases polymerase activity and (iii) the alteration in poly(A) length is sufficient to cause dysregulation of post-transcriptional expression and the pathogenic lack of respiratory chain complexes.
    Print ISSN: 0964-6906
    Electronic ISSN: 1460-2083
    Topics: Biology , Medicine
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 9
    Publication Date: 2017-04-04
    Description: During the cruise of the Italian research vessel URANIA on August 2007, a new tsunami detector was successfully deployed at 3200 b. s. l. in the Gulf of Cadiz, Portugal. The new detector is installed on board the multi-parameter abyssal observatory GEOSTAR. This activity is a task of NEAREST EC Project (http://nearest.bo.ismar.cnr.it/ ). Among other tasks, the NEAREST project will produce and test the basic parts of an operational prototype of a near field tsunami warning system. The warning system includes an onshore warning centre based on the seismic and tide gauges monitoring networks which are already operating in the area of Gulf of Cadiz and connected in real time with many warning receiving shore stations, a buoy equipped with meteostation and two way acoustic and satellite links, and the tsunami detector installed on board GEOSTAR. The warning centre is in charge of collecting, integrating, and evaluating data recorded at sea. In the observatory at the sea bottom, data are recorded and processed by the tsunami detector which includes a pressure sensor, a seismometer and two accelerometers. The observatory communicates acoustically with a surface buoy in two-way mode. The buoy is equipped with meteo station and GPS and it is connected to the shore station via satellite dual-link. The prototype is designed to operate in tsunami generation areas for detection-warning purpose as well as for scientific measurements during long term monitoring. The pressure data are processed in real time on the sea floor observatory by a tsunami detection algorithm able to detect small tsunami waves, less than one centimetre, in a very noisy environment. At the same time the seismic data are analysed using a STA/LTA algorithm. The tsunami detector sends a near real time automatic alert message when a seismic or a pressure signal exceeds a selectable threshold indicating a strong local earthquake or a tsunami wave event. After the detection of an event, the seafloor observatory will start sending updated pressure data to the shore station. Our objective is to combine a novel approach to the tsunami warning problem, with a study of the coupling between the water column perturbations and sea floor motion, together with the long term monitoring of geophysical, geochemical and oceanographic parameters.
    Description: Published
    Description: Vienna
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: open
    Keywords: tsunami detection ; tsunami warning ; seafloor observatory ; multiparameter ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2017-04-04
    Description: Nell' ambito del progetto NEAREST finanziato dalla EC sono stati sviluppati alcuni elementi di un sistema di allerta per tsunami, fra i quali un prototipo di detector di onde anomale istallato a bordo dell' osservatorio abissale GEOSTAR: l' osservatorio con il detector di onde anomale ha operato per un anno nel Golfo di Cadice, a 3200m di profondità
    Description: Published
    Description: Sassari
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: open
    Keywords: seafloor observatories, ; tsunami detection ; 1775 earthquake ; Cadiz Gulf ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...