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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 105 (1990), S. 486-490 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Baumgartner and Rumble (1988) apply a ‘kinetic continuum theory for stable isotope transport’ to unidimensional infiltration of fluid into rock. Their numerical applications are restricted to the simplified case of rapid isotope exchange between phases, where the sharp isotope fronts of pure advection are distended by dispersive mechanisms only. However, kinetic limitations of isotope exchange are potentially an equally important distending mechanism, and it will only rarely be possible to ascribe front gradients to diffusion/dispersion alone. Abrupt isotopic changes at vein boundaries are more often a secondary signal of lithologic change than the expression of a retarded advective front. At such boundaries, diffusion and dispersion play a role that is comparable to, or greater than, that of advection, so that the detailed shapes of isotope fronts depend upon boundary conditions for the infiltration process. Zerodimensional box models have legitimate, if limited, uses in the modelling of fluid-rock interaction, and are reexamined.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 105 (1990), S. 650-661 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Meta-igneous granulite (MIG) xenoliths in lavas from Mount Ruapehu, Taupo Volcanic Zone, New Zealand, have variable but relatively high δ18O (+8.2 to +11.7) and 87Sr/86Sr (0.70506 to 0.70872), and εNd ranging from +1.5 to +6.2. They show a strong positive correlation between 87Sr/86Sr and δ18O, both of which are also broadly correlated with Mg number, but lack any correlation between 87Sr/86Sr and εNd. The xenoliths have been mineralogically re-equilibrated at lower-crustal temperatures (800–930°C) and pressures (7–10 kbar). Geochemical and isotopic evidence suggests they are fragments of oceanic crust that have been altered previously in an ocean floor hydrothermal system. Alternatively, they may be igneous rocks of unknown origin hydrothermally altered in the lower crust. Irrespective of this uncertainty, the xenoliths provide rare samples of the lower crustal basement beneath Taupo Volcanic Zone and represent a potential source rock for the voluminous rhyolites and ignimbrites that dominate the zone.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 44 (1974), S. 17-27 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A lamprophyre dike swarm intruding the Haast Schist terrain of Southern New Zealand includes Ba-, Sr-, and REE-rich carbonatites with carbon and oxygen isotopic compositions quite distinct from those of the country rock. In the light of more recent literature data it is argued that the field of carbon and oxygen isotopic compositions defined by Taylor et al. (1967) as pertaining to “primary igneous carbonatites” (PIC), is still relevant. The Haast carbonatite isotopic compositions are readily derived from the PIC field, if assimilation of and isotopic exchange with the known country rock by the magma is allowed for. The Haast Schist terrain is very poor in carbonate rocks and may directly overlie oceanic crust. Hence δC13 values typical of lower crust or upper mantle sources are preserved in the Haast carbonatites, and only δO18 has been modified during intrusion.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 55 (1976), S. 181-190 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract In hypersthene bearing hornblende metadiorites near Milford Sound garnet replaces hornblende in ∼5 cm wide subplanar zones, patterned almost certainly on joints. The alteration has been accompanied by a change in bulk rock composition (increase of Al, decrease of Na) and the occurrence constitutes good evidence for external chemical control of the overprinting of “hornblende granulites” with garnet.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 72 (1980), S. 291-296 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Literature data on chlorine and fluorine in apatite and biotite of different rocks correspond reasonably well with thermodynamic expectations, indicating that concentrations are related to primary or major crystallisation events. Petrographically similar leucogabbros in the Riwaka and Milford Sound areas, widely separated on opposite sides of the Alpine Fault, are characterised by similar fluorine and similar, unusually high, chlorine concentrations in their minerals and appear genetically equivalent.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 74 (1980), S. 339-348 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A network of 5 cm wide subplanar zones of garnet-granolite with accessory apatite as the dominant hydrous mineral, is overprinted on basic hornblende-granolites in an area of present and past tectonic uplift. Fracturing and the garnet forming reactions appear to be caused by destabilisation of hornblende, as a hydrous phase, through a critical drop in the P∶T ratio. Whereas the apatites from the hornblende-granolite have normal compositions, apatites from the garnet-granolite zones are among the most chlorine enriched hydroxyfluorapatites known. A later amphibolite facies event has depleted hydrous minerals of fluorine and chlorine, affecting hornblende more strongly than apatite. Based on literature data on F and Cl in coexisting minerals, original hornblende compositions are tentatively restored. It is then possible to derive all the chlorine of the garnet zone apatites from the original rock, with differential loss of H2O and HF over chlorine during the dehydration reaction. Diffusion coefficients would have been larger for H2O and HF than for the large chloride ion, and if the gas phase was in contact with even minor anatectic melts, activity gradients would also have been relatively small for chlorine. Low-Cl scapolite is present in quartz-free pegmatoid veins. Field evidence for a genetic tie between the garnet zones and these veins is inconclusive, but liberation of H2O and HF under granolite facies conditions is likely to have caused limited fusion of the plagioclase. Since many garnet zones do not contain even small pegmatoid veins, melts related to their formation could have collected in veins only after initial diffusion or ‘infiltration’ over a distance, and without leaving segregated mafic residues.
    Type of Medium: Electronic Resource
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