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  • 1
    Publication Date: 2022-01-31
    Description: Groundwater, the largest available store of global freshwater1, is relied upon by more than two billion people2. It is therefore important to quantify the spatiotemporal interactions between groundwater and climate. However, current understanding of the global-scale sensitivity of groundwater systems to climate change3,4—as well as the resulting variation in feedbacks from groundwater to the climate system5,6—is limited. Here, using groundwater model results in combination with hydrologic data sets, we examine the dynamic timescales of groundwater system responses to climate change. We show that nearly half of global groundwater fluxes could equilibrate with recharge variations due to climate change on human (~100 year) timescales, and that areas where water tables are most sensitive to changes in recharge are also those that have the longest groundwater response times. In particular, groundwater fluxes in arid regions are shown to be less responsive to climate variability than in humid regions. Adaptation strategies must therefore account for the hydraulic memory of groundwater systems, which can buffer climate change impacts on water resources in many regions, but may also lead to a long, but initially hidden, legacy of anthropogenic and climatic impacts on river flows and groundwater-dependent ecosystems.
    Type: Article , PeerReviewed
    Format: text
    Format: text
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  • 2
    Publication Date: 2015-06-23
    Description: Spherulites in rhyolitic obsidian provide a record of the thermal history of their host lava during the interval of spherulite growth. We use trace element concentration profiles across spherulites and into the obsidian host from Yellowstone National Park (USA) to reconstruct the conditions that existed during spherulite formation. The measured transects reveal three behaviors: expulsion of the most diffusively mobile elements from spherulites with no concentration gradients in the surrounding glass (type 1); enrichment of slower-diffusing elements around spherulites, with concentration gradients extending outward into the glass (type 2); and complete entrapment of the slowest-diffusing elements by the spherulite (type 3). We compare the concentration profiles, measured by laser ablation–inductively coupled plasma–mass spectrometry and Fourier transform infrared spectroscopy, to the output of a spherulite growth model that incorporates known diffusion parameters, the temperature interval of spherulite growth, the cooling rate of the lava, and data on the temporal evolution of spherulite radius. Our results constrain spherulite nucleation to the temperature interval 700–550 °C and spherulite growth to 700–400 °C in a portion of lava that cooled at 10 –5.2 ± 0.3 °C s –1 , which matches an independent experimental estimate of 10 –5.3 °C s –1 measured using differential scanning calorimetry. Maximum spherulite growth rates at nucleation are on the order of 1 μm hr –1 and are inferred to decrease exponentially with time. Hence, spherulites may serve as valuable in-situ recorders of the thermal history of lava flows.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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